Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization
Broschiertes Buch

Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization

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The activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the ...