Henry Warson, C. A. Finch

Applications of Synthetic Resin Latices, Fundamental Chemistry of Latices and Applications in Adhesives

• Gebundenes Buch

Produktbeschreibung

Das dreibändige Werk behandelt die Herstellung und Anwendung spezieller Gruppen von Polymeremulsionen. Dieser 1. Band beginnt mit einem Überblick über die Grundlagen der Polymerchemie, Prinzipien und Praxis der Emulsionspolymerisation sowie die resultierenden Latexmischungen und ihre Eigenschaften. Ausführlich diskutiert wird die Formulierung von Klebstoffen auf Latexbasis.

Produktdetails

• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 728
• Erscheinungstermin: 8. Oktober 2001
• Englisch
• Abmessung: 235mm x 157mm x 47mm
• Gewicht: 1150g
• ISBN-13: 9780471952688
• ISBN-10: 0471952680
• Artikelnr.: 14924512

Autorenporträt

H. Warson is the author of Applications of Synthetic Resin Latices, Volume 1, Fundamental Chemistry of Latices & Applications in Adhesives, published by Wiley. C. A. Finch is the author of Applications of Synthetic Resin Latices, Volume 1, Fundamental Chemistry of Latices & Applications in Adhesives, published by Wiley.

Inhaltsangabe

Preface. Applications--A Note on References. Patent Viability.
Introduction. FUNDAMENTALS OF POLYMER CHEMISTRY. The Concept of a Polymer.
Historical Introduction. Definitions. Addition Polymerisation. Free radical
polymerisation. Copolymerisation. Chain Branching; Block and Graft
Copolymers. Chain Branching. Graft Copolymers. Polymer Structure and
Properties. Polymer structure. Molecular weight effects. Transition points.
Technology of Polymerisation. Bulk polymerisation. Solution polymerisation.
Suspension polymerisation. The Principal Monomers and Their Polymer.
Hydrocarbons. Vinyl esters. Clorinated monomers. Acrylics. Polymerisable
acids and anhydrides. Self-emulsifying monomers. Esters for
copolymerisation. Monomers with several double bonds. Allyl derivatives.
Vinyl ethers. Miscellaneous monomers containing nitrogen. Toxicity and
handling. Physical Properties of Monomers. Appendix. References. EMULSIONS
AND COLLOIDS. Introduction to Colloid Chemistry. Historical. Emulsions.
Surfactants and Stabilisers. A Survey of Technical Surfactants. Anionic
types-fatty acids and allied salts. Sulfates and sulfonates. Hydrotropes.
Phosphates. Fluorochemical emulsifiers. Non-ionic types. Biodegradable
emulsifiers. Cationic types. Amphoteric emulsifiers. Polymerisable agents.
Dispersing agents. Solid dispersants. Colloids and High Molecular Weight
Stabilisers. Starch and dextrin. Cellulose ethers. Other semi-synthetic
colloids. Polyvinyl alcohol. Polyelectrolytes. Other synthetic
water-soluble polymers. Associative thickeners. References. Supplementary
references for Section 3.9. EMULSION POLYMERISATION. General Principles.
Chemistry and fundamentals. Technology, Laboratory and Large Scale.
Monomers. Pilot plants and large-scale reactors. Special techniques;
continuous processes. Varied polymerisation techniques. Vinyl Acetate and
Copolymer Latices. Historical development of latices. Polyvinyl acetate and
related coploymers. Copolymers of vinyl acetate. Alkali-soluble polymers.
Equivalence of 'external' and 'internal' plasticisation. Acrylic Latices.
Typical acrylic formulations. Developments in polymerisation of acrylics.
Styrene Latices. Processes-general. Diene Polymers and Copolymers.
Introduction. Dienes: non-rubber applications. Carboxylated latex
formulations. Vinyl Halides. Vinyl chloride polymers and copolymers.
Vinylidene chloride polymers and copolymers. Monomers containing bromine.
Vinyl compounds containing fluorine. Emulsion Polymerisation-Theoretical
Considerations. Types of mechanism. Theories of Harkins and Smith and
Ewart. Theory of Medvedev. Theoretical developments-Fitch and Ugelstadt.
Copolymerisation-theoretical. Specificity of surfactants and stabilisers.
Latex particle stablization. Further quantitative investigations. 1
Styrene. Emulsion polymerisation, acrylic and methacrylic esters. Emulsion
polymerisation of vinyl acetate. Styrene copolymers (except with dienes).
Butadiene copolymers. Copolymerisation including a water-soluble monomer.
Emulsion Polymerisation in Supercritical Carbon Dioxide. Inverse Emulsions.
Interpenetrating Networks (IPN). Conclusions. References. LATEX PROPERTIES
RELATIVE TO APPLICATIONS. Introduction. Various Properties and
Descriptions. Emulsion particles and resultant properties. Particle
characterization. Core-shell copolymers-surface and buried groups.
Adsorption of surfactants on latex particles. Emulsion viscosity.
Freeze-Thaw and Tropical Stability. Freeze-thaw stability-general
principles. Freeze-thaw stability-technical methods of control. Freeze-thaw
stability-tests. Tropical stability. Emulsion Films. Film formation.
Theoretical developments. Minimum film-forming temperature. Specific
studies-film formation. Summary. Addition of Plasticisers and Coalescing
Solvents. Introduction. The mechanism of platicisation in emulsion.
Plasticisation of principle polymers. Transient plasticisers (coalescing
solvents). Pigementation. Introduction. Pigmentary power. Some common
pigments and extenders. Pigmentation of latices. General properties of
pigmented systems. Critical pigment volume concentration. Pigment
encapsulation. Organic Extenders. References. CROSSLINKING AND CURING.
Introduction. Problems of crosslinking in latices. A survey of
crosslinking. Estimation of Crosslinking. Cure studies. Cure tests.
Multiple Double Bonds. Polymers including divinylbenzene and allied
monomers. Polymers derived from acrylic and allied esters-multiple double
bonds. Allyl polymers-multiple double bonds. Diene polymers. Other
vinyl-type polymers with residual unsaturation. The Carboxyl Function in
Polymers. Introduction. Combinations with hydroxyl and epoxide groups.
Metal oxides. The Hydroxyl Function. Reactions with aldehydes. Dioxalane
derivatives. The Epoxide Function. Internal epoxide groups in unsaturated
monomer. External epoxide compounds. Di-Isocyanates and Polyurethanes In
Vinyl-Type Cures. Polymers Containing (Meth)Acrylamide. Chemistry of the
reactions. Simple derivatives of acrylamide. Diacetoneacrylamide (DAAM).
Methylene bis acrylamide (MBAM). The aminimides. Acrylamidoglycollates.
Other amide derivatives with unsaturation. Cure with aminoplasts. Polymers
Containing Halogens. Radiation Curing. Ultraviolet curing. Cure by electron
beam (EB). Incorporation of Siloxanes. Cure of Eva and Saturated Polymers.
Other Crosslinking Systems. Acid and alkali induced crosslinking.
Crosslinking via beta-ketonic acid esters. Crosslinking with reactive
nitrogen compounds. Intra- and inter-molecular reactions. Unspecified.
References. TECHNICAL POLYMER LATICES. Introduction. Polyvinyl Acetate and
Related Polymers. Polyvinyl acetate. Copolymers of dinyl acetate. Typical
commercial products. Acrylic Polymers and Copolymers. Properties of acrylic
polymers. Properties of acrylic resin films. Vinyl Halide Polymers.
Polyvinyl chloride. Polymers and copolymers of vinylidene chloride.
Fluorocarbon latices. Styrene Polymers and Copolymers. Polystyrene.
Styrene-butaiene copolymers. Polymers Based on Aliphatic Hydrocarbons.
Vinylpyrrolidone Copolymersd. The Testing of Latices. Total solids content.
Monomer content. Specific gravity. pH stability. Freeze-thaw stability.
Emulsion viscosity. Particle size. Soap titration; surface tension
measurements. Settling and sedimentation. Mechanical stability. Minimum
film temperature (MFT). Relative molecular weight (viscosity). General film
measurements. Determination of charge. UNSATURATED POLYMERS AND NON-VINYL
EMULSIONS. Introduction. Alkyds and Polyesters. Polyesters. Alkyds and
allied products. Aminoplasts. Polyamide Emulsions. Epoxide Resins and
Blends. Initial condensation in emulsion. Amine salt emulsification.
Non-ionic emulsifiers. Cycloaliphatic epoxides. Water-in-oil emulsions.
Epoxides containing halogens. Epoxide-polyamide emulsions. Epoxide
emulsions-miscellaneous blends and reactions. Applications. Phenoplasts.
Silicones. Elementary chemistry. Some methods of emulsification. Textile
and paper applications of silicone oragnopolysiloxane latices. Silicone
latices in surface coating and building. Miscellaneous applications.
Polyurethanes. Chemistry of isocyanate adducts. Polyurethane latex.
Applications of polyurethane latices. References. POLYMER LATICES IN THE
FORMULATION OF ADHESIVES. Introduction. Terminology of adhesives. Survey of
Theories of Adhesion. Basic theory. The function of adhesives: latex
adhesives. Latex-Based Adhesives: Some Practical Aspects. Introduction.
Functions of adhesives. Practical requirements of adhesives. Specific
Adhesive Types. Polyvinyl acetate homopolymer-based adhesives. Polyvinyl
acetate copolymer-based adhesives. Polyvinyl propionate latices in
adhesives. Acrylic copolymer latices. Vinylidene chloride and other
halogenated polymer latices in adhesive. Butadiene coploymer latices. Other
latex types. Latex-Based Adhesives with Specific Functions.
Pressure-sensitive adhesives. Removable pressure-sensitive adhesives.
Contact adhesives. Heat-seal adhesives. Delayed tack adhesives.
Remoistenable adhesives. Quick-tack and contact-grab adhesives.
Redispersible components for pressure-sensitive adhesives. Adhesive for
Specific Applications. Wood adhesives. Latex-based adhesives for paper
bonding. Adhesives for packaging. Miscellaneous latex-based adhesives.
Rubber-to-Fabric Adhesives. Introduction. Vinylpyriding copolymer
adhesives. Dip additives and composition. Other rubber adhesive systems.
Modifications of resorcinol-formaldehyde resins. Latex modifications. Test
Methods for Adhesives. Appendix: Some Technical Products for Water-Based
Adhesives. Glossary of Terms Relating to Adhesives. References. Index.

Rezensionen

"...a valuable reference resource..."(Polymer International, Vol 54 (9) September 2005)