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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Autoxidation is any oxidation that occurs in open air or in presence of oxygen and/or UV radiation and forms peroxides and hydroperoxides. A classic example of autoxidation is that of simple ethers like diethyl ether, whose peroxides can be dangerously explosive. It can be considered to be a slow, flameless combustion of materials by reaction with oxygen. Autoxidation is important because it is a useful reaction for converting compounds to oxygenated derivatives, and also because it occurs in situations where it is not desired (as in the destructive cracking of the rubber in automobile tires). Although virtually all types of organic materials can undergo air oxidation, certain types are particularly prone to autoxidation, including unsaturated compounds that have allylic hydrogens or benzylic hydrogens; these materials are converted to hydroperoxides by autoxidation.