The concept of concerted mechanisms was formulated nearly 90 years ago . Until now, however, no monograph has addressed the concept explicitly. Over the last two decades, substantial advancements made in the development of precise methods for elucidating concerted mechanisms have heightened the need for a comprehensive text on the subject. Concerted Organic and Bio-Organic Mechanisms gathers the salient materials related to this emerging field into a single text. It sets forth the precise definition of concertedness along with working sub-definitions and describes rigorous experimental tools…mehr
The concept of concerted mechanisms was formulated nearly 90 years ago . Until now, however, no monograph has addressed the concept explicitly. Over the last two decades, substantial advancements made in the development of precise methods for elucidating concerted mechanisms have heightened the need for a comprehensive text on the subject. Concerted Organic and Bio-Organic Mechanisms gathers the salient materials related to this emerging field into a single text. It sets forth the precise definition of concertedness along with working sub-definitions and describes rigorous experimental tools chemists can use to diagnose the existence or absence of concerted mechanisms. TOC:Definitions. Techniques. Proton Transfer. Nucleophilic Displacements at Unsaturated Carbon. Nucleophilic Displacements at Saturated Carbon. Displacement Reactions at Heteroatoms. Cyclic Reactions. Enzyme Reactions.
DEFINITIONS Origin of the Concept Mechanism and its Description The Definition of Concertedness Bond Order and Coupling Potential energy or Free Energy? Classes of Concerted Reactions TECHNIQUES Detection of Intermediates Exclusion of Stepwise Mechanisms Transition State Structure PROTON TRANSFER Proton Transfer between Bases Proton Transfer and Displacement Reactions at Saturated Carbon Centers Proton Transfer and Double Bond Changes Non-Perfect Synchronization NUCLEOPHILIC DISPLACEMENTS AT UNSATURATED CARBON Displacements at the Carbonyl Group Vinyl Group Transfer Nucleophilic Aromatic Substitution Nucleophilic Substitution at Diagonal Carbon NUCLEOPHILIC DISPLACEMENTS AT SATURATED CARBON Mechanisms The Carbenium Ion Ion-Pair Intermediates The Concerted Mechanism DISPLACEMENT REACTIONS AT HETEROATOMS Electophilic Displacement at Hydrogen Nucleophilic Displacement at Saturated Nitrogen Nucleophilc Displacement at Silicon Nuleophilic Displacement at Phosphorus(V) Displacement at Sulfur CYCLIC REACTIONS Intermediates Clock Reactions Energetic Relationships Nascent Products Isotope Effects Theoretical Methods ENZYME REACTIONS Proton Transfer Theoretical Calculations Isotopes Carbohydrases Aspartyl Proteases Hydride Transfer Amine Oxidases Carbon-Carbon Bond Formation Clocks Cyclic Reactions
DEFINITIONS Origin of the Concept Mechanism and its Description The Definition of Concertedness Bond Order and Coupling Potential energy or Free Energy? Classes of Concerted Reactions TECHNIQUES Detection of Intermediates Exclusion of Stepwise Mechanisms Transition State Structure PROTON TRANSFER Proton Transfer between Bases Proton Transfer and Displacement Reactions at Saturated Carbon Centers Proton Transfer and Double Bond Changes Non-Perfect Synchronization NUCLEOPHILIC DISPLACEMENTS AT UNSATURATED CARBON Displacements at the Carbonyl Group Vinyl Group Transfer Nucleophilic Aromatic Substitution Nucleophilic Substitution at Diagonal Carbon NUCLEOPHILIC DISPLACEMENTS AT SATURATED CARBON Mechanisms The Carbenium Ion Ion-Pair Intermediates The Concerted Mechanism DISPLACEMENT REACTIONS AT HETEROATOMS Electophilic Displacement at Hydrogen Nucleophilic Displacement at Saturated Nitrogen Nucleophilc Displacement at Silicon Nuleophilic Displacement at Phosphorus(V) Displacement at Sulfur CYCLIC REACTIONS Intermediates Clock Reactions Energetic Relationships Nascent Products Isotope Effects Theoretical Methods ENZYME REACTIONS Proton Transfer Theoretical Calculations Isotopes Carbohydrases Aspartyl Proteases Hydride Transfer Amine Oxidases Carbon-Carbon Bond Formation Clocks Cyclic Reactions
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