Joel S. Miller

Extended Linear Chain Compounds

Volume 2

• Broschiertes Buch

Produktbeschreibung

Linear chain substances span a large cross section of contemporary chemistry ranging from covalent polymers, to organic charge transfer com plexes to nonstoichiometric transition metal coordination complexes. Their commonality, which coalesced intense interest in the theoretical and exper imental solid state physics/chemistry communities, was based on the obser vation that these inorganic and organic polymeric substrates exhibit striking metal-like elec,trical and optical properties. Exploitation and extension of these systems has led to the systematic study of both the chemistry and physics of highly and poorly conducting linear chain substances. To gain a salient understanding of these complex materials rich in anomalous aniso tropic electrical, optical, magnetic, and mechanical properties, the conver gence of diverse skills and talents was required. The constructive blending of traditionally segregated disciplines such as synthetic and physical organic, inorganic, and polymer chemistry, crystallography, and theoretical and ex perimental solid state physics has led to the timely development of a truly interdisciplinary science. This is evidenced in the contributions of this monograph series. Within the theme of Extended Linear Chain Compounds, experts in important, but varied, facets of the discipline have reflected upon the progress that has been made and have cogently summarized their field of speciality. Consequently, up-to-date reviews of numerous and varied aspects of "extended linear chain compounds" have developed. Within these vol umes, numerous incisive contributions covering all aspects of the diverse linear chain substances have been summarized.

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Produktdetails

• Verlag: Springer / Springer US / Springer, Berlin
• Artikelnr. des Verlages: 978-1-4684-3934-2
• 1982
• Seitenzahl: 536
• Erscheinungstermin: 22. März 2012
• Englisch
• Abmessung: 229mm x 152mm x 29mm
• Gewicht: 767g
• ISBN-13: 9781468439342
• ISBN-10: 1468439340
• Artikelnr.: 41326510

Inhaltsangabe

1. An Added Dimension-Two-Dimensional Analogs of One-Dimensional Materials.- 1. Introduction-General Considerations.- 2. Carbon and Other Elemental Phases.- 3. Transition Metal Dichalcogenides and Trichalcogenides.- 4. Phosphates, Phosphonates, and Phosphinates.- 5. Silicates, Clays, and Related Substances.- 6. Metal Halides, Oxyhalides, and Related Compositions.- 7. Metal Cyanide, Macrocyclic, and Related Coordination Compounds.- 8. New Directions and Conclusions.- Notation.- Addendum.- References.- 2. The Electronic Structure of Semiconducting Polymers.- 1. Introduction.- 2. Electronic Excitations: Measurements and Concepts.- 3. The Molecular Solid State.- 4. Localization and Transport.- 5. Synopsis.- Notation.- References.- 3. Band Structures of One-Dimensional Inorganic, Organic, and Polymeric Conductors.- 1. Introduction.- 2. Energy Band.- 3. Band Theory.- 4. Electron-Electron Repulsion and Orbital Occupancy.- 5. Band Structures of Some Conducting Polymer Chains.- 6. Concluding Remarks.- Notation.- References.- 4. Quasi-One-Dimensional Conductors: The Peierls Instability, Pressure and Fluctuation Effects.- 1. Introduction.- 2. Phase transitions.- 3. Phase Transitions: Theoretical Treatment.- 4. Commensurate CDW State under Pressure.- 5. Fluctuations in Quasi-One-Dimensional Conductors.- 6. Fröhlich Fluctuation Conductivity.- 7. Single-Particle versus Fluctuating Conductivity.- Notation.- References.- 5. Optical Properties of One-Dimensional Systems.- 1. Introduction.- 2. Optical Properties of Solids.- 3. The Platinum Chain Salts.- 4. Linear Chain Organic Systems.- 5. Conducting Polymers.- 6. Conclusion.- Notation.- References.- 6. Superstructures and Phase Transitions in One-Dimensional Inorganic and Organic Materials.- 1. Structural Changes and PhaseTransitions in One-Dimensional Conductors.- 2. X-Ray Diffraction Patterns of Sinusoidal Structure.- 3. 2kF Superstructures of Partially Oxidized Bis(oxalato)platinate Complexes.- 4. 4kF-2kF Transition in K1.75[Pt(CN)4]·1.5H2O, K(def)TCP.- 5. Monomer-Dimer (M-D) Transition of (Alkali Metal) (TCNQ) Complexes.- 6. Phase Transitions in N-Methyl-N-Ethylmorpholinium-bis-(7,7,8,8-tetracyano-p-quinodimethanide)(MeEtM) (TCNQ)2-A Large-U Model for 1 : 2 TCNQ Salts.- 7. High-Pressure Structures and Phase Transitions in K2[Pt(CN)4]Br0.3·3H2O, KCP(Br).- Notation.- References.- 7. X-ray, Neutron, and Electron Scattering Studies of One-Dimensional Inorganic and Organic Conductors.- 1. Introduction.- 2. Structural Results in K2Pt(CN)4Br0.3·3H2O.- 3. Organic Solids-7,7,8,8-Tetracyano-p-quinodimethane (TCNQ) Charge Transfer Salts.- 4. Structural Results in MX3 (M = Ta, Nb; X = S, Se).- 5. Concluding Remarks.- Notation.- References.- 8. Photoconductive Properties of Organic Assemblies and a Comparison with Dark Conductors.- 1. Introduction.- 2. Some Chemical Aspects of Charge Generation and Transport.- 3. Some Qualitative Energetics of Light-Induced Charge Generation-Comparison with Dark Conductors.- 4. Three-Dimensional versus Low-Dimensional Interactions-The Importance of Surface Area.- 5. Three-Dimensionally Ordered Systems-Anthracene.- 6. Low-Dimensional Photoconductive Systems.- 7. From Excitons to Charge Carriers.- 8. Geminate Recombination.- 9. Charge Generation in Polymers.- 10. Charge Transport.- 11. Charge Transport in Polymers.- 12. Summary and Conclusions.- Notation.- References.- 9. Cation-Radical Salts of Tetrathiotetracene and Tetraselenotetracene: Synthetic Aspects and Physical Properties.- 1. Introduction.- 2. Synthesis and General Chemical and PhysicalProperties of Tetrathiotetracene (TTT) and Tetraselenotetracene (TSeT).- 3. Cation-Radical Salts of Tetrathiotetracene (TTT) and Tetraselenotetracene (TSeT) with Inorganic Anions.- 4. Complexes of Tetrathiotetracene (TIT) and Tetraselenotetracene (TSeT) with Organic and Metal-Organic Acceptors.- 5. Peierls Transition in Nonstoichiometric Series of (TTT)2 I3+? Compounds.- 6. Peierls-Type Transition in the Isostructural Salts (TSeT)2C1 and (TSeT)2Br.- Notation.- References.- 10. Structural Aspects of One-Dimensional Conductors Based on Tetrathiafulvalene and Tetrathiatetracene.- 1. Introduction.- 2. Structures of Charge Transfer Complexes Based on Tetrathiatetracene (TTT) and Tetraselenotetracene (TSeT).- 3. Structures of Charge Transfer Complexes Based on Tetrathiafulvalene (TTF).- 4. Conclusion.- Notation.- References.- 11. Metal Complexes of Tetrathiafulvalene and Related Compounds.- 1. Introduction.- 2. Characterization.- 3. Tetrathiafulvalene Salts.- 4. Derivatives of Neutral Tetrathiafulvalene.- 5. Complexes with Metal-Sulfur Bonds.- 6. Metal-Tetrathialene Complexes.- 7. Bis(dithiolene) Metal-Thiacarbon Complexes.- Notation.- References.