Coordination polymers incorporating poly(pyrazole)-type ligands - Tabacaru, Aurel
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Five types of polypyrazolyl ligands have been introduced into the construction of forty three coordination polymers (CPs), also including metal-organic frameworks (MOFs). The structural versatility, along with the advantage of both conventional and solvothermal routes, has been proved toward the formation of a wide set of crystal structures with diverse topologies and dimensionalities. Their specific structural motifs, retrieved by state-of-the-art X-ray powder diffraction methods, have been found to depend both on the stereochemistry of the metal ions, and on the structural feature of each…mehr

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Produktbeschreibung
Five types of polypyrazolyl ligands have been introduced into the construction of forty three coordination polymers (CPs), also including metal-organic frameworks (MOFs). The structural versatility, along with the advantage of both conventional and solvothermal routes, has been proved toward the formation of a wide set of crystal structures with diverse topologies and dimensionalities. Their specific structural motifs, retrieved by state-of-the-art X-ray powder diffraction methods, have been found to depend both on the stereochemistry of the metal ions, and on the structural feature of each ligand. The obtained CPs and MOFs were found to exhibit interesting properties like permanent porosity, thermal resistance, photoluminescence, and even antibacterial action. A combination of two or three properties displayed by some of the synthesized polymeric species makes them suitable candidates as multifunctional materials.
Autorenporträt
Aurel T¿b¿caru (born in 1984 in Galäi, Romania) defended his PhD thesis in 2013, in the field of General and Inorganic Chemistry, at the University of Camerino (Italy), under the supervision of Professor Claudio Pettinari. In 2014, he joined the Department of Chemistry, Physics and Environment, from the ¿Dun¿rea de Jos¿ University of Galäi.