Andere Kunden interessierten sich auch für
![Detailed Kinetic Study of the FTS over the co-precipitated Co-Ce/SiO2]( "Detailed Kinetic Study of the FTS over the co-precipitated Co-Ce/SiO2")
Detailed Kinetic Study of the FTS over the co-precipitated Co-Ce/SiO226,99 €![Non-Ionic Binary Surfactant Systems and Microemulsions as Model Systems for Thermal Diffusion Studies]( "Non-Ionic Binary Surfactant Systems and Microemulsions as Model Systems for Thermal Diffusion Studies")
Non-Ionic Binary Surfactant Systems and Microemulsions as Model Systems for Thermal Diffusion Studies34,30 €![Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductases]( "Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductases")
Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductases34,95 €![Polymer or Macrocycle? Cobalt Complexes of Ditopic 2,2':6',2]( "Polymer or Macrocycle? Cobalt Complexes of Ditopic 2,2':6',2")
Polymer or Macrocycle? Cobalt Complexes of Ditopic 2,2':6',2"- Terpyridine Ligands with Flexible Spacers46,60 €![A Mechanistic Basis for The Coupled Electron/Proton Transfer Reaction]( "A Mechanistic Basis for The Coupled Electron/Proton Transfer Reaction")
A Mechanistic Basis for The Coupled Electron/Proton Transfer Reaction36,99 €![On the structure and reactivity of large complexes of metals and metalloids. A quantum chemical study]( "On the structure and reactivity of large complexes of metals and metalloids. A quantum chemical study")
On the structure and reactivity of large complexes of metals and metalloids. A quantum chemical study20,66 €![Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands]( "Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands")
Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands34,70 €
The present work comprises a study of the kinetics and mechanism of oxidation of binary and ternary cobalt (II) complexes involving CoII ADA and malonic , succinic , or maleic acids by periodateThe kinetics of oxidation of [CoII(ADA)(H2O)3], [CoII(ADA)(M)(H2O)]2- , [CoII(ADA)(Su)(H2O)]2-and [CoII(ADA)(Ma)(H2O)]2- by periodate in aqueous solutions have been studied. Oxidation of CoII complexes show the formation of an initial CoIII product. This may be due to the oxidation process being inner sphere. This is consistent with inner sphere oxidation which are generally proposed for IO4- reactions. Through transformation of initial to final CoIII product an IVI in the initial product is probably substituted by a water molecule with a slow rate due to inertness of CoIII Comprises the layout of the results obtained and their discussions. The effect of various parameters on the rate of reaction has been discussed. An inner- sphere process may be still accommodating through replacement of coordinate H2O by periodate species. The enthalpy of activation ¿H* and entropy of activation ¿S* also were calculated.
Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.