Cavity Ring-Down Spectroscopy
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Cavity ring-down spectroscopy (CRDS) is a highly sensitive optical spectroscopic technique that enables measurement of absolute optical extinction by samples that scatter and absorb light. It has been widely used to study gaseous samples which absorb light at specific wavelengths, and in turn to determine concentrations down to the parts per trillion level. The technique is also known as cavity ring-down laser absorption spectroscopy (CRLAS). A typical CRDS setup consists of a laser that is used to illuminate a high-finesse optical cavity, which in its simplest form consists of two highly…mehr

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Cavity ring-down spectroscopy (CRDS) is a highly sensitive optical spectroscopic technique that enables measurement of absolute optical extinction by samples that scatter and absorb light. It has been widely used to study gaseous samples which absorb light at specific wavelengths, and in turn to determine concentrations down to the parts per trillion level. The technique is also known as cavity ring-down laser absorption spectroscopy (CRLAS). A typical CRDS setup consists of a laser that is used to illuminate a high-finesse optical cavity, which in its simplest form consists of two highly reflective mirrors. When the laser is in resonance with a cavity mode, intensity builds up in the cavity due to constructive interference. The laser is then turned off in order to allow the measurement of the exponentially decaying light intensity leaking from the cavity. During this decay, light is reflected back and forth thousands of times between the mirrors giving an effective path length for the extinction on the order of a few kilometers. If something that absorbs light is placed in the cavity, the amount of light decreases faster it makes fewer bounces before it is all gone.