Zhimin Liu, Yanfei Zhao

Ionic Liquid Catalyzed Reactions

Green Concepts and Sustainable Applications

• Gebundenes Buch

Produktbeschreibung

An invaluable resource for all those working in catalysis, green chemistry, and advanced synthetic methods related to ionic liquids.

Produktdetails

• Verlag: Wiley-VCH
• Artikelnr. des Verlages: 1135075 000
• 1. Auflage
• Seitenzahl: 384
• Erscheinungstermin: 2. April 2025
• Englisch
• Abmessung: 244mm x 170mm
• ISBN-13: 9783527350759
• ISBN-10: 3527350756
• Artikelnr.: 71538774

Autorenporträt

Zhimin Liu, PhD, is Professor at the Institute of Chemistry, Chinese Academy of Sciences (ICCAS), China. She has spent most of her career conducting research at ICCAS. She is the recipient of numerous scientific awards. She is an Editor-in-Chief of Current Opinion in Green and Sustainable Chemistry. Yanfei Zhao, PhD, is Associate Professor at ICCAS, China. Her current research interest concentrates on the ionic liquid-promoted transformation of renewable carbon resources.

Inhaltsangabe

Chapter 1 Ionic liquid catalysts
1.1 Acidic ionic liquids
1.2 Basic ionic liquids
1.3 Neutra ionic liquids with hydrogen-bond donor/acceptor
1.4 Chiral ionic liquids

Chapter 2 Ionic liquid-catalyzed transformation of carbon dioxide to chemicals under metal-free conditions
2.1 Synthesis of organic carbonates
2.2 Synthesis of N-containing heterocycles
2.3 Reductive transformation of CO2
2.4 Synthesis of other compounds
2.5 Remarks and perspectives

Chapter 3 Ionic liquid-mediated reductive transformation of carbon dioxide with hydrogen
3.1 Direct hydrogenation of CO2
3.2 N-formylated or N-methylated reaction of amines with CO2/H2
3.3 Hydroformylation of olefin with CO2/H2
3.4 Hydromethylamination of olefin with CO2/H2 and amines
3.5 Carbonylation of alcohol/ethers with CO2/H2
3.6 Remarks and perspectives

Chapter 4 Electrochemical reduction of carbon dioxide in ionic liquid-based electrolytes
4.1 Fundamentals of CO2 electroreduction
4.2 Ionic liquid-based electrolytes for CO2 electroreduction
4.3 Electroreduction of CO2 to various chemicals in IL-based electrolytes
4.4 Electro-transformation of CO2 into value-added chemicals
4.5 Remarks and perspectives
Chapter 5 Ionic liquid-catalyzed chemical transformation of lignocellulose
5.1 Ionic liquid-catalyzed transformation of cellulose and its derivatives
5.2 Ionic liquid-catalyzed transformation of hemicellulose and xylose to furfural
5.3 Ionic liquid-catalyzed transformation of lignin and its platforms
5.4 Remarks and perspectives

Chapter 6 Ionic liquid catalyzed oxidation reactions
6.1 Oxidation of alcohols/aldehydes
6.2 Oxidation of organic sulfides and oxidative desulfurization
6.3 Oxidative cyclization of olefins and allylic alcohols
6.4 Oxidation of amines
6.5 Baeyer-Villiger oxidation
6.6 Oxidation of other compounds
6.7 Remarks and perspectives

Chapter 7 Ionic liquid catalyzed water-involved reactions
7.1 Dehydrative esterification
7.2 Dehydrative etherification of alcohols
7.3 Dehydration alkenylation
7.4 Dehydrative amidation
7.5 Ionic liquid catalyzed hydration reaction
7.6 Hydrolysis of esters/ ethers
7.7 Remarks and perspectives

Chapter 8 Ionic liquid-catalyzed other organic reactions
8.1 Alkylation reaction
8.2 Michael addition reaction
8.3 Diels-Alder reactions
8.4 Markovnikov addition
8.5 Knoevenagel condensation
8.6 Aldol condensation reaction
8.7 Ring-closing C-O/C-O and C-O/O-H bond metathesis
8.8 Remarks and perspectives

Chapter 9 Ionic liquid catalyzed recycling of spent polymers
9.1 Degradation of polyesters 1
9.2 Degradation of polyamides
9.3 Upcycling of polyolefins
9.4 Co-upcycling of PVC and polyester
9.5 Remarks and perspectives

Acknowledgements