Written by international experts, this must-have reference is the first on this rapidly growing topic and provides an essential up-to-date guide to current and emerging trends, covering all key aspects, and also including industrial applications. The first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends. A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial applications. The resulting unique overview is a…mehr
Written by international experts, this must-have reference is the first on this rapidly growing topic and provides an essential up-to-date guide to current and emerging trends, covering all key aspects, and also including industrial applications.The first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends. A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial applications. The resulting unique overview is a must-have for researchers, both in academia and industry, who are entering or already working in the field. Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Richard Layfield is a Reader in Inorganic Chemistry at The University of Manchester, UK. He obtained his undergraduate degree in Chemistry at the University of Leeds, UK, and his PhD in Inorganic Chemistry at the University of Cambridge, UK. He has received several awards, including an Alexander von Humboldt Foundation Fellowship for Experienced Researchers, and the Royal Society of Chemistry Meldola Medal and the Sir Edward Frankland Fellowship.
Muralee Murugesu is an Associate Professor at the University of Ottawa, Canada. He studied Chemistry at the University of Paris 7 Jussieu, France. Afterwards he obtained his MSc in Chemistry at the University of East Anglia, UK, and PhD in Chemistry at the University of Karlsruhe, Germany. His first postdoctoral appointment was at University of Florida with Prof. George Christou, followed by a postdoctoral position working jointly between the University of California, Berkeley and the University of California, San Francisco under the supervision of Prof. Jeffrey Long and the Nobel Laureate Prof. Stanley Prusiner.
Inhaltsangabe
Preface
ELECTRONIC STRUCTURE AND MAGNETIC PROPERTIES OF LANTHANIDE MOLECULAR COMPLEXES Introduction Free Ion Electronic Structure Electronic Structure of Lanthanide Ions in a Ligand Field Magnetic Properties of Isolated Lanthanide Ions Exchange Coupling in Systems Containing Orbitally Degenerate Lanthanides
MONONUCLEAR LANTHANIDE COMPLEXES: USE OF THE CRYSTAL FIELD THEORY TO DESIGN SINGLE-ION MAGNETS AND SPIN QUBITS Introduction Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets:TheUse of the Crystal FieldModel Magneto-Structural Correlations for Some Typical Symmetries Impact of Lanthanide Complexes in Quantum Computing Conclusions
POLYNUCLEAR LANTHANIDE SINGLE MOLECULE MAGNETS Introduction Synthetic Strategies Conclusion
LANTHANIDES IN EXTENDED MOLECULAR NETWORKS Introduction Extended Networks Based on Gd3+ Extended Networks Based on Anisotropic Ions Conclusions
EXPERIMENTAL ASPECTS OF LANTHANIDE SINGLE-MOLECULE MAGNET PHYSICS Introduction Manifestation of Single-Molecule Magnet Behaviour Quantifying the Magnetic Anisotropy Splitting of the Ground Multiplet Observation of the Signatures of Exchange Coupling Concluding Remarks and Perspectives
COMPUTATIONAL MODELLING OF THE MAGNETIC PROPERTIES OF LANTHANIDE COMPOUNDS Introduction Ab Initio Description of Lanthanides and its Relation to Other Methods Ab Initio Calculation of Anisotropic Magnetic Properties of Mononuclear Complexes Ab Initio Calculation of Anisotropic Magnetic Properties of Polynuclear Complexes Conclusions
LANTHANIDE COMPLEXES AS REALIZATION OF QUBITS AND QUGATES FOR QUANTUM COMPUTING Introduction to Quantum Computation Quantum Computing with Electron Spin Qubits Single Lanthanide Ions as Spin Qubits Lanthanide Molecules as Prototypes of Two-Qubit Quantum Gates Conclusions and Outlook
BIS(PHTHALOCYANINATO) LANTHANIDE(III) COMPLEXES - FROM MOLECULAR MAGNETISM TO SPINTRONIC DEVICES Introduction Synthesis and Structure of LnPc2 Complexes Bulk Magnetism of LnPc2 Complexes Surface Magnetism of LnPc2 Complexes Molecular Spintronic Devices on the Base of [TbPc2]0 SIMs Conclusion and Outlook
LANTHANIDES AND THE MAGNETOCALORIC EFFECT Applications of Magnets Cold Reasoning Current Technologies How Paramagnets Act as Refrigerants More Parameters Aims Important Concepts for a Large Magnetocaloric Effect High-Performance MCE Materials Outlook
ACTINIDE SINGLE-MOLECULE MAGNETS Introduction Literature Survey of Published Actinide Single-Molecule Magnets Magnetic Coupling in Actinides Conclusions
ELECTRONIC STRUCTURE AND MAGNETIC PROPERTIES OF LANTHANIDE MOLECULAR COMPLEXES Introduction Free Ion Electronic Structure Electronic Structure of Lanthanide Ions in a Ligand Field Magnetic Properties of Isolated Lanthanide Ions Exchange Coupling in Systems Containing Orbitally Degenerate Lanthanides
MONONUCLEAR LANTHANIDE COMPLEXES: USE OF THE CRYSTAL FIELD THEORY TO DESIGN SINGLE-ION MAGNETS AND SPIN QUBITS Introduction Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets:TheUse of the Crystal FieldModel Magneto-Structural Correlations for Some Typical Symmetries Impact of Lanthanide Complexes in Quantum Computing Conclusions
POLYNUCLEAR LANTHANIDE SINGLE MOLECULE MAGNETS Introduction Synthetic Strategies Conclusion
LANTHANIDES IN EXTENDED MOLECULAR NETWORKS Introduction Extended Networks Based on Gd3+ Extended Networks Based on Anisotropic Ions Conclusions
EXPERIMENTAL ASPECTS OF LANTHANIDE SINGLE-MOLECULE MAGNET PHYSICS Introduction Manifestation of Single-Molecule Magnet Behaviour Quantifying the Magnetic Anisotropy Splitting of the Ground Multiplet Observation of the Signatures of Exchange Coupling Concluding Remarks and Perspectives
COMPUTATIONAL MODELLING OF THE MAGNETIC PROPERTIES OF LANTHANIDE COMPOUNDS Introduction Ab Initio Description of Lanthanides and its Relation to Other Methods Ab Initio Calculation of Anisotropic Magnetic Properties of Mononuclear Complexes Ab Initio Calculation of Anisotropic Magnetic Properties of Polynuclear Complexes Conclusions
LANTHANIDE COMPLEXES AS REALIZATION OF QUBITS AND QUGATES FOR QUANTUM COMPUTING Introduction to Quantum Computation Quantum Computing with Electron Spin Qubits Single Lanthanide Ions as Spin Qubits Lanthanide Molecules as Prototypes of Two-Qubit Quantum Gates Conclusions and Outlook
BIS(PHTHALOCYANINATO) LANTHANIDE(III) COMPLEXES - FROM MOLECULAR MAGNETISM TO SPINTRONIC DEVICES Introduction Synthesis and Structure of LnPc2 Complexes Bulk Magnetism of LnPc2 Complexes Surface Magnetism of LnPc2 Complexes Molecular Spintronic Devices on the Base of [TbPc2]0 SIMs Conclusion and Outlook
LANTHANIDES AND THE MAGNETOCALORIC EFFECT Applications of Magnets Cold Reasoning Current Technologies How Paramagnets Act as Refrigerants More Parameters Aims Important Concepts for a Large Magnetocaloric Effect High-Performance MCE Materials Outlook
ACTINIDE SINGLE-MOLECULE MAGNETS Introduction Literature Survey of Published Actinide Single-Molecule Magnets Magnetic Coupling in Actinides Conclusions
Index
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