Mai Sebastian

Interfacial properties of LiS battery anodes in presence of additives

A EIS and XPS study on the formation and development of the SEI on Li anodes in LiS systems

• Broschiertes Buch

Produktbeschreibung

The influence of additives and salt concentration on the lithium anode solid electrolyte interface(SEI)in lithium sulfursystem wasinvestigated. Thecharacterization wasperformed by galvanostatic cycling (GSC), symmetric electrochemical impedance spectroscopy (EIS) and x-ray photoelectron spectroscopy (XPS). The obtained results from galvanostatic cycling, SEI composition and electrochemical parameters were successfully combined to correlate chemical changes in the composition of the SEI. The distribution of SEI layer components and LiS cell performance are influenced by increased LiTFSI concentration, the presence of lithium nitrate (LiNO 3 ), butyl-metyl-pyrrolidinium trifluorosulforylimide ([BMP][TFSI]) and lithium polysulfides. The results show, that the combination of LiNO 3 , polysulfides and higher salt concentration can increase the Coulombic efficiency as well as cycling life of LiS systems significantly.The developed methodology can be applied as a systematic approach to evaluate LiS cell components and cycling performance for efficient iteration of LiS cell chemistry.

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Produktdetails

• Verlag: AV Akademikerverlag
• Seitenzahl: 112
• Erscheinungstermin: 11. Oktober 2017
• Englisch
• Abmessung: 220mm x 150mm x 7mm
• Gewicht: 185g
• ISBN-13: 9786202204033
• ISBN-10: 6202204036
• Artikelnr.: 56610878

Autorenporträt

Sebastian Mai finished his Bachelor of Science in Chemistry 2012 at the HHU-Düsseldorf, Germany. He acquired a Master of Science in Elektrochemie und Galvanotechnik (electrochemistry and galvanotechnology) 2017 at TU-Ilmenau.