Application of IC-MS and IC-Icp-MS in Environmental Research

Herausgeber: Michalski, Rajmund

• Gebundenes Buch

Produktbeschreibung

Introduces the reader to the field of ion chromatography, species analysis and hyphenated methods IC-MS and IC-ICP-MS including the theory and theirs applications * Covers the importance of species analysis and hyphenated methods in ion chromatography * Includes practical applications of IC-MS and IC-ICP-MS in environmental analysis * Details sample preparation methods for ion chromatography * Discusses hyphenated methods IC-MS and IC-ICP-MS used in determining both the total element contents and its elements * Details speciation analysis used in studying biochemical cycles of selected chemical compounds; determining toxicity and ecotoxicity of elements; food and pharmaceuticals quality control; and in technological process control and clinical analytics

Produktdetails

• Verlag: John Wiley & Sons / Wiley
• Seitenzahl: 288
• Erscheinungstermin: 7. Juni 2016
• Englisch
• Abmessung: 244mm x 163mm x 20mm
• Gewicht: 522g
• ISBN-13: 9781118862001
• ISBN-10: 1118862007
• Artikelnr.: 42966502

Autorenporträt

Rajmund Michalski works at the Institute of Environmental Engineering of Polish Academy of Sciences. He has authored/edited a dozen of books and over 250 publications about applications of ion chromatography in environmental samples analysis, as well as application of modern analytical methods and techniques for environmental protection and assessment. Since 2005 he has annually organized the since international ion chromatography conference in Poland.

Inhaltsangabe

List of Contributors ix Preface xi 1 Principles and Applications of Ion Chromatography 1 Rajmund Michalski 1.1 Principles of Ion Chromatography
1 1.1.1 Introduction
1 1.1.2 Stationary Phases
6 1.1.3 Eluents
13 1.1.4 Suppressors
16 1.1.5 Detection Methods
18 1.2 Ion Chromatography Applications
23 1.2.1 Speciation Analysis with the Hyphenated Methods of IC-ICP-MS and IC-MS
29 1.3 Sample Preparation for Ion Chromatography
32 1.4 Selected Methodological Aspects of Ion Determination with Ion Chromatography
34 1.5 Ion Chromatography Development Perspectives
37 1.6 References
37 2 Mass Spectrometric Detectors for Environmental Studies 47 Maria Balcerzak 2.1 Introduction
47 2.2 Mass Spectrometric Detectors
49 2.2.1 Ionization Methods
50 2.2.2 Mass Analyzers
58 Acknowledgments
62 2.3 References
62 3 High-Performance Liquid Chromatography Coupled to Inductively Coupled Plasma MS/Electrospray Ionization MS 79 Jürgen Mattusch 3.1 Separation Principles
79 3.1.1 Ion Chromatography (Anion/Cation Exchange
Mixed Mode)
80 3.1.2 High-Performance Liquid Chromatography (Reversed-Phase Mode
HILIC)
81 3.1.3 Size Exclusion Chromatography (SEC) (Gel Filtration Chromatography
GFC)
82 3.2 Detection Principles
83 3.2.1 Common Detection in IC: Conductivity
UV-Vis
Electrochemical Detection
83 3.2.2 Element Specific Detection
83 3.3 Hyphenated Techniques
87 3.3.1 HPLC(IC)-ICP-MS
87 3.4 HPLC(IC)-ICP-MS/ESI-MS
90 3.4.1 Fundamentals
90 3.4.2 Methodology of Data Evaluation
90 3.4.3 Technical Requirements
91 3.5 Applications and Conclusion
91 3.6 References
102 4 Application of IC-MS in Organic Environmental Geochemistry 109 Klaus Fischer 4.1 Introduction
109 4.2 Carboxylic Acids
114 4.2.1 Molecular Structure
Molecular Interaction Potential
and Chromatographic Retention
114 4.2.2 Environmental Analysis of Carboxylic Acids by Ion Exclusion Chromatography-Mass Spectrometry (HPICE-MS)
116 4.2.3 Environmental Analysis of Carboxylic Acids by Ion-Exchange Chromatography-Mass Spectrometry (HPI-EC-MS)
124 4.3 Carbohydrates
135 4.3.1 Structural Diversity and Ion Chromatographic Behavior
135 4.3.2 Environmental Analysis of Carbohydrates by Various IC-MS Methods
136 4.4 Amines and Amino Acids
143 4.5 Trends and Perspectives
144 4.6 References
145 5 Analysis of Oxyhalides and Haloacetic Acids in Drinking Water Using IC-MS and IC-ICP-MS 152 Koji Kosaka 5.1 Introduction
152 5.2 Source of Oxyhalides and HAAs
154 5.3 Analysis of Oxyhalides and HAAs
158 5.3.1 Suppressed IC-MS
158 5.3.2 Nonsuppressed IC-MS and LC-MS
162 5.3.3 IC-ICP-MS
165 5.4 Application for Monitoring of Oxyhalides and HAAs in Drinking Water
166 5.4.1 Oxyhalides
166 5.4.2 HAAs
171 Summary
171 5.5 References
172 6 Analysis of Various Anionic Metabolites in Plant and Animal Material by IC-MS 178 Adam Konrad Jagielski and Michal Usarek 6.1 Introduction
178 6.2 Optimization of HPIC and Ms Settings
179 6.2.1 HPIC Settings
179 6.2.2 MS Settings
183 6.2.3 HPIC-MS Settings
185 6.2.4 Extraction of Metabolites from Cells and Tissues
189 6.3 Application of the Method in Analysis of Metabolites in Plant and Animal Material
191 6.3.1 Analysis of Metabolites from Cell Cultures (Primary Cultures as well as Established Cell Lines)
192 6.3.2 Analysis of Metabolites from Solid Tissues
192 6.3.3 Extraction of Metabolites from Plants
194 6.4 Conclusions
196 6.5 References
197 7 Analysis of Perchlorate Ion in Various Matrices Using Ion Chromatography Hyphenated with Mass Spectrometry 199 Jay Gandhi 7.1 Introduction
199 7.2 Precautions Unique to Ion Chromatography-Mass Spectrometry
200 7.2.1 Instrumental and Operating Parameters
201 7.3 Results and Discussion
204 Acknowledgment
209 7.4 References
209 8 Sample Preparation Techniques for Ion Chromatography 210 Wolfgang Frenzel and Rajmund Michalski 8.1 Introduction
210 8.2 When and Why is Sample Preparation Required in Ion Chromatography? 213 8.3 Automation of Sample Preparation (IN-LINE Techniques)
215 8.4 Sample Preparation Methods
217 8.4.1 Filtration and Ultrafiltration
219 8.4.2 Solid-Phase Extraction (SPE)
220 8.4.3 Liquid-Liquid Extraction
225 8.4.4 Gas-Phase Separations
226 8.4.5 Precipitation
226 8.4.6 Membrane-Based Separations and Sample Treatment
227 8.5 Trace Analysis and Preconcentration for Ion Chromatographic Analysis
238 8.5.1 Preconcentration Using SPE
239 8.5.2 Membrane-Based In-Line Preconcentration
241 8.6 In-Line Preseparations Using Two-Dimensional Ion Chromatography (2D-IC)
243 8.7 Sample Preparation of Solid Samples
244 8.7.1 Dissolution and Aqueous or Acid Extraction
246 8.7.2 Wet-Chemical Acid Digestions
247 8.7.3 UV Photolytic Digestion
248 8.7.4 Fusion Methods
249 8.7.5 Dry Ashing and Combustion Methods
249 8.8 Air Analysis Using Ion Chromatography - Application to Gases and Particulate Matter
251 8.9 Postcolumn Eluent Treatment Prior to Ms Detection
255 8.10 Concluding Remarks
257 8.11 References
258 Index 267