This volume contains the papers presented at the Sixth International Ion Exchange Conference organised by the SCI and held at Churchill College, Cambridge, UK, in July 1992. As on previous occasions, most recently in 1988, the organising committee did not engage plenary speakers but decided to solicit state-of-the-art contributions from the ion exchange community. This book contains the refereed papers presented at the meeting, whether in poster or oral form. Extra papers were presented at the meeting as posters because they were not available in time for refereeing purposes. The subject…mehr
This volume contains the papers presented at the Sixth International Ion Exchange Conference organised by the SCI and held at Churchill College, Cambridge, UK, in July 1992. As on previous occasions, most recently in 1988, the organising committee did not engage plenary speakers but decided to solicit state-of-the-art contributions from the ion exchange community. This book contains the refereed papers presented at the meeting, whether in poster or oral form. Extra papers were presented at the meeting as posters because they were not available in time for refereeing purposes. The subject matter of the meeting and therefore the contents of the book is subdivided into seven separate topic areas as follows: resin developments; water treatment; fundamentals; biotechnology, food and pharmaceuticals; environmental and pollution control; membranes, inorganic materials and nuclear; and hydrometallurgy. The coverage of the meeting is similar to 1988 although there are fewer subdivisions on this occasion. The more restricted coverage this time reflects the smaller number of papers offered by authors. This is probably due to the world wide industrial recession which has affected commercial development and exploitation of the technology and restricts the ability of practitioners and academics to contribute to and attend international meetings. Nevertheless, the advances in biotechnology, growing concern about the environment and the. need for novel separation processes have provided sufficient impetus to stimulate a sufficient number of workers in the field.
Design of Polymeric Adsorbents for Food and Chemical Processing.- Comb-Like Polyethylene Oxide Polymers as Chelating Agents for Mercuric (II) Chloride: Study of the Complex Formation by Solid-State 1H-NMR.- Preparation of Chelating Hollow Fibers Based on Chlorosulfonated Polyethylene and its Uses for Metal Extraction.- Preparation and Chromate Selectivity of Weakly Basic Ion Exchangers Based on Macroporous Polyacrylonitrile.- Comparison of Strong Base Resin Types.- Nitrate Removal from Water: The Effect of Structure on the Performance of Anion Exchange Resins.- Development of Exxchange, A Continuous Ion Exchange Process Using Powdered Resins and Cross-Flow Filtration.- Operating Experience with Different Weak Base Anion Resins in the Following Configuration: WAC-WBA-SAC-Degas-SBA.- The Properties and Advantages of Uniform Particle Size Ion Exchange Resins.- The Separation of Component Ion Exchange Resins of Narrow Size Grading in Mixed Bed Exchangers, and Evaluation of Performance.- Improvements in Regeneration, Resin Separations, Resin Residuals Removal in Condensate Polishing.- Challenges in The Manufacture of Ultra-Pure Water.- Ion Exchange Studies on Strongly Basic Anion Exchange Resins Prepared with Tertiary Amines of Varying Molecular Weight.- Alternative Routes to Chloromethylation for Preparation of Anion Exchangers.- Weak Base Anion Exchange Resin: Simplification of Amination Process and Control on SBC.- Multi-Component Mixed-Bed Ion Exchange Modeling in Aminated Waters.- Leachables from Cation Resins in Demineralization and Polishing Plants and Their Significance in Water/Steam Circuits.- Municipal Drinking Water Treatment by the Carix Ion Exchange Process.- Catalytic Removal of Dissolved Oxygen from Water.- The Wilson Equation Applied to the Non-Idealities ofthe Resin Phase of Multicomponent Ion Exchange Equilibria.- Mathematical Modelling of Ion Exchange Equilibria on Polymer Ion Exchangers.- A General Solution of the Nernst-Planck Equations for Ion Exchange with Rate Control by Liquid-Phase Mass Transfer.- Heats of Sorption of Gold and Platinum Complexes on a Graphitic Carbon and an Ion Exchanger.- Flow Analysis Method for Trace Elements by Ion-Exchanger Phase Absorptiometry.- 31 P NMR Spectroscopic Studies on the Complexation Equilibria in the Ion-Exchanger Resin Phase.- Synthesis and Characterisation of Resin Sorbents for Cephalosporin C Recovery.- Ion Exchange Equilibrium and Transport of Biologicals in Resins for Pharmaceutical Processing.- The Application of Modelling to the Prediction of Adsorption in Batch-Stirred Tanks, Packed-Bed and Fluidised-Bed Columns in Biotechnological Separations.- Determination of Adsorption/Desorption Kinetics of Proteins on Ion Exchange Media.- A Monolithic Ion-Exchange Material Suitable for Downstream Processing of Bioproducts.- Direct Recovery of Protein Products from Whole Fermentation Broths.- Microbiological Treatment of Radioactive Waste Ion Exchange Resins.- Resolution of Potato Tuber Esterase Glycoforms on Fast-Flow Cellulose Ion Exchangers.- ISEP Continuous Contactor for Continuous Ion Exchange.- Adsorption of Trace Metals on Modified Activated Carbons.- Electrochemical Ion Exchange.- Hydroxyazo-Dyes in Metal Ions Preconcentration by Ion Exchange.- Selective and Reversible Sorption of Target Anions by Ligand Exchange.- The Treatment of a Board Mill Effluent Using a Combination of UF, IX and Ro Systems.- An Ion Exchange Extraction of Valuable Components Out of Waste Waters.- Inorganic Sorbents for Aqueous Effluent Treatment.- Surface Charge and Ion Sorption Properties Influencing the Fouling and Flow Characteristics of Ceramic Membranes.- Adsorption and Desorption Behaviour of Arsenic Compounds on Various Inorganic Ion Exchangers.- Inorganic Membranes in Ion Separation by Dialysis.- Hydrolysis and Trace Cs+ exchange in Na- and K-mordenite.- Inorganic Anion Exchangers for 99-Tc and 125-1 Uptake.- The Effects of External Gamma Radiation and of in Situ Alpha Particles on Five Strong-Base Anion Exchange Resins.- Ion-Exchange Fibres for the Recovery of Gold Cyanide.- Medium Base Polyamine Ion Exchange Resins for the Extraction of Gold from Cyanide Solutions.- Separation of Molybdenum and Tungsten by a Polystyrene Resin Functionalized with Iminodiacetate Ligand.- Use of New Functionalised Materials with Organopolysiloxane Structure for Purification of Arsenic (III) in Hydrochloric acid Media.- A Weak Base Copolymer for the Separation of Gold (III) from Base Metals.- Hydrolysis of Chelex 100 Chelating Resin and its Effect on Nickel Ion Exchange.- The Removal of Divalent Anions and Cations from Feed Brine for Chloralkali-Electrolysis Cells by Utilization of Ion Exchange Technology.- Index of Contributors.
Design of Polymeric Adsorbents for Food and Chemical Processing.- Comb-Like Polyethylene Oxide Polymers as Chelating Agents for Mercuric (II) Chloride: Study of the Complex Formation by Solid-State 1H-NMR.- Preparation of Chelating Hollow Fibers Based on Chlorosulfonated Polyethylene and its Uses for Metal Extraction.- Preparation and Chromate Selectivity of Weakly Basic Ion Exchangers Based on Macroporous Polyacrylonitrile.- Comparison of Strong Base Resin Types.- Nitrate Removal from Water: The Effect of Structure on the Performance of Anion Exchange Resins.- Development of Exxchange, A Continuous Ion Exchange Process Using Powdered Resins and Cross-Flow Filtration.- Operating Experience with Different Weak Base Anion Resins in the Following Configuration: WAC-WBA-SAC-Degas-SBA.- The Properties and Advantages of Uniform Particle Size Ion Exchange Resins.- The Separation of Component Ion Exchange Resins of Narrow Size Grading in Mixed Bed Exchangers, and Evaluation of Performance.- Improvements in Regeneration, Resin Separations, Resin Residuals Removal in Condensate Polishing.- Challenges in The Manufacture of Ultra-Pure Water.- Ion Exchange Studies on Strongly Basic Anion Exchange Resins Prepared with Tertiary Amines of Varying Molecular Weight.- Alternative Routes to Chloromethylation for Preparation of Anion Exchangers.- Weak Base Anion Exchange Resin: Simplification of Amination Process and Control on SBC.- Multi-Component Mixed-Bed Ion Exchange Modeling in Aminated Waters.- Leachables from Cation Resins in Demineralization and Polishing Plants and Their Significance in Water/Steam Circuits.- Municipal Drinking Water Treatment by the Carix Ion Exchange Process.- Catalytic Removal of Dissolved Oxygen from Water.- The Wilson Equation Applied to the Non-Idealities ofthe Resin Phase of Multicomponent Ion Exchange Equilibria.- Mathematical Modelling of Ion Exchange Equilibria on Polymer Ion Exchangers.- A General Solution of the Nernst-Planck Equations for Ion Exchange with Rate Control by Liquid-Phase Mass Transfer.- Heats of Sorption of Gold and Platinum Complexes on a Graphitic Carbon and an Ion Exchanger.- Flow Analysis Method for Trace Elements by Ion-Exchanger Phase Absorptiometry.- 31 P NMR Spectroscopic Studies on the Complexation Equilibria in the Ion-Exchanger Resin Phase.- Synthesis and Characterisation of Resin Sorbents for Cephalosporin C Recovery.- Ion Exchange Equilibrium and Transport of Biologicals in Resins for Pharmaceutical Processing.- The Application of Modelling to the Prediction of Adsorption in Batch-Stirred Tanks, Packed-Bed and Fluidised-Bed Columns in Biotechnological Separations.- Determination of Adsorption/Desorption Kinetics of Proteins on Ion Exchange Media.- A Monolithic Ion-Exchange Material Suitable for Downstream Processing of Bioproducts.- Direct Recovery of Protein Products from Whole Fermentation Broths.- Microbiological Treatment of Radioactive Waste Ion Exchange Resins.- Resolution of Potato Tuber Esterase Glycoforms on Fast-Flow Cellulose Ion Exchangers.- ISEP Continuous Contactor for Continuous Ion Exchange.- Adsorption of Trace Metals on Modified Activated Carbons.- Electrochemical Ion Exchange.- Hydroxyazo-Dyes in Metal Ions Preconcentration by Ion Exchange.- Selective and Reversible Sorption of Target Anions by Ligand Exchange.- The Treatment of a Board Mill Effluent Using a Combination of UF, IX and Ro Systems.- An Ion Exchange Extraction of Valuable Components Out of Waste Waters.- Inorganic Sorbents for Aqueous Effluent Treatment.- Surface Charge and Ion Sorption Properties Influencing the Fouling and Flow Characteristics of Ceramic Membranes.- Adsorption and Desorption Behaviour of Arsenic Compounds on Various Inorganic Ion Exchangers.- Inorganic Membranes in Ion Separation by Dialysis.- Hydrolysis and Trace Cs+ exchange in Na- and K-mordenite.- Inorganic Anion Exchangers for 99-Tc and 125-1 Uptake.- The Effects of External Gamma Radiation and of in Situ Alpha Particles on Five Strong-Base Anion Exchange Resins.- Ion-Exchange Fibres for the Recovery of Gold Cyanide.- Medium Base Polyamine Ion Exchange Resins for the Extraction of Gold from Cyanide Solutions.- Separation of Molybdenum and Tungsten by a Polystyrene Resin Functionalized with Iminodiacetate Ligand.- Use of New Functionalised Materials with Organopolysiloxane Structure for Purification of Arsenic (III) in Hydrochloric acid Media.- A Weak Base Copolymer for the Separation of Gold (III) from Base Metals.- Hydrolysis of Chelex 100 Chelating Resin and its Effect on Nickel Ion Exchange.- The Removal of Divalent Anions and Cations from Feed Brine for Chloralkali-Electrolysis Cells by Utilization of Ion Exchange Technology.- Index of Contributors.
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