This reference details the theory and application of cation complexation, including the design and synthesis of various cyclic systems, these materials' use as transport systems, in complexation and selectivity studies by macrocyclic systems, and methodologies for understanding these phenomena. In a
This reference details the theory and application of cation complexation, including the design and synthesis of various cyclic systems, these materials' use as transport systems, in complexation and selectivity studies by macrocyclic systems, and methodologies for understanding these phenomena. In a
Preface Contributors 1 Thermodynamics of Cation-Macrocycle Complexation: Enthalpy Entropy Compensation 2 Understanding Cation-Macrocycle Binding Selectivity in Single-Solvent Extraction and Liquid Membrane Systems by Quantifying Thermodynamic Interactions 3 Conductometric Behavior of Cation-Macrocycle Complexes in Solutions 4 Rates and Mechanisms of Complexation Reactions of Cations with Crown Ethers and Related Macrocycles 5 Electrostatic Ion Binding by Synthetic Receptors 6 Cation Binding by Lariat Ethers 7 Crystallography of Cation Complexes of Lariat Ethers 8 Redox Control of Cation Binding in Macrocyclic Systems 9 Dynamic Control of Cation Binding 10 Application of Macrocycles to Ion-Selective Electrodes 11 Complexation by Chromoionophores 12 Cation Binding by Natural and Modified Ionophores: From Natural Ionophore to Synthetic Ionophore 13 Unsaturated Crown Ethers: Synthesis Cation Binding and Reactions 14 Complexation by Crown Ethers of Low Symmetry 15 Cation Complexation by Calixarenes 16 Mixed-Donor Macrocycles: Solution and Structural Aspects of Their Complexation with Transition and Post-Transition Ions 17 Second-Sphere Coordination of Transition Metal Complexes by Crown Ethers 18 Macrocyclic Complexes of Lanthanide Ions Index
Preface Contributors 1 Thermodynamics of Cation-Macrocycle Complexation: Enthalpy Entropy Compensation 2 Understanding Cation-Macrocycle Binding Selectivity in Single-Solvent Extraction and Liquid Membrane Systems by Quantifying Thermodynamic Interactions 3 Conductometric Behavior of Cation-Macrocycle Complexes in Solutions 4 Rates and Mechanisms of Complexation Reactions of Cations with Crown Ethers and Related Macrocycles 5 Electrostatic Ion Binding by Synthetic Receptors 6 Cation Binding by Lariat Ethers 7 Crystallography of Cation Complexes of Lariat Ethers 8 Redox Control of Cation Binding in Macrocyclic Systems 9 Dynamic Control of Cation Binding 10 Application of Macrocycles to Ion-Selective Electrodes 11 Complexation by Chromoionophores 12 Cation Binding by Natural and Modified Ionophores: From Natural Ionophore to Synthetic Ionophore 13 Unsaturated Crown Ethers: Synthesis Cation Binding and Reactions 14 Complexation by Crown Ethers of Low Symmetry 15 Cation Complexation by Calixarenes 16 Mixed-Donor Macrocycles: Solution and Structural Aspects of Their Complexation with Transition and Post-Transition Ions 17 Second-Sphere Coordination of Transition Metal Complexes by Crown Ethers 18 Macrocyclic Complexes of Lanthanide Ions Index
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