Comprehensive coverage of the fabrication of nanomaterials from a chemical engineering perspective This practical chemical engineering textbook serves as an in-depth introduction to the synthesis, characterization, and functionalization of nanomaterials using solution-based methods. Written by a recognized expert in the field, the book combines theoretical fundamentals with experimental results. You will explore specific applications, including targeted drug delivery, hydrological tracing, water purification, and catalysis. Fabrication and Application of Nanomaterials offers clear explanations…mehr
Comprehensive coverage of the fabrication of nanomaterials from a chemical engineering perspective This practical chemical engineering textbook serves as an in-depth introduction to the synthesis, characterization, and functionalization of nanomaterials using solution-based methods. Written by a recognized expert in the field, the book combines theoretical fundamentals with experimental results. You will explore specific applications, including targeted drug delivery, hydrological tracing, water purification, and catalysis. Fabrication and Application of Nanomaterials offers clear explanations and illustrates physio-chemical properties through state-of-the-art techniques, both in situ and post modifications. You will master the techniques for synthesis and applications of fabricated nanomaterials through concise theory, numerical problems, and recent case studies from industry and academia. .This is the first graduate-level textbook to teach the fabrication of nanomaterials from a chemical engineering perspective .Presented in a multidisciplinary format that allows instructors to tailor a course for study .Written by a recognized expert and chemical engineering academicHinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Sulalit Bandyopadhyay earned a Ph.D. and M.Sc. in chemical engineering from the Norwegian University of Science and Technology (NTNU). He is a post-doctoral researcher in the Department of Chemical Engineering at NTNU and a visiting researcher at TU Delft and IHE Delft Institute for Water Education. He has been actively teaching chemical engineering courses at the graduate and post-graduate levels at NTNU since 2013. Dr. Bandyopadhyay's research interests include synthesis, characterization, and functionalization of nanoparticles; development of nanoparticle-based hydrological tracers; drug delivery; modeling of nanosystems; and recycling of Li-ion batteries.
Inhaltsangabe
About the Author Contents Preface 1 Introduction 1.1 Importance of Nanoscale 1.2 Inorganic Nanoparticles 1.2.1 Plasmonic Nanoparticles 1.2.2 Magnetic Nanoparticles 1.3 Organic Nanoparticles 1.4 Synthesis 1.4.1 Top-Down Synthesis 1.4.2 Bottom-Up Synthesis 1.5 Functionalization 1.6 Characterization 1.7 Applications 1.8 Study Questions 1.9 References 2 Nucleation 2.1 Classical Nucleation Theory 2.1.1 Activity-Based Supersaturation 2.1.2 Primary Nucleation 2.1.3 Nucleation Rate 2.1.4 Phase Stability and Phase Transitions 2.2 Alternative Nucleation Hypotheses 2.3 Concluding Remarks 2.4 Study Questions 2.4.1 Concept-Based Questions 2.4.2 Research-Based Questions 2.5 References 3 Crystal Growth 3.1 Classical Theory of Crystal Growth 3.2 Experimental Determination of Growth Rates 3.2.1 Seeded Batch Experiments 3.2.2 Seeded Constant Composition Experiments 3.3 Crystal Size and Size Distribution 3.4 Crystal Morphology 3.5 Concluding Remarks 3.6 Study Questions 3.6.1 Concept-Based Questions 3.6.2 Research-Based Questions 3.7 References 4 Synthesis of Metal Nanoparticles 4.1 Reduction of Metal Precursors in Solution 4.1.1 Mechanism 4.1.2 Parameters Influencing Nucleation and Growth 4.1.3 Examples of Metallic Precursor Reduction in Solution 4.2 Colloidal Templating: Reverse Micelles as Spherical Nanoreactors 4.3 Sol-Gel Method 4.4 One-Pot Synthesis Methods: Globular Proteins, Viruses, and Microorganisms 4.5 Nucleotide-Mediated Synthesis of Metal Nanoparticles 4.6 Natural Selection of Biomolecules Capable of Nanoparticle Formation 4.7 Seeded Growth of Gold Nanostructures 4.7.1 Under-Potential Deposition 4.7.2 Face-Specific Capping 4.7.3 Surfactant Templating 4.8 Study Questions 4.8.1 Concept-Based Questions 4.8.2 Research-Based Questions 4.9 References 5 Functionalization of Metal Nanoparticles 5.1 In Situ Functionalization 5.2 Post-Synthesis Functionalization 5.3 Langmuir Adsorption 5.3.1 Theoretical Basis 5.3.2 Assumptions, Caveats, and Validity 5.3.3 Macromolecular Adsorption 5.3.4 Protein Adsorption 5.3.5 Quartz Crystal Microbalance for Studying Adsorption 5.4 Study Questions 5.4.1 Concept-Based Questions 5.4.2 Research-Based Questions 5.5 References 6 Synthesis of Polymer-Based Nanoparticles 6.1 Classification of Polymer-Based Nanoparticles 6.1.1 Morphology 6.1.2 Hydrophilicity 6.1.3 Charge 6.1.4 Preparation Techniques 6.1.5 Phase-Based Classification 6.1.6 Mode/Type-Based Classification 6.1.7 Examples of Polymer-Based Nanoparticles: pNIPAm-Based Systems 6.2 Stimuli-Sensitive Hydrogels 6.3 Study Questions 6.3.1 Concept-Based Questions 6.3.2 Research-Based Questions 6.4 References 7 Functionalization and Properties of Hydrogels 7.1 Functionalization 7.1.1 In Situ Functionalization 7.1.2 Post-Synthesis Functionalization 7.2 Properties of Hydrogels 7.2.1 Size 7.2.2 Swelling Collapse 7.2.3 Optical Properties 7.2.4 Water Content 7.2.5 Mechanical Properties 7.3 Study Questions 7.3.1 Concept-Based Questions 7.3.2 Research-Based Question 7.4 References 8 Characterization of Metal Nanoparticles 8.1 Optical Properties 8.1.1 Scattering and Absorption 8.1.2 Localized Surface Plasmon Resonance 8.1.3 UV-Vis Spectroscopy 8.2 Dynamic Light Scattering 8.2.1 Theory 8.2.2 Autocorrelation Function 8.2.3 Stokes-Einstein Equation 8.3 Differential Scanning Calorimetry 8.3.1 Mathematical Background 8.3.2 Modulated Differential Scanning Calorimetry 8.4 Scanning Transmission Electron Microscopy 8.5 Fourier Transform Infrared Spectroscopy 8.6 X-ray Photoelectron Spectroscopy 8.7 Study Questions 8.7.1 Concept-Based Questions 8.7.2 Research-Based Questions 8.8 References 9 Applications in Catalysis 9.1 Introduction 9.1.1 Brief Introduction to Heterogeneous Catalysis 9.1.2 Adsorption 9.2 Nanoporous Materials-Catalyst Supports and Active Materials 9.2.1 Oxide Supports 9.2.2 Alumina and Silica 9.2.3 Zeolites and Zeotype Materials 9.3 Carbon Materials 9.4 Metal Particles 9.5 Summary and Further Reading 9.6 Study Questions 9.6.1 Concept-Based Questions 9.6.2 Research-Based Questions 9.7 References 10 Applications in Drug Delivery and Biomedicine 10.1 Drug Delivery 10.1.1 Passive Targeting 10.1.2 Active Targeting 10.1.3 Loading and Encapsulation 10.1.4 Drug Release and Mathematical Models 10.2 Magnetic Resonance Imaging 10.2.1 Fundamentals of Magnetic Resonance Imaging 10.2.2 Nanoparticle Contrast Agents for Magnetic Resonance Imaging 10.3 Biosensing 10.4 Study Questions 10.4.1 Concept-Based Questions 10.4.2 Research-Based Questions 10.5 References 11 Applications in Water Management 11.1 Wastewater Treatment 11.1.1 Adsorption 11.1.2 Membrane Separation 11.2 Hydrological Tracers in Water Management 11.2.1 Potential of Covered DNA Tracers: Case Studies 11.2.2 Colloidal Forces Governing Particle-Surface and Particle-Particle Contact 11.2.3 Colloid Filtration and Mechanistic Prediction of Retention 11.2.4 Continuum-Scale Transport Models 11.2.5 Transport of DNA Tracers in Surface Water 11.2.6 Challenges 11.3 Study Questions 11.3.1 Concept-Based Questions 11.3.2 Research-Based Questions 11.4 References 12 Applications in Energy Harvesting 12.1 Harvesting Energy from Heat 12.1.1 Overview 12.1.2 Nanomaterials for Heat Energy Harvesting 12.2 Photovoltaics 12.2.1 Overview 12.2.2 Nanomaterials for Photovoltaics 12.3 Mechanical Energy Harvesting 12.3.1 Overview 12.3.2 Nanomaterials for Mechanical Energy Harvesting 12.4 Magnetic Energy Harvesting 12.4.1 Overview 12.4.2 Magnetic Nanomaterials 12.5 Summary 12.6 Study Questions 12.7 References Index
