Donor-Acceptor Cyclopropapyranone - Mane, Sumit;Gharpure, Santosh J.;Nanda, Laxminarayan
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My primary research interests center on the Organic Synthesis and study of Donor-Acceptor cyclopropane chemistry. Research activities include the impact of D-A cyclopropanes and cyclobutanes in organic synthesis and its application towards natural product synthesis. An intramolecular, stereoselective cyclopropanation of vinylogous carbonates with carbenes using copper catalyst is developed for the synthesis of donor-acceptor substituted cyclopropapyranones. Completely regioselective ring cleavage of each of the cyclopropane bonds was achieved under suitable reaction conditions, leading to a…mehr

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Produktbeschreibung
My primary research interests center on the Organic Synthesis and study of Donor-Acceptor cyclopropane chemistry. Research activities include the impact of D-A cyclopropanes and cyclobutanes in organic synthesis and its application towards natural product synthesis. An intramolecular, stereoselective cyclopropanation of vinylogous carbonates with carbenes using copper catalyst is developed for the synthesis of donor-acceptor substituted cyclopropapyranones. Completely regioselective ring cleavage of each of the cyclopropane bonds was achieved under suitable reaction conditions, leading to a diverse array of cyclic ethers. The developed method is utilized in the total synthesis of ( )-diospongin B.
Autorenporträt
Sumit Popat Mane Professeur assistant en chimie, BCE Bhagalpur, NH-80, Sabour, Bhagalpur, Bihar-India-813210 Motivé et talentueux, il inspire les étudiants pour leur excellence académique et personnelle. S'efforce constamment de créer un environnement d'apprentissage stimulant et engageant dans lequel les étudiants deviennent des érudits et des apprenants à vie.