C-H functionalisation and fluorescent chiral discrimination - Munusamy, Sathishkumar;Kulathu Iyer, Sathiyanarayan
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This study speaks about practical and efficient synthesis of 2-phenyl-4H-benzo[d][1,3]oxazine-4-one derivatives through copper catalyzed tandem reaction of 2-iodobenzoic acid with arylmethanamines under air. Compared to the literature methods toward the synthesis of 2-phenyl-4H-benzo[d][1,3]oxazine-4-one, the synthetic method reported in this paper has broad substrate scope, mild reaction condition and uses an inexpensive catalyst. In order to understand the interactions of biological molecules and for the designing of asymmetric catalytic systems particular significance must be given to…mehr

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Produktbeschreibung
This study speaks about practical and efficient synthesis of 2-phenyl-4H-benzo[d][1,3]oxazine-4-one derivatives through copper catalyzed tandem reaction of 2-iodobenzoic acid with arylmethanamines under air. Compared to the literature methods toward the synthesis of 2-phenyl-4H-benzo[d][1,3]oxazine-4-one, the synthetic method reported in this paper has broad substrate scope, mild reaction condition and uses an inexpensive catalyst. In order to understand the interactions of biological molecules and for the designing of asymmetric catalytic systems particular significance must be given to chiral recognition. Among many chiral discrimination methods known, the method involves fluorescent chiral discrimination has advantages. Considering this we have designed and synthesized minor groove functionalized (S)-BINOL fluorescent probes starting from (S)-BINOL. The synthesized molecules introduce new opportunities in the field of chiral recognition.
Autorenporträt
Sathishkumar Munusamy travaille actuellement comme chercheur post-doctoral à l'Institut des sciences physiques de l'Université nationale autonome du Mexique. Ses recherches actuelles portent sur les biocapteurs fluorescents et les matériaux optoélectroniques organiques.