This volume contains the papers presented at the Third European Symposium on electrochemical engineering "Electrochemical Engineering and Energy", held on March 23- 25, 1994 in Nancy, France. This meeting was organised by the Laboratoire des Sciences du Genie Chimique, CNRS, and the Centre de Perfectionnement des Industries Chimiques, in conjunction with the Groupe Fran~ais de Genie des Procectes, the Society of Chemical Industry, Dechema, and the European Federation of Chemical Engineeling. The organisers would like to thank the members of the Scientific Committee for the careful selection…mehr
This volume contains the papers presented at the Third European Symposium on electrochemical engineering "Electrochemical Engineering and Energy", held on March 23- 25, 1994 in Nancy, France. This meeting was organised by the Laboratoire des Sciences du Genie Chimique, CNRS, and the Centre de Perfectionnement des Industries Chimiques, in conjunction with the Groupe Fran~ais de Genie des Procectes, the Society of Chemical Industry, Dechema, and the European Federation of Chemical Engineeling. The organisers would like to thank the members of the Scientific Committee for the careful selection and refereeing of the papers. We are grateful to all contributors for the thorough preparation of their manuscripts. Thanks are due to the International Society of Electrochemistry, District Urbain de Nancy, Region Lorraine, Electticite de France, Institut National Poly technique de Lorraine, and CNRS for their support. The meeting was devoted to the role of electrochemical engineeting and itsrelationship to the general issue of energy. The twenty-four papers contained here represent new research results and the potential technological developments in a variety of impOltant and relevant areas of the field. The remaining three papers are expert reviews in areas of current technological concern where electrochemical engineering can clearly be seen to have major relevance to energy policy and environmental protection.
Energy Conversion.- On the Environment Impact of Energy Conversion Systems.- Electrochemical Energy Conversion: Potential Applications and Conditions for Possible Future Introduction in Electrical Systems.- Laboratory Production of Components for Rechargeable Bipolar Manganese Dioxide Zinc Batteries.- Improvement of Secondary Zinc Electrodes.- Hydrogen Gas Diffusion Electrode in Dilute Sulphuric Acid Solution.- A New Concept of an Electrochemical Heat Pump System: Theoretical Consideration and Experimental Results.- Combined Electrochemical and Dilatometry Studies on Metal Hydrides.- Galvanic Deposition of Photovoltaic Compound Semiconductor Coatings.- Transport Processes in Electrochemical Cells.- Energy Correlation of Mass Transfer in Decaying Annular Swirl Flow.- Using of Metallic Foams in Electrochemical Reactors of Filter-Press Type: Mass Transfer and Flow Visualisation.- Electrochemistry in a Packed-Bed Electrode of Activated Carbon Particles: An Investigation of Faradaic and Capacitive Processes.- Modelling the Phenomena Associated with the Application of Centrigugal Fields in Fused Salt Electrolysis Manufacture of Light Metals.- Electrochemical Synthesis.- The Anodic Oxidation of Vanadium - A Possible Technical Application of Electrochemical Fixed Bed Reactors.- Electrosynthesis of Aqueous Ti3+ Solutions.- A Model for the Electrochemical Fonnation of Bromate.- From Voltammetry to Industrial Plant: Electrochemical Synthesis of DL-Homocysteine from DL-Homocystine - An example of Scale-Up.- Aspects of the Electrosynthesis of 2-Hydromethylpyridine.- Modelling of a Polypyrolle Modified Electrode.- Estimation of Current Bypass in Bipolar Electrode Stack.- Modelling of Electrochemical Systems.- Proton Exchange Membrane Fuel Cell Model.- A Model of a Phase TransferCatalyst Liquid/Liquid Electrochemical Membrane Reactor.- Advanced Dynamic Optimization of Batch Electrochemical Reactors.- Modelling and Design of Industrial Fluorine Electrolyzers.- Potential Distribution in a Porous Percolated Reactor with Radial Field: Modelling and Simulation.- Continuous Electrodeposition Modelling: Tertiary Current Distribution on a Plane Electrode - Effect of Axial Diffusion at Low Peclet Number.- A New Approach for Solving Mass and Charge Transport in Electrochemical Systems.- Environmental Electrochemical Engineering Review.- Towards a Cleaner Environment Using Electrochemical Techniques.
Energy Conversion.- On the Environment Impact of Energy Conversion Systems.- Electrochemical Energy Conversion: Potential Applications and Conditions for Possible Future Introduction in Electrical Systems.- Laboratory Production of Components for Rechargeable Bipolar Manganese Dioxide Zinc Batteries.- Improvement of Secondary Zinc Electrodes.- Hydrogen Gas Diffusion Electrode in Dilute Sulphuric Acid Solution.- A New Concept of an Electrochemical Heat Pump System: Theoretical Consideration and Experimental Results.- Combined Electrochemical and Dilatometry Studies on Metal Hydrides.- Galvanic Deposition of Photovoltaic Compound Semiconductor Coatings.- Transport Processes in Electrochemical Cells.- Energy Correlation of Mass Transfer in Decaying Annular Swirl Flow.- Using of Metallic Foams in Electrochemical Reactors of Filter-Press Type: Mass Transfer and Flow Visualisation.- Electrochemistry in a Packed-Bed Electrode of Activated Carbon Particles: An Investigation of Faradaic and Capacitive Processes.- Modelling the Phenomena Associated with the Application of Centrigugal Fields in Fused Salt Electrolysis Manufacture of Light Metals.- Electrochemical Synthesis.- The Anodic Oxidation of Vanadium - A Possible Technical Application of Electrochemical Fixed Bed Reactors.- Electrosynthesis of Aqueous Ti3+ Solutions.- A Model for the Electrochemical Fonnation of Bromate.- From Voltammetry to Industrial Plant: Electrochemical Synthesis of DL-Homocysteine from DL-Homocystine - An example of Scale-Up.- Aspects of the Electrosynthesis of 2-Hydromethylpyridine.- Modelling of a Polypyrolle Modified Electrode.- Estimation of Current Bypass in Bipolar Electrode Stack.- Modelling of Electrochemical Systems.- Proton Exchange Membrane Fuel Cell Model.- A Model of a Phase TransferCatalyst Liquid/Liquid Electrochemical Membrane Reactor.- Advanced Dynamic Optimization of Batch Electrochemical Reactors.- Modelling and Design of Industrial Fluorine Electrolyzers.- Potential Distribution in a Porous Percolated Reactor with Radial Field: Modelling and Simulation.- Continuous Electrodeposition Modelling: Tertiary Current Distribution on a Plane Electrode - Effect of Axial Diffusion at Low Peclet Number.- A New Approach for Solving Mass and Charge Transport in Electrochemical Systems.- Environmental Electrochemical Engineering Review.- Towards a Cleaner Environment Using Electrochemical Techniques.
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