Proceedings of the 27th International Conference on the Applications of the Mössbauer Effect (ICAME 2003) held in Muscat, Oman, 21¿25 September 2003 Herausgegeben:Elzain, M. E.; Yousif, A. A.; Al Rawas, A. D.; Gismelseed, A. M.
Proceedings of the 27th International Conference on the Applications of the Mössbauer Effect (ICAME 2003) held in Muscat, Oman, 21¿25 September 2003 Herausgegeben:Elzain, M. E.; Yousif, A. A.; Al Rawas, A. D.; Gismelseed, A. M.
Researchers and graduate students interested in the Mössbauer Effect and its Application will find this volume of the Hyperfine Interactions Journal indispensable. The volume presents the most recent developments in the methodology of Mössbauer spectroscopy; it covers the progress in the understanding of the more recent fields of nanoparticles, nanowires, multilayers and superlattices, surfaces and interfaces. In addition, the traditional areas of applications in physics, chemistry, biology, medicine, earth science, mineralogy, archaeology, material science, thin films, metallurgy and…mehr
Researchers and graduate students interested in the Mössbauer Effect and its Application will find this volume of the Hyperfine Interactions Journal indispensable. The volume presents the most recent developments in the methodology of Mössbauer spectroscopy; it covers the progress in the understanding of the more recent fields of nanoparticles, nanowires, multilayers and superlattices, surfaces and interfaces. In addition, the traditional areas of applications in physics, chemistry, biology, medicine, earth science, mineralogy, archaeology, material science, thin films, metallurgy and industrial applications like corrosion and catalysis are well presented. The contributions include theoretical treatments using ab initio calculations, molecular simulations as well as experimental results utilizing techniques like transmission spectroscopy, CEMS and nuclear resonance scattering.
Mössbauer Instrument Package MS-2000IP.- Nuclear Resonant Scattering of Synchrotron Radiation as a Method for Distinction between Covariant Ether Theories and Special Relativity.- Mössbauer Spectrometer with Novel Moving System and Resonant Detection of Gamma Rays.- Angular Distribution of Hyperfine Magnetic Field in Fe3O4 and Fe66Ni34 from Mössbauer Polarimetry.- Two-Dimensional Mössbauer Spectra.- 57Fe Mössbauer Study of Magnetic Nanowires.- Synthesis and Mössbauer Study of Maghemite Nanowire Arrays.- Mössbauer Characterization of Iron-Based Nanogranular Films.- Mössbauer Study of Nanocrystalline ?-Fe3?xCoxN System.- Mössbauer Studies of Nanosize CuFe2O4 Particles.- Mössbauer Studies on Nanocrystalline Diol Capped ?-Fe2O3.- Hyperfine and Structural Properties of the Mechanically Alloyed (FeMn)30Cu70 System.- 197Au Mössbauer Study of Bimetallic Nanoparticles Prepared by Sonochemical Technique.- Phase Composition and Properties of Iron Nanocrystals and Clusters Embedded in MgO Matrix.- Shifting the Superparamagnetic Limit of Nanosized Copper Iron Spinel.- Synthesis of Nanocrystalline Ni0.5Zn0.5Fe2O4 by Aerosol Route and Its Characterization.- Transitions and Spin Dynamics at Very Low Temperature in the Pyrochlores Yb2Ti2O7 and Gd2Sn2O7.- Mössbauer and Neutron Diffraction Studies on Co-Al Ferrite.- Mössbauer Studies of Fe0.7?xSi0.3Mnx Alloys.- Observation of Substitutional Fe in CEMS Measurements on Synthetic CVD Diamond.- Interaction between Interstitial Hydrogen and Fe Atoms within the ?-Hydride Phase in Nb1?yFeyHx Alloys.- First Observation of Photoinduced Magnetization for the Cyano-Bridged 3d-4f Heterobimetallic Assembly Nd(DMF)4(H2O)3(?-CN)Fe(CN)5·H2O (DMF = N,N-Dimethylformamide).- Non-Magnetic Stainless Steels Reinvestigated - a SmallEffective Field Component in External Magnetic Fields.- Magnetic Response and Hyperfine Magnetic Fields at Fe Sites of Sr3Fe2MO9 (M = Mo, Te, W, U) Double-Perovskites.- Modification of Nuclear Decay Constant in the Finite Space.- Mössbauer Studies and Magnetic Properties of Y3?xCexFe5O12.- Control of Charge Transfer Phase Transition in Iron Mixed-Valence System (n-CnH2n+1)4 N[FeIIFeIII(dto)3] (n = 3?6; dto = C2O2S2).- Mössbauer Spectroscopy Study on the Effect of Al-Cr Co-Substitution in Yttrium and Yttrium-Gadolinium Iron Garnets.- Mössbauer Study of Microstructure and Magnetic Properties (Co, Ni)-Zr Substituted Ba Ferrite Particles.- Mössbauer Studies of Dilute 119Sn and 57Fe in SrRuO3 and Sr2FeRuO6.- Mössbauer Studies on the Quasibinary System FeTe1.45-TiTe1.45.- Magnetic Properties of Iron Clusters in Silver.- Magnetic Properties of Nanocrystalline FexCu1?x Alloys Prepared by Ball Milling.- The Formation of Lithiated Ti-Doped ?-Fe2O3 Nanocrystalline Particles by Mechanical Milling of Ti-Doped Lithium Spinel Ferrite.- Effect of Mg2+ on the Magnetic Compensation of Lithium-Chromium Ferrite.- High-Pressure 57Fe Mössbauer Spectroscopy of Octamethyl-Ethynyl-Ferrocene.- 57Fe Mössbauer Spectroscopic Study of Fe-B Compounds.- Mössbauer- and EPR-Snapshots of an Enzymatic Reaction: The Cytochrome P450 Reaction Cycle.- The Effect of Biocompatible Coating Layers on Magnetic Properties of Superparamagnetic Iron Oxide Nanoparticles.- Spin States of Iron(III) in Highly Saddled Dodecaphenylporphyrin Complexes.- Mössbauer Spectroscopy of Iron Containing Vitamins and Dietary Supplements.- Comparative Study of Human Liver Ferritin and Chicken Liver by Mössbauer Spectroscopy. Preliminary Results.- Low-Spin Ferriheme Models of the Cytochromes: Correlation of MolecularStructure with EPR and Mössbauer Spectral Parameters.- Iron-Sulfur Proteins Investigated by EPR-, Mössbauer- and EXAFS-Spectroscopy.- Mössbauer Study of Lanthanum-Strontium Ferromanganite Oxides.- Iron-57 Mössbauer Spectroscopic Investigation of Manganese-Doped ?-Fe2O3.- Study on Chemical Bond and Electronic State of New Gold Mixed Valence Complexes Cs2[Au1X2][AuIIIY4] (X, Y = Cl, Br, I) by Means of 197Au Mössbauer Spectroscopy.- Magnetic Properties of TlCo2Se2 Studied by Mössbauer Spectroscopy.- Exploring the Verwey-Type Transition in GdBaFe2O5+? Using 57Fe Mössbauer Spectroscopy.- First Principles Calculations of Mössbauer Spectra of Intermetallic Anodes for Lithium-Ion Batteries.- 57Fe Mössbauer Spectroscopy Study of LaFe1?xCoxO3 (x = 0 and 0.5) Formed by Mechanical Milling.- A Crystallographic and Mössbauer Spectroscopic Study of BaCo0.5xZn0.5xTix Fe12?2xO19 (M-Type Hexagonal Ferrite).- Laboratory Intercomparison on the Determination of the Fe(II)/Fe(III) Ratio in Glass Using Mössbauer Spectroscopy.- 57Fe Mössbauer Spectroscopic Study on the Assembled Iron Complexes.- 155Gd Mössbauer Isomer Shifts and Quadrupole Coupling Constants of Gadolinium Complexes.- Mössbauer Spectroscopy in the Characterisation of Polymetallic Cluster Compounds: a Triple Mössbauer Study of (PPh4)[Fe2Ir2(CO)12{?3-Au(PPh3)}].- The Nonanuclear [Mo(IV){(CN)Fe(III)(3-ethoxysaldptn)}8]Cl4 Complex Compound Exhibits Multiple Spin Transitions Observed by Mössbauer Spectroscopy.- Processes in Geophysics Studied by Mössbauer Spectroscopy.- High Pressure Mössbauer Studies on FCC Fe53Ni47 Alloy.- Mössbauer and XRD Comparative Study of Host Rock and Iron Rich Mineral Samples from Paz del Rio Iron Ore Mineral Mine in Colombia.- Characterization and Thermal Behaviour of Garnetsfrom Almandine-Pyrope Series at 1200°C.- Mössbauer Study of Magnetite Formation by Iron- and Sulfate-Reducing Bacteria.- What Oxidation State of Iron Determines the Amethyst Colour?.- Fe-Hydroxysulphates from Bacterial Fe2+ Oxidation.- Mössbauer Spectroscopic Study of a Mural Painting from Morgadal Grande, Mexico.- Quantification of Secondary Fe-Phases Formed During Sorption Experiments on Chlorites.- Synthesis by Coprecipitation of Al-Substituted Hydroxysulphate Green Rust Fe4IIFe(2?y)IIIAlyIII(OH)12SO4, nH2O.- Mössbauer Study of Ancient Albanian Ceramics.- Variation of Some Physical Properties of Brownmillerite Doped with a Transition Metal Oxide.- Iron-Containing Adsorbents in Great Nile Sediments.- Fe(II-III) Hydroxysalt Green Rusts; from Corrosion to Mineralogy and Abiotic to Biotic Reactions by Mössbauer Spectroscopy.- Identification of Corrosion Products Due to Seawater and Fresh Water.- Atmospheric Corrosion on Steel Studied by Conversion Electron Mössbauer Spectroscopy.- Mössbauer Spectrometry as a Powerful Tool to Study Lithium Reactivity Mechanisms for Battery Electrode Materials.- Arrangements of Interstitial Atoms in fcc Fe-C and Fe-N Solid Solutions.- A Dilute-Limit Heat of Solution of 3d Transition Metals in Iron Studied with 57Fe Mössbauer Spectroscopy.- Distribution of N Atoms in the fcc Fe-N Interstitial Solid Solution.- Distribution of Mn Atoms in a Substitutional bcc-FeMn Solid Solution.- Effect of Sulfur Addition on the Redox State of Iron in Iron Phosphate Glasses.- Structural and Electronic Features of Sb-Based Electrode Materials: 121Sb Mössbauer Spectrometry.- Study of Disordered Fe2Cr(1?x)MnxAl Alloys.- Mössbauer and X-ray Study of Fe1?xAlx, 0.2 ? x ? 0.5, Samples Produced by Mechanical Alloying.- Investigation of SteelSurfaces Treated by a Hybrid Ion Implantation Technique.- Ferromagnetic Planar Nanocomposites.- Surface and Interface Investigations by Nuclear Resonant Scattering with Standing Waves.- Nuclear Resonant Reflectivity Investigations of a Thin Magnetic 57Fe Layer Adjacent to a Superconducting V Layer.- CEMS Investigations of Swift Heavy Ion Irradiation Effects in Tb/Fe Multilayers.- Thermally Induced Processes of Intermetalloid Phase Formation in Laminar Systems Fe-Sn.- DCEMS Study of Thin Oxide Layers and Interface of Stainless Steel Films Deposited by Sputtering Austenitic AISI304.- CEMS Study on Fe Films Deposited by Laser Ablation.- The Investigation of the Magnetic Properties of Metallic Multilayers by Angle Dependent Mössbauer Spectroscopy.- Concluding Remarks.- Author Index.
Mössbauer Instrument Package MS-2000IP.- Nuclear Resonant Scattering of Synchrotron Radiation as a Method for Distinction between Covariant Ether Theories and Special Relativity.- Mössbauer Spectrometer with Novel Moving System and Resonant Detection of Gamma Rays.- Angular Distribution of Hyperfine Magnetic Field in Fe3O4 and Fe66Ni34 from Mössbauer Polarimetry.- Two-Dimensional Mössbauer Spectra.- 57Fe Mössbauer Study of Magnetic Nanowires.- Synthesis and Mössbauer Study of Maghemite Nanowire Arrays.- Mössbauer Characterization of Iron-Based Nanogranular Films.- Mössbauer Study of Nanocrystalline ?-Fe3?xCoxN System.- Mössbauer Studies of Nanosize CuFe2O4 Particles.- Mössbauer Studies on Nanocrystalline Diol Capped ?-Fe2O3.- Hyperfine and Structural Properties of the Mechanically Alloyed (FeMn)30Cu70 System.- 197Au Mössbauer Study of Bimetallic Nanoparticles Prepared by Sonochemical Technique.- Phase Composition and Properties of Iron Nanocrystals and Clusters Embedded in MgO Matrix.- Shifting the Superparamagnetic Limit of Nanosized Copper Iron Spinel.- Synthesis of Nanocrystalline Ni0.5Zn0.5Fe2O4 by Aerosol Route and Its Characterization.- Transitions and Spin Dynamics at Very Low Temperature in the Pyrochlores Yb2Ti2O7 and Gd2Sn2O7.- Mössbauer and Neutron Diffraction Studies on Co-Al Ferrite.- Mössbauer Studies of Fe0.7?xSi0.3Mnx Alloys.- Observation of Substitutional Fe in CEMS Measurements on Synthetic CVD Diamond.- Interaction between Interstitial Hydrogen and Fe Atoms within the ?-Hydride Phase in Nb1?yFeyHx Alloys.- First Observation of Photoinduced Magnetization for the Cyano-Bridged 3d-4f Heterobimetallic Assembly Nd(DMF)4(H2O)3(?-CN)Fe(CN)5·H2O (DMF = N,N-Dimethylformamide).- Non-Magnetic Stainless Steels Reinvestigated - a SmallEffective Field Component in External Magnetic Fields.- Magnetic Response and Hyperfine Magnetic Fields at Fe Sites of Sr3Fe2MO9 (M = Mo, Te, W, U) Double-Perovskites.- Modification of Nuclear Decay Constant in the Finite Space.- Mössbauer Studies and Magnetic Properties of Y3?xCexFe5O12.- Control of Charge Transfer Phase Transition in Iron Mixed-Valence System (n-CnH2n+1)4 N[FeIIFeIII(dto)3] (n = 3?6; dto = C2O2S2).- Mössbauer Spectroscopy Study on the Effect of Al-Cr Co-Substitution in Yttrium and Yttrium-Gadolinium Iron Garnets.- Mössbauer Study of Microstructure and Magnetic Properties (Co, Ni)-Zr Substituted Ba Ferrite Particles.- Mössbauer Studies of Dilute 119Sn and 57Fe in SrRuO3 and Sr2FeRuO6.- Mössbauer Studies on the Quasibinary System FeTe1.45-TiTe1.45.- Magnetic Properties of Iron Clusters in Silver.- Magnetic Properties of Nanocrystalline FexCu1?x Alloys Prepared by Ball Milling.- The Formation of Lithiated Ti-Doped ?-Fe2O3 Nanocrystalline Particles by Mechanical Milling of Ti-Doped Lithium Spinel Ferrite.- Effect of Mg2+ on the Magnetic Compensation of Lithium-Chromium Ferrite.- High-Pressure 57Fe Mössbauer Spectroscopy of Octamethyl-Ethynyl-Ferrocene.- 57Fe Mössbauer Spectroscopic Study of Fe-B Compounds.- Mössbauer- and EPR-Snapshots of an Enzymatic Reaction: The Cytochrome P450 Reaction Cycle.- The Effect of Biocompatible Coating Layers on Magnetic Properties of Superparamagnetic Iron Oxide Nanoparticles.- Spin States of Iron(III) in Highly Saddled Dodecaphenylporphyrin Complexes.- Mössbauer Spectroscopy of Iron Containing Vitamins and Dietary Supplements.- Comparative Study of Human Liver Ferritin and Chicken Liver by Mössbauer Spectroscopy. Preliminary Results.- Low-Spin Ferriheme Models of the Cytochromes: Correlation of MolecularStructure with EPR and Mössbauer Spectral Parameters.- Iron-Sulfur Proteins Investigated by EPR-, Mössbauer- and EXAFS-Spectroscopy.- Mössbauer Study of Lanthanum-Strontium Ferromanganite Oxides.- Iron-57 Mössbauer Spectroscopic Investigation of Manganese-Doped ?-Fe2O3.- Study on Chemical Bond and Electronic State of New Gold Mixed Valence Complexes Cs2[Au1X2][AuIIIY4] (X, Y = Cl, Br, I) by Means of 197Au Mössbauer Spectroscopy.- Magnetic Properties of TlCo2Se2 Studied by Mössbauer Spectroscopy.- Exploring the Verwey-Type Transition in GdBaFe2O5+? Using 57Fe Mössbauer Spectroscopy.- First Principles Calculations of Mössbauer Spectra of Intermetallic Anodes for Lithium-Ion Batteries.- 57Fe Mössbauer Spectroscopy Study of LaFe1?xCoxO3 (x = 0 and 0.5) Formed by Mechanical Milling.- A Crystallographic and Mössbauer Spectroscopic Study of BaCo0.5xZn0.5xTix Fe12?2xO19 (M-Type Hexagonal Ferrite).- Laboratory Intercomparison on the Determination of the Fe(II)/Fe(III) Ratio in Glass Using Mössbauer Spectroscopy.- 57Fe Mössbauer Spectroscopic Study on the Assembled Iron Complexes.- 155Gd Mössbauer Isomer Shifts and Quadrupole Coupling Constants of Gadolinium Complexes.- Mössbauer Spectroscopy in the Characterisation of Polymetallic Cluster Compounds: a Triple Mössbauer Study of (PPh4)[Fe2Ir2(CO)12{?3-Au(PPh3)}].- The Nonanuclear [Mo(IV){(CN)Fe(III)(3-ethoxysaldptn)}8]Cl4 Complex Compound Exhibits Multiple Spin Transitions Observed by Mössbauer Spectroscopy.- Processes in Geophysics Studied by Mössbauer Spectroscopy.- High Pressure Mössbauer Studies on FCC Fe53Ni47 Alloy.- Mössbauer and XRD Comparative Study of Host Rock and Iron Rich Mineral Samples from Paz del Rio Iron Ore Mineral Mine in Colombia.- Characterization and Thermal Behaviour of Garnetsfrom Almandine-Pyrope Series at 1200°C.- Mössbauer Study of Magnetite Formation by Iron- and Sulfate-Reducing Bacteria.- What Oxidation State of Iron Determines the Amethyst Colour?.- Fe-Hydroxysulphates from Bacterial Fe2+ Oxidation.- Mössbauer Spectroscopic Study of a Mural Painting from Morgadal Grande, Mexico.- Quantification of Secondary Fe-Phases Formed During Sorption Experiments on Chlorites.- Synthesis by Coprecipitation of Al-Substituted Hydroxysulphate Green Rust Fe4IIFe(2?y)IIIAlyIII(OH)12SO4, nH2O.- Mössbauer Study of Ancient Albanian Ceramics.- Variation of Some Physical Properties of Brownmillerite Doped with a Transition Metal Oxide.- Iron-Containing Adsorbents in Great Nile Sediments.- Fe(II-III) Hydroxysalt Green Rusts; from Corrosion to Mineralogy and Abiotic to Biotic Reactions by Mössbauer Spectroscopy.- Identification of Corrosion Products Due to Seawater and Fresh Water.- Atmospheric Corrosion on Steel Studied by Conversion Electron Mössbauer Spectroscopy.- Mössbauer Spectrometry as a Powerful Tool to Study Lithium Reactivity Mechanisms for Battery Electrode Materials.- Arrangements of Interstitial Atoms in fcc Fe-C and Fe-N Solid Solutions.- A Dilute-Limit Heat of Solution of 3d Transition Metals in Iron Studied with 57Fe Mössbauer Spectroscopy.- Distribution of N Atoms in the fcc Fe-N Interstitial Solid Solution.- Distribution of Mn Atoms in a Substitutional bcc-FeMn Solid Solution.- Effect of Sulfur Addition on the Redox State of Iron in Iron Phosphate Glasses.- Structural and Electronic Features of Sb-Based Electrode Materials: 121Sb Mössbauer Spectrometry.- Study of Disordered Fe2Cr(1?x)MnxAl Alloys.- Mössbauer and X-ray Study of Fe1?xAlx, 0.2 ? x ? 0.5, Samples Produced by Mechanical Alloying.- Investigation of SteelSurfaces Treated by a Hybrid Ion Implantation Technique.- Ferromagnetic Planar Nanocomposites.- Surface and Interface Investigations by Nuclear Resonant Scattering with Standing Waves.- Nuclear Resonant Reflectivity Investigations of a Thin Magnetic 57Fe Layer Adjacent to a Superconducting V Layer.- CEMS Investigations of Swift Heavy Ion Irradiation Effects in Tb/Fe Multilayers.- Thermally Induced Processes of Intermetalloid Phase Formation in Laminar Systems Fe-Sn.- DCEMS Study of Thin Oxide Layers and Interface of Stainless Steel Films Deposited by Sputtering Austenitic AISI304.- CEMS Study on Fe Films Deposited by Laser Ablation.- The Investigation of the Magnetic Properties of Metallic Multilayers by Angle Dependent Mössbauer Spectroscopy.- Concluding Remarks.- Author Index.
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