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The goal of the work reported in this dissertation is to develop methods for the acquisition and reproduction of high quality digital color images. To reach this goal it is necessary to understand and control the way in which the different devices involved in the entire color imaging chain treat colors. Therefore we addressed the problem of colorimetric characterization of scanners and printers, providing efficient and colorimetrically accurate means of conversion between a device-independent color space such as the CIELAB space, and the device-dependent color spaces of a scanner and a printer.