First of its kind book on Denitrogenative Transformations helps researchers and scientists working in organic chemistry, organometallic chemistry, and transition metal catalysis, as well as academicians, industry professionals. It comprises of all the types of polynitrogen heterocycles that are studied to undergo denitrogenative transformation. The first chapter introduces denitrogenative Transformation, its historical aspects and present status. The following chapters use a reaction-based approach to explain denitrogenative transformations in detail.
First of its kind book on Denitrogenative Transformations helps researchers and scientists working in organic chemistry, organometallic chemistry, and transition metal catalysis, as well as academicians, industry professionals. It comprises of all the types of polynitrogen heterocycles that are studied to undergo denitrogenative transformation. The first chapter introduces denitrogenative Transformation, its historical aspects and present status. The following chapters use a reaction-based approach to explain denitrogenative transformations in detail.
Pazhamalai Anbarasan obtained his Ph.D. from the Indian Institute of Science (IISc), Bangalore, after which he moved to Germany as an Alexander-von-Humboldt foundation post-doctoral fellow at the Leibniz Institute for Catalysis (LIKAT). He spent another year at the University of California, Berkely, he returned to India in December 2011 to start his academic career at the Department of Chemistry, Indian Institute of Technology Madras (IIT Madras), where currently he is a professor. His research program is focused on the development of new synthetic strategies employing transition-metal catalysis with special focus on asymmetric synthesis and their implementation in organic synthesis.
Inhaltsangabe
Table of Content 1. Synthesis of N-sulfonyl-1,2,3-triazoles and related compounds 2. Transannulation of N-sulfonyl-1,2,3-triazoles with polar multiple bonds such as carbonyls and nitriles 3. Transannulation of N-sulfonyl-1,2,3-triazoles with non-polar multiple bonds such as alkenes, alkynes and allenes 4. Transannulations of N-sulfonyl-1,2,3-triazoles with Carbo/Heterocycles 5. Insertion of azavinyl carbenes to C-H/X-H bond 6. Insertion of azavinyl carbenes to C-X/X-X bond 7. Denitrogenative rearrangements of N-sulfonyl-1,2,3-triazoles 8. Denitrogenative transformations of NH- and N-fluoroalkyl-1,2,3-triazoles 9. Asymmetric perspective on denitrogenative transformation of 1,2,3-triazoles 10. Denitrogenative transformations of triazoloindoles 11. Metal-catalyzed denitrogenative transformations of pyridotriazoles 12. Metal-free denitrogenative transformations of pyridotriazoles 13. Denitrogenative transannulation of benzotriazoles 14. Denitrogenative transannulation of thiadiazoles 15. Denitrogenative transformations of benzotriazinones and related compounds 16. Denitrogenative transformations of 3-aminoindazoles 17. Denitrogenative transformations of tetrazoles and pyridotetrazoles 18. Radical denitrogenative transformations of polynitrogen heterocycles 19. Application of denitrogenative transformations in synthesis of natural products
Table of Content 1. Synthesis of N-sulfonyl-1,2,3-triazoles and related compounds 2. Transannulation of N-sulfonyl-1,2,3-triazoles with polar multiple bonds such as carbonyls and nitriles 3. Transannulation of N-sulfonyl-1,2,3-triazoles with non-polar multiple bonds such as alkenes, alkynes and allenes 4. Transannulations of N-sulfonyl-1,2,3-triazoles with Carbo/Heterocycles 5. Insertion of azavinyl carbenes to C-H/X-H bond 6. Insertion of azavinyl carbenes to C-X/X-X bond 7. Denitrogenative rearrangements of N-sulfonyl-1,2,3-triazoles 8. Denitrogenative transformations of NH- and N-fluoroalkyl-1,2,3-triazoles 9. Asymmetric perspective on denitrogenative transformation of 1,2,3-triazoles 10. Denitrogenative transformations of triazoloindoles 11. Metal-catalyzed denitrogenative transformations of pyridotriazoles 12. Metal-free denitrogenative transformations of pyridotriazoles 13. Denitrogenative transannulation of benzotriazoles 14. Denitrogenative transannulation of thiadiazoles 15. Denitrogenative transformations of benzotriazinones and related compounds 16. Denitrogenative transformations of 3-aminoindazoles 17. Denitrogenative transformations of tetrazoles and pyridotetrazoles 18. Radical denitrogenative transformations of polynitrogen heterocycles 19. Application of denitrogenative transformations in synthesis of natural products
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