Gilbert F. Froment, Kenneth B. Bischoff, Juray De Wilde

Chemical Reactor Analysis and Design

• Gebundenes Buch

Produktbeschreibung

This is the Third Edition of the standard text on chemical reaction engineering, beginning with basic definitions and fundamental principles and continuing all the way to practical applications, emphasizing real-world aspects of industrial practice. The two main sections cover applied or engineering kinetics, reactor analysis and design. Includes updated coverage of computer modeling methods and many new worked examples. Most of the examples use real kinetic data from processes of industrial importance.

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Produktdetails

• Verlag: Wiley & Sons
• 3. Aufl.
• Seitenzahl: 912
• Erscheinungstermin: 24. August 2010
• Englisch
• Abmessung: 261mm x 207mm x 40mm
• Gewicht: 1610g
• ISBN-13: 9780470565414
• ISBN-10: 0470565411
• Artikelnr.: 31187344

Autorenporträt

Dr. Gilbert F. Froment is Professor Emeritus of Chemical Engineering at the University of Gent, Belgium, and Research Professor of Texas A&M University. Kenneth B. Bischoff is the author of Chemical Reactor Analysis and Design, 3rd Edition, published by Wiley.

Inhaltsangabe

Chapter 1: Elements of Reaction Kinetics. 1.1 Definitions of Chemical
Rates. 1.2 Rate Equations. 1.3 Coupled Reactions. 1.4 Reducing the Size of
Kinetic Models. 1.5 Bio-Kinetics. 1.6 Complex Reactions. 1.7 Modeling the
Rate Coefficient. Chapter 2: Kinetics of Heterogeneous Catalytic Reactions.
2.1 Introduction. 2.2 Adsorption on Solid Catalysts. 2.3 Rate Equations.
2.4 Complex Catalytic Reactions. 2.5 Experimental Reactors. 2.6 Model
Discrimination and Parameter Estimation. 2.7 Sequential Design of
Experiments. 2.8 Expert Systems in Kinetics Studies. Chapter 3: Transport
Processes with Reactions Catalyzed by Solids. Part One Interfacial Gradient
Effects. 3.1 Reaction of a component of a fluid at the surface of a solid.
3.2 Mass and heat transfer resistances. 3.3 Concentration or partial
pressure and temperature differences. Part Two Intraparticle Gradient
Effects. 3.4 Molecular-, Knudsen-, and surface diffusion in pores. 3.5
Diffusion in a catalyst particle. 3.6 Diffusion and reaction in a catalyst
particle. A continuum model. 3.7 Falsification of rate coefficient and
activation energy by diffusion limitations. 3.8 Influence of diffusion
limitations on the selectivities of coupled reactions. 3.9 Criteria for the
importance of intraparticle diffusion limitations. 3.10 Multiplicity of
steady states in catalyst particles. 3.11 Combination of external and
internal diffusion limitations. 3.12 Diagnostic experimental criteria for
the absence of internal and external mass transfer limitations. 3.13
Nonisothermal particles. Chapter 4: Noncatalytic Gas-Solid Reactions. 4.1 A
Qualitative Discussion of Gas-Solid Reactions. 4.2 General Model with
Interfacial and Intraparticle Gradients. 4.3 Heterogeneous Model with
Shrinking Unreacted Core. 4.4 Models Accounting Explicitly for the
Structure of the Solid. 4.5 On the Use of More Complex Kinetic Equations.
Chapter 5: Catalyst Deactivation. 5.1 Types of Catalyst Deactivation. 5.2
Kinetics of Catalyst Poisoning. 5.3 Kinetics of Catalyst Deactivation by
Coke Formation. Chapter 6: Gas-Liquid Reactions. 6.1 Introduction. 6.2
Models for Transfer at a Gas-Liquid Interface. 6.3 Two-Film Theory. 6.4
Surface Renewal Theory. 6.5 Experimental Determination of the Kinetics of
Gas-Liquid Reactions. Chapter 7: The Modeling of Chemical Reactors. 7.1
Approach. 7.2 Aspects of Mass-, Heat- and Momentum Balances. 7.3 The
Fundamental Model Equations. Chapter 8: The Batch and Semibatch Reactors.
Introduction. 8.1 The Isothermal Batch Reactor. 8.2 The Nonisothermal Batch
Reactor. 8.3 Semibatch Reactor Modeling. 8.4 Optimal Operation Policies and
Control Strategies. Chapter 9: The Plug Flow Reactor. 9.1 The Continuity,
Energy, and Momentum Equations. 9.2 Kinetic Studies Using a Tubular Reactor
with Plug Flow. 9.3 Design and Simulation of Tubular Reactors with Plug
Flow. Chapter 10: The Perfectly Mixed Flow Reactor. 10.1 Introduction. 10.2
Mass and Energy Balances . 10.3 Design for Optimum Selectivity in
Simultaneous Reactions. 10.4 Stability of Operation and Transient Behavior.
Chapter 11: Fixed Bed Catalytic Reactors. Part One Introduction. 11.1 The
Importance and Scale of Fixed Bed Catalytic Processes. 11.2 Factors of
Progress: Technological Innovations and Increased Fundamental Insight. 11.3
Factors Involved in the Preliminary Design of Fixed Bed Reactors. 11.4
Modeling of Fixed Bed Reactors. Part Two Pseudohomogeneous Models. 11.5 The
Basic One-Dimensional Model. 11.6 One-Dimensional Model with Axial Mixing.
11.7 Two-Dimensional Pseudohomogeneous Models. Part Three Heteorgeneous
Models. 11.8 One-Dimensional Model Accounting for Interfacial Gradients.
11.9 One-Dimensional Model Accounting for Interfacial and Intraparticle
Gradients. 11.10 Two-Dimensional Heterogeneous Models. Chapter 12: Complex
Flow Patterns. 12.1 Introduction. 12.2 Macro- and Micro-Mixing in Reactors.
12.3 Models Explicitly Accounting for Mixing. 12.4 Micro- Probability
Density Function Methods. 12.5 Micro-PDF Moment Methods: Computational
Fluid Dynamics. 12.6 Macro-PDF / Residence Time Distribution Methods. 12.7
Semi-Empirical Models for Reactors with Complex Flow Patterns. Chapter 13:
Fluidized Bed and Transport Reactors. 13.1 Introduction. 13.2 Technological
Aspects of Fluidized Bed and Riser Reactors. 13.3 Some Features of the
Fluidization and Transport of Solids. 13.4 Heat Transfert in Fluidized
Beds. 13.5 Modeling of Fluidized Bed Reactors. 13.6 Modeling of a Transport
of Riser Reactor. 13.7 Fluidized Bed Reactor Models Considering Detailed
Flow Patterns. 13.8 Catalytic Cracking of Vacuum Gas Oil. Chapter
14:Multiphase Flow Reactors. 14.1 Types of Multiphase Flow Reactors. 14.2
Design Models for Multiphase Flow Reactors. 14.3 Specific Design Aspects.