Handbook of Fluoropolymer Science and Technology
Ed. by Smith, Dennis W.; Iacono, Scott T.; Iyer, Suresh S.
Handbook of Fluoropolymer Science and Technology
Ed. by Smith, Dennis W.; Iacono, Scott T.; Iyer, Suresh S.
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Fluoropolymers continue to enable new materials and technologies as a result of their remarkable properties. This book reviews fluoropolymer platforms of established commercial interest, as well as recently discovered methods for the preparation and processing of new fluorinated materials. It covers the research and development of fluoropolymer synthesis, characterization, and processing. Emphasis is placed on emerging technologies in optics, space exploration, fuel cells, microelectronics, gas separation membranes, biomedical instrumentation, and much more. In addition, the book covers the…mehr
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Fluoropolymers continue to enable new materials and technologies as a result of their remarkable properties. This book reviews fluoropolymer platforms of established commercial interest, as well as recently discovered methods for the preparation and processing of new fluorinated materials. It covers the research and development of fluoropolymer synthesis, characterization, and processing. Emphasis is placed on emerging technologies in optics, space exploration, fuel cells, microelectronics, gas separation membranes, biomedical instrumentation, and much more. In addition, the book covers the current environmental concerns associated with fluoropolymers, as well as relevant regulations and potential growth opportunities. Concepts, studies, and new discoveries are taken from leading international laboratories, including academia, government, and industrial institutions.
Produktdetails
- Produktdetails
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 672
- Erscheinungstermin: 27. Mai 2014
- Englisch
- Abmessung: 240mm x 161mm x 40mm
- Gewicht: 1055g
- ISBN-13: 9780470079935
- ISBN-10: 0470079932
- Artikelnr.: 26646768
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 672
- Erscheinungstermin: 27. Mai 2014
- Englisch
- Abmessung: 240mm x 161mm x 40mm
- Gewicht: 1055g
- ISBN-13: 9780470079935
- ISBN-10: 0470079932
- Artikelnr.: 26646768
DENNIS W. SMITH JR. is a Professor of Chemistry at The University of Texas at Dallas, Texas. Previously, he was at The Dow Chemical Company Central Research Laboratory and worked in synthesis and characterization. His research interests include synthesis, mechanism, structure/property relationships, and applications of polymer materials and composites. SCOTT T. IACONO is an Associate Professor of Chemistry and concurrently serves as the Chemistry Research Center Director at US Air Force Academy. His research focuses on organofluorine methodologies for monomer development for fluorosiloxane polymers, metalized fluoropolymer composites, and fulvene-based conjugated polymers for light emissive applications. SURESH S. IYER is a Technical Manager at the 3M Safety & Graphics business lab, 3M India Ltd. His research interests include high performance polymers, functional coatings and low surface energy materials.
Foreword ix Patrick E. Cassidy In Memoriam xi Preface xiii Contributors xv About the Editors xxi 1 Fluorinated Polyphosphazenes 1 Harry R. Allcock 2 Mn2 (CO)10-Visible Light Photomediated
Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof 21 Alexandru D. Asandei
Olumide I. Adebolu
and Christopher P. Simpson 3 Interfacial Response of Semifluorinated Multi-block Copolymers 43 Anupriya Agrawal
Dipak Aryal
Dvora Perahia
and Gary S. Grest 4 Fluoropolymer Nanocomposites 57 Hideo Sawada 5 Thermal Degradation and Pyrolysis of Polytetrafluoroethylene 81 Gerard Puts
Philip Crouse
and Bruno Ameduri 6 Molecular Simulation of Fluoropolymers 105 Armand Soldera
Francois Porzio
and Nasim Anousheh 7 Vapor Deposition of Fluoropolymer Surfaces 131 Jose Yague and Karen K. Gleason 8 Functionalized and Functionalizable Fluoropolymer Membranes 149 Tao Cai
Koon-Gee Neoh
and En-Tang Kang 9 Poly[Methyl(3
3
3-Trifluoropropyl)Siloxane] 183 Michael J. Owen 10 Functional Fluorous Copolyoxetane Polymer Surface Modifiers 201 Kenneth J. Wynne
Pinar Kurt
Umit Makal
Tomoko Fujiwara
Kennard Brunson
Asima Chakravorty
Lynn Wood
and Dennis E. Ohman 11 Self-Organizing Semifluorinated Methacrylate Copolymers 235 Doris Pospiech and Dieter Jehnichen 12 Synthesis of Fluoropolymers Using Borane-Mediated Control Radical Polymerization for Energy Storage Applications 291 T.C. Mike Chung 13 Fluoropolymers in Supercritical Carbon Dioxide: Phase Behavior
Self-Assembly
and Stabilization of Water/CO2 Emulsions 315 Etienne Girard
Jean-Daniel Marty
and Mathias Destarac 14 Semifluorinated Polymers from Trifluorovinyl Aromatic Ether Monomers 343 Jianyong Jin
Scott T. Iacono
and Dennis W. Smith Jr. 15 Combustion Characterization of Energetic Fluoropolymer Composites 363 Oliver Mulamba and Michelle Pantoya 16 Amorphous Perfluoropolymers 377 Yoshiyuki Okamoto
Frantisek Mikes
Kotaro Koike
and Yasuhiro Koike 17 Fluoropolymers for Sustainable Energy 393 Vincenzo Arcella
Luca Merlo
Riccardo Pieri
Paolo Toniolo
Francesco Triulzi
and Marco Apostolo 18 Evolution of Academic Barricades for the Use of Tetrafluoroethylene (TFE) in the Preparation of Fluoropolymers 413 Daniel A. Hercules
Darryl D. DesMarteau
Richard E. Fernandez
James L. Clark Jr.
and Joseph S. Thrasher 19 Fluoropolymer Surfaces/Interfaces 433 Yuji Higaki
Ryohei Ishige
and Atsushi Takahara 20 Fluoropolymer Dielectrics 451 Mustapha Raihane and Bruno Ameduri 21 Fluoropolymers--Environmental Aspects 495 Klaus Hintzer and Werner Schwertfeger 22 Fluorinated Ionomers and Ionomer Membranes Containing the bis[(perfluoroalkyl) sulfonyl]imide Protogenic Group 521 Iqbal Sharif
Stephen Creager
and Darryl D. DesMarteau 23 Fluorinated Silsesquioxanes 545 Sean Ramirez and Joseph Mabry 24 Multidimensional NMR of Fluoropolymers 565 Xiaohong Li
Jessi Baughman
Chun Gao
Linlin Li
Peter L. Rinaldi
Eric B. Twum
Elizabeth F. McCord
and Faith J. Wyzgoski 25 Melt Processible Perfluoroplastics for Demanding Applications 599 Paul Brothers
Gregory Chapman
Kimberly Farnsworth
and Richard Morgan Index 623
Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof 21 Alexandru D. Asandei
Olumide I. Adebolu
and Christopher P. Simpson 3 Interfacial Response of Semifluorinated Multi-block Copolymers 43 Anupriya Agrawal
Dipak Aryal
Dvora Perahia
and Gary S. Grest 4 Fluoropolymer Nanocomposites 57 Hideo Sawada 5 Thermal Degradation and Pyrolysis of Polytetrafluoroethylene 81 Gerard Puts
Philip Crouse
and Bruno Ameduri 6 Molecular Simulation of Fluoropolymers 105 Armand Soldera
Francois Porzio
and Nasim Anousheh 7 Vapor Deposition of Fluoropolymer Surfaces 131 Jose Yague and Karen K. Gleason 8 Functionalized and Functionalizable Fluoropolymer Membranes 149 Tao Cai
Koon-Gee Neoh
and En-Tang Kang 9 Poly[Methyl(3
3
3-Trifluoropropyl)Siloxane] 183 Michael J. Owen 10 Functional Fluorous Copolyoxetane Polymer Surface Modifiers 201 Kenneth J. Wynne
Pinar Kurt
Umit Makal
Tomoko Fujiwara
Kennard Brunson
Asima Chakravorty
Lynn Wood
and Dennis E. Ohman 11 Self-Organizing Semifluorinated Methacrylate Copolymers 235 Doris Pospiech and Dieter Jehnichen 12 Synthesis of Fluoropolymers Using Borane-Mediated Control Radical Polymerization for Energy Storage Applications 291 T.C. Mike Chung 13 Fluoropolymers in Supercritical Carbon Dioxide: Phase Behavior
Self-Assembly
and Stabilization of Water/CO2 Emulsions 315 Etienne Girard
Jean-Daniel Marty
and Mathias Destarac 14 Semifluorinated Polymers from Trifluorovinyl Aromatic Ether Monomers 343 Jianyong Jin
Scott T. Iacono
and Dennis W. Smith Jr. 15 Combustion Characterization of Energetic Fluoropolymer Composites 363 Oliver Mulamba and Michelle Pantoya 16 Amorphous Perfluoropolymers 377 Yoshiyuki Okamoto
Frantisek Mikes
Kotaro Koike
and Yasuhiro Koike 17 Fluoropolymers for Sustainable Energy 393 Vincenzo Arcella
Luca Merlo
Riccardo Pieri
Paolo Toniolo
Francesco Triulzi
and Marco Apostolo 18 Evolution of Academic Barricades for the Use of Tetrafluoroethylene (TFE) in the Preparation of Fluoropolymers 413 Daniel A. Hercules
Darryl D. DesMarteau
Richard E. Fernandez
James L. Clark Jr.
and Joseph S. Thrasher 19 Fluoropolymer Surfaces/Interfaces 433 Yuji Higaki
Ryohei Ishige
and Atsushi Takahara 20 Fluoropolymer Dielectrics 451 Mustapha Raihane and Bruno Ameduri 21 Fluoropolymers--Environmental Aspects 495 Klaus Hintzer and Werner Schwertfeger 22 Fluorinated Ionomers and Ionomer Membranes Containing the bis[(perfluoroalkyl) sulfonyl]imide Protogenic Group 521 Iqbal Sharif
Stephen Creager
and Darryl D. DesMarteau 23 Fluorinated Silsesquioxanes 545 Sean Ramirez and Joseph Mabry 24 Multidimensional NMR of Fluoropolymers 565 Xiaohong Li
Jessi Baughman
Chun Gao
Linlin Li
Peter L. Rinaldi
Eric B. Twum
Elizabeth F. McCord
and Faith J. Wyzgoski 25 Melt Processible Perfluoroplastics for Demanding Applications 599 Paul Brothers
Gregory Chapman
Kimberly Farnsworth
and Richard Morgan Index 623
Foreword ix Patrick E. Cassidy In Memoriam xi Preface xiii Contributors xv About the Editors xxi 1 Fluorinated Polyphosphazenes 1 Harry R. Allcock 2 Mn2 (CO)10-Visible Light Photomediated
Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof 21 Alexandru D. Asandei
Olumide I. Adebolu
and Christopher P. Simpson 3 Interfacial Response of Semifluorinated Multi-block Copolymers 43 Anupriya Agrawal
Dipak Aryal
Dvora Perahia
and Gary S. Grest 4 Fluoropolymer Nanocomposites 57 Hideo Sawada 5 Thermal Degradation and Pyrolysis of Polytetrafluoroethylene 81 Gerard Puts
Philip Crouse
and Bruno Ameduri 6 Molecular Simulation of Fluoropolymers 105 Armand Soldera
Francois Porzio
and Nasim Anousheh 7 Vapor Deposition of Fluoropolymer Surfaces 131 Jose Yague and Karen K. Gleason 8 Functionalized and Functionalizable Fluoropolymer Membranes 149 Tao Cai
Koon-Gee Neoh
and En-Tang Kang 9 Poly[Methyl(3
3
3-Trifluoropropyl)Siloxane] 183 Michael J. Owen 10 Functional Fluorous Copolyoxetane Polymer Surface Modifiers 201 Kenneth J. Wynne
Pinar Kurt
Umit Makal
Tomoko Fujiwara
Kennard Brunson
Asima Chakravorty
Lynn Wood
and Dennis E. Ohman 11 Self-Organizing Semifluorinated Methacrylate Copolymers 235 Doris Pospiech and Dieter Jehnichen 12 Synthesis of Fluoropolymers Using Borane-Mediated Control Radical Polymerization for Energy Storage Applications 291 T.C. Mike Chung 13 Fluoropolymers in Supercritical Carbon Dioxide: Phase Behavior
Self-Assembly
and Stabilization of Water/CO2 Emulsions 315 Etienne Girard
Jean-Daniel Marty
and Mathias Destarac 14 Semifluorinated Polymers from Trifluorovinyl Aromatic Ether Monomers 343 Jianyong Jin
Scott T. Iacono
and Dennis W. Smith Jr. 15 Combustion Characterization of Energetic Fluoropolymer Composites 363 Oliver Mulamba and Michelle Pantoya 16 Amorphous Perfluoropolymers 377 Yoshiyuki Okamoto
Frantisek Mikes
Kotaro Koike
and Yasuhiro Koike 17 Fluoropolymers for Sustainable Energy 393 Vincenzo Arcella
Luca Merlo
Riccardo Pieri
Paolo Toniolo
Francesco Triulzi
and Marco Apostolo 18 Evolution of Academic Barricades for the Use of Tetrafluoroethylene (TFE) in the Preparation of Fluoropolymers 413 Daniel A. Hercules
Darryl D. DesMarteau
Richard E. Fernandez
James L. Clark Jr.
and Joseph S. Thrasher 19 Fluoropolymer Surfaces/Interfaces 433 Yuji Higaki
Ryohei Ishige
and Atsushi Takahara 20 Fluoropolymer Dielectrics 451 Mustapha Raihane and Bruno Ameduri 21 Fluoropolymers--Environmental Aspects 495 Klaus Hintzer and Werner Schwertfeger 22 Fluorinated Ionomers and Ionomer Membranes Containing the bis[(perfluoroalkyl) sulfonyl]imide Protogenic Group 521 Iqbal Sharif
Stephen Creager
and Darryl D. DesMarteau 23 Fluorinated Silsesquioxanes 545 Sean Ramirez and Joseph Mabry 24 Multidimensional NMR of Fluoropolymers 565 Xiaohong Li
Jessi Baughman
Chun Gao
Linlin Li
Peter L. Rinaldi
Eric B. Twum
Elizabeth F. McCord
and Faith J. Wyzgoski 25 Melt Processible Perfluoroplastics for Demanding Applications 599 Paul Brothers
Gregory Chapman
Kimberly Farnsworth
and Richard Morgan Index 623
Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof 21 Alexandru D. Asandei
Olumide I. Adebolu
and Christopher P. Simpson 3 Interfacial Response of Semifluorinated Multi-block Copolymers 43 Anupriya Agrawal
Dipak Aryal
Dvora Perahia
and Gary S. Grest 4 Fluoropolymer Nanocomposites 57 Hideo Sawada 5 Thermal Degradation and Pyrolysis of Polytetrafluoroethylene 81 Gerard Puts
Philip Crouse
and Bruno Ameduri 6 Molecular Simulation of Fluoropolymers 105 Armand Soldera
Francois Porzio
and Nasim Anousheh 7 Vapor Deposition of Fluoropolymer Surfaces 131 Jose Yague and Karen K. Gleason 8 Functionalized and Functionalizable Fluoropolymer Membranes 149 Tao Cai
Koon-Gee Neoh
and En-Tang Kang 9 Poly[Methyl(3
3
3-Trifluoropropyl)Siloxane] 183 Michael J. Owen 10 Functional Fluorous Copolyoxetane Polymer Surface Modifiers 201 Kenneth J. Wynne
Pinar Kurt
Umit Makal
Tomoko Fujiwara
Kennard Brunson
Asima Chakravorty
Lynn Wood
and Dennis E. Ohman 11 Self-Organizing Semifluorinated Methacrylate Copolymers 235 Doris Pospiech and Dieter Jehnichen 12 Synthesis of Fluoropolymers Using Borane-Mediated Control Radical Polymerization for Energy Storage Applications 291 T.C. Mike Chung 13 Fluoropolymers in Supercritical Carbon Dioxide: Phase Behavior
Self-Assembly
and Stabilization of Water/CO2 Emulsions 315 Etienne Girard
Jean-Daniel Marty
and Mathias Destarac 14 Semifluorinated Polymers from Trifluorovinyl Aromatic Ether Monomers 343 Jianyong Jin
Scott T. Iacono
and Dennis W. Smith Jr. 15 Combustion Characterization of Energetic Fluoropolymer Composites 363 Oliver Mulamba and Michelle Pantoya 16 Amorphous Perfluoropolymers 377 Yoshiyuki Okamoto
Frantisek Mikes
Kotaro Koike
and Yasuhiro Koike 17 Fluoropolymers for Sustainable Energy 393 Vincenzo Arcella
Luca Merlo
Riccardo Pieri
Paolo Toniolo
Francesco Triulzi
and Marco Apostolo 18 Evolution of Academic Barricades for the Use of Tetrafluoroethylene (TFE) in the Preparation of Fluoropolymers 413 Daniel A. Hercules
Darryl D. DesMarteau
Richard E. Fernandez
James L. Clark Jr.
and Joseph S. Thrasher 19 Fluoropolymer Surfaces/Interfaces 433 Yuji Higaki
Ryohei Ishige
and Atsushi Takahara 20 Fluoropolymer Dielectrics 451 Mustapha Raihane and Bruno Ameduri 21 Fluoropolymers--Environmental Aspects 495 Klaus Hintzer and Werner Schwertfeger 22 Fluorinated Ionomers and Ionomer Membranes Containing the bis[(perfluoroalkyl) sulfonyl]imide Protogenic Group 521 Iqbal Sharif
Stephen Creager
and Darryl D. DesMarteau 23 Fluorinated Silsesquioxanes 545 Sean Ramirez and Joseph Mabry 24 Multidimensional NMR of Fluoropolymers 565 Xiaohong Li
Jessi Baughman
Chun Gao
Linlin Li
Peter L. Rinaldi
Eric B. Twum
Elizabeth F. McCord
and Faith J. Wyzgoski 25 Melt Processible Perfluoroplastics for Demanding Applications 599 Paul Brothers
Gregory Chapman
Kimberly Farnsworth
and Richard Morgan Index 623