Macromolecular Self-Assembly
Herausgeber: Billon, Laurent; Borisov, Oleg
Macromolecular Self-Assembly
Herausgeber: Billon, Laurent; Borisov, Oleg
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This book describes techniques of synthesis and self-assembly of macromolecules for developing new materials and improving functionality of existing ones. Because self-assembly emulates how nature creates complex systems, they likely have the best chance at succeeding in real-world biomedical applications. * Employs synthetic chemistry, physical chemistry, and materials science principles and techniques * Emphasizes self-assembly in solutions (particularly, aqueous solutions) and at solid-liquid interfaces * Describes polymer assembly driven by multitude interactions, including solvophobic,…mehr
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This book describes techniques of synthesis and self-assembly of macromolecules for developing new materials and improving functionality of existing ones. Because self-assembly emulates how nature creates complex systems, they likely have the best chance at succeeding in real-world biomedical applications. * Employs synthetic chemistry, physical chemistry, and materials science principles and techniques * Emphasizes self-assembly in solutions (particularly, aqueous solutions) and at solid-liquid interfaces * Describes polymer assembly driven by multitude interactions, including solvophobic, electrostatic, and obligatory co-assembly * Illustrates assembly of bio-hybrid macromolecules and applications in biomedical engineering
Produktdetails
- Produktdetails
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 272
- Erscheinungstermin: 6. September 2016
- Englisch
- Abmessung: 240mm x 161mm x 20mm
- Gewicht: 604g
- ISBN-13: 9781118887127
- ISBN-10: 1118887123
- Artikelnr.: 42834298
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 272
- Erscheinungstermin: 6. September 2016
- Englisch
- Abmessung: 240mm x 161mm x 20mm
- Gewicht: 604g
- ISBN-13: 9781118887127
- ISBN-10: 1118887123
- Artikelnr.: 42834298
Laurent Billon, PhD, is Professor at Pau University (France) and leader of the polymer group at the Interdisciplinary Institute of Environmental and Material Research (IPREM) in Pau, France. He is the author of over 90 scientific publications and 12 patents. He received his PhD in Polymer Chemistry from Pau University. Oleg Borisov, PhD, is research director at the Institute of Environmental and Material Research at Pau University, France. He received his PhD in physics and mechanics of polymers in the Institute of Macromolecular Compounds of the Russian Academy of Sciences. He is the author of over 150 scientific publications and received the Friedrich Wilhelm Bessel Research Award (2004) from the Alexander von Humboldt Foundation.
List of Contributors ix Preface xiii 1 A Supramolecular Approach to Macromolecular Self-Assembly: Cyclodextrin Host/Guest Complexes 1 Bernhard V. K. J. Schmidt and Christopher Barner-Kowollik 1.1 Introduction
1 1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks
3 1.2.1 CD Functionalization
3 1.2.2 Suitable Guest Groups
5 1.3 Supramolecular CD Self-Assemblies
7 1.3.1 Linear Polymers
7 1.3.2 Branched Polymers
12 1.3.3 Cyclic Polymer Architectures
17 1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward Nanostructures
17 1.4.1 Micelles/Core-Shell Particles
17 1.4.2 Vesicles
19 1.4.3 Nanotubes and Fibers
20 1.4.4 Nanoparticles and Hybrid Materials
21 1.4.5 Planar Surface Modification
22 1.5 Applications
23 1.6 Conclusion and Outlook
26 References
26 2 Polymerization-Induced Self-Assembly: The Contribution of Controlled Radical Polymerization to The Formation of Self-Stabilized Polymer Particles of Various Morphologies 33 Muriel Lansalot
Jutta Rieger
and Franck D'Agosto 2.1 Introduction
33 2.2 Preliminary Comments Underlying Controlled Radical Polymerization
36 2.2.1 Introduction
36 2.2.2 Major Methods Based on a Reversible Termination Mechanism
37 2.2.3 Major Methods Based on a Reversible Transfer Mechanism
39 2.3 Pisa Via CRP Based on Reversible Termination
40 2.3.1 PISA Using NMP
40 2.3.2 Using ATRP
46 2.4 Pisa Via CRP Based on Reversible Transfer
48 2.4.1 Using RAFT in Emulsion Polymerization
48 2.4.2 Using RAFT in Dispersion Polymerization
61 2.4.3 Using TERP
70 2.5 Concluding Remarks
71 Acknowledgments
73 Abbreviations
73 References
75 3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in Aqueous Solution 83 Elise Deniau-Lejeune
Olga Borisova
Petr St¡epánek
Laurent Billon
and Oleg Borisov 3.1 Introduction
83 3.2 Synthetic Strategies for The Preparation of Gradient Copolymers
86 3.2.1 Preparation of Gradient Copolymers by Controlled Radical Copolymerization
87 3.2.2 Preparation of Block-Gradient Copolymers Using Controlled Radical Polymerization
106 3.3 Self-Assembly
110 3.3.1 Gradient Copolymers
110 3.3.2 Diblock-Gradient Copolymers
111 3.3.3 Triblock-Gradient Copolymers
113 3.4 Conclusion and Outlook
114 Abbreviations
115 References
117 4 Electrostatically Assembled Complex Macromolecular Architectures Based on Star-Like Polyionic Species 125 Dmitry V. Pergushov and Felix A. Plamper 4.1 Introduction
125 4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed with Linear Polyions
127 4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic Amphiphilic Diblock Copolymers Complexed with Linear Polyions
130 4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed with Linear Polyions
133 4.5 Conclusions
137 Acknowledgment
137 References
137 5 Solution Properties of Associating Polymers 141 Olga Philippova 5.1 Introduction
141 5.2 Structures of Associating Polyelectrolytes
142 5.3 Associating Polyelectrolytes in Dilute Solutions
142 5.3.1 Intramolecular Association
145 5.3.2 Intermolecular Association
147 5.4 Associating Polyelectrolytes in Semidilute Solutions
151 5.5 Conclusions
155 References
155 6 Macromolecular Decoration of Nanoparticles for Guiding Self-Assembly in 2D and 3D 159 Christian Kuttner
Munish Chanana
Matthias Karg
and Andreas Fery 6.1 Introduction
159 6.2 Guiding Assembly by Decoration with Artificial Macromolecules
160 6.2.1 Decoration of Nanoparticles
161 6.2.2 Distance Control in 2D and 3D
166 6.2.3 Breaking the Symmetry
171 6.3 Guiding Assembly by Decoration with Biomacromolecules
173 6.3.1 DNA-Assisted Assembly
173 6.3.2 Protein-Assisted Assembly
177 6.4 Application of Assemblies
181 6.5 Conclusions and Outlook
183 References
184 7 Self-Assembly of Biohybrid Polymers 193 Dawid Kedracki
Jancy Nixon Abraham
Enora Prado
and Corinne Nardin 7.1 Introduction
193 7.1.1 Amphiphiles
194 7.1.2 Packing Parameter and Interfacial Tension
195 7.1.3 Interaction Forces in Self-Assembly
196 7.2 Self-Assembly of Biohybrid Polymers
198 7.2.1 Polymer-DNA Hybrids
198 7.2.2 Polypeptide Block Copolymers
204 7.2.3 Block Copolypeptides
205 7.3 Self-Assembly Driven Nucleation Polymerization
207 7.3.1 Polymer-DNA Hybrids
209 7.3.2 Polymer-Peptide Hybrids
209 7.3.3 DNA-Peptide Hybrids
212 7.4 Self-Assembly Driven by Electrostatic Interactions
213 7.4.1 DNA/Polymer Bio-IPECs
216 7.4.2 DNA/Copolymer Bio-IPECs
216 7.5 Conclusion
218 References
219 8 Biomedical Application of Block Copolymers 231 Martin Hrub?
Sergey K. Filippov
and Petr St¡epánek 8.1 Introduction
231 8.2 Diblock and Triblock Copolymers
234 8.3 Graft and Statistical Copolymers
240 8.4 Concluding Remarks
245 Acknowledgment
245 References
245 Index 251
1 1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks
3 1.2.1 CD Functionalization
3 1.2.2 Suitable Guest Groups
5 1.3 Supramolecular CD Self-Assemblies
7 1.3.1 Linear Polymers
7 1.3.2 Branched Polymers
12 1.3.3 Cyclic Polymer Architectures
17 1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward Nanostructures
17 1.4.1 Micelles/Core-Shell Particles
17 1.4.2 Vesicles
19 1.4.3 Nanotubes and Fibers
20 1.4.4 Nanoparticles and Hybrid Materials
21 1.4.5 Planar Surface Modification
22 1.5 Applications
23 1.6 Conclusion and Outlook
26 References
26 2 Polymerization-Induced Self-Assembly: The Contribution of Controlled Radical Polymerization to The Formation of Self-Stabilized Polymer Particles of Various Morphologies 33 Muriel Lansalot
Jutta Rieger
and Franck D'Agosto 2.1 Introduction
33 2.2 Preliminary Comments Underlying Controlled Radical Polymerization
36 2.2.1 Introduction
36 2.2.2 Major Methods Based on a Reversible Termination Mechanism
37 2.2.3 Major Methods Based on a Reversible Transfer Mechanism
39 2.3 Pisa Via CRP Based on Reversible Termination
40 2.3.1 PISA Using NMP
40 2.3.2 Using ATRP
46 2.4 Pisa Via CRP Based on Reversible Transfer
48 2.4.1 Using RAFT in Emulsion Polymerization
48 2.4.2 Using RAFT in Dispersion Polymerization
61 2.4.3 Using TERP
70 2.5 Concluding Remarks
71 Acknowledgments
73 Abbreviations
73 References
75 3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in Aqueous Solution 83 Elise Deniau-Lejeune
Olga Borisova
Petr St¡epánek
Laurent Billon
and Oleg Borisov 3.1 Introduction
83 3.2 Synthetic Strategies for The Preparation of Gradient Copolymers
86 3.2.1 Preparation of Gradient Copolymers by Controlled Radical Copolymerization
87 3.2.2 Preparation of Block-Gradient Copolymers Using Controlled Radical Polymerization
106 3.3 Self-Assembly
110 3.3.1 Gradient Copolymers
110 3.3.2 Diblock-Gradient Copolymers
111 3.3.3 Triblock-Gradient Copolymers
113 3.4 Conclusion and Outlook
114 Abbreviations
115 References
117 4 Electrostatically Assembled Complex Macromolecular Architectures Based on Star-Like Polyionic Species 125 Dmitry V. Pergushov and Felix A. Plamper 4.1 Introduction
125 4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed with Linear Polyions
127 4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic Amphiphilic Diblock Copolymers Complexed with Linear Polyions
130 4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed with Linear Polyions
133 4.5 Conclusions
137 Acknowledgment
137 References
137 5 Solution Properties of Associating Polymers 141 Olga Philippova 5.1 Introduction
141 5.2 Structures of Associating Polyelectrolytes
142 5.3 Associating Polyelectrolytes in Dilute Solutions
142 5.3.1 Intramolecular Association
145 5.3.2 Intermolecular Association
147 5.4 Associating Polyelectrolytes in Semidilute Solutions
151 5.5 Conclusions
155 References
155 6 Macromolecular Decoration of Nanoparticles for Guiding Self-Assembly in 2D and 3D 159 Christian Kuttner
Munish Chanana
Matthias Karg
and Andreas Fery 6.1 Introduction
159 6.2 Guiding Assembly by Decoration with Artificial Macromolecules
160 6.2.1 Decoration of Nanoparticles
161 6.2.2 Distance Control in 2D and 3D
166 6.2.3 Breaking the Symmetry
171 6.3 Guiding Assembly by Decoration with Biomacromolecules
173 6.3.1 DNA-Assisted Assembly
173 6.3.2 Protein-Assisted Assembly
177 6.4 Application of Assemblies
181 6.5 Conclusions and Outlook
183 References
184 7 Self-Assembly of Biohybrid Polymers 193 Dawid Kedracki
Jancy Nixon Abraham
Enora Prado
and Corinne Nardin 7.1 Introduction
193 7.1.1 Amphiphiles
194 7.1.2 Packing Parameter and Interfacial Tension
195 7.1.3 Interaction Forces in Self-Assembly
196 7.2 Self-Assembly of Biohybrid Polymers
198 7.2.1 Polymer-DNA Hybrids
198 7.2.2 Polypeptide Block Copolymers
204 7.2.3 Block Copolypeptides
205 7.3 Self-Assembly Driven Nucleation Polymerization
207 7.3.1 Polymer-DNA Hybrids
209 7.3.2 Polymer-Peptide Hybrids
209 7.3.3 DNA-Peptide Hybrids
212 7.4 Self-Assembly Driven by Electrostatic Interactions
213 7.4.1 DNA/Polymer Bio-IPECs
216 7.4.2 DNA/Copolymer Bio-IPECs
216 7.5 Conclusion
218 References
219 8 Biomedical Application of Block Copolymers 231 Martin Hrub?
Sergey K. Filippov
and Petr St¡epánek 8.1 Introduction
231 8.2 Diblock and Triblock Copolymers
234 8.3 Graft and Statistical Copolymers
240 8.4 Concluding Remarks
245 Acknowledgment
245 References
245 Index 251
List of Contributors ix Preface xiii 1 A Supramolecular Approach to Macromolecular Self-Assembly: Cyclodextrin Host/Guest Complexes 1 Bernhard V. K. J. Schmidt and Christopher Barner-Kowollik 1.1 Introduction
1 1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks
3 1.2.1 CD Functionalization
3 1.2.2 Suitable Guest Groups
5 1.3 Supramolecular CD Self-Assemblies
7 1.3.1 Linear Polymers
7 1.3.2 Branched Polymers
12 1.3.3 Cyclic Polymer Architectures
17 1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward Nanostructures
17 1.4.1 Micelles/Core-Shell Particles
17 1.4.2 Vesicles
19 1.4.3 Nanotubes and Fibers
20 1.4.4 Nanoparticles and Hybrid Materials
21 1.4.5 Planar Surface Modification
22 1.5 Applications
23 1.6 Conclusion and Outlook
26 References
26 2 Polymerization-Induced Self-Assembly: The Contribution of Controlled Radical Polymerization to The Formation of Self-Stabilized Polymer Particles of Various Morphologies 33 Muriel Lansalot
Jutta Rieger
and Franck D'Agosto 2.1 Introduction
33 2.2 Preliminary Comments Underlying Controlled Radical Polymerization
36 2.2.1 Introduction
36 2.2.2 Major Methods Based on a Reversible Termination Mechanism
37 2.2.3 Major Methods Based on a Reversible Transfer Mechanism
39 2.3 Pisa Via CRP Based on Reversible Termination
40 2.3.1 PISA Using NMP
40 2.3.2 Using ATRP
46 2.4 Pisa Via CRP Based on Reversible Transfer
48 2.4.1 Using RAFT in Emulsion Polymerization
48 2.4.2 Using RAFT in Dispersion Polymerization
61 2.4.3 Using TERP
70 2.5 Concluding Remarks
71 Acknowledgments
73 Abbreviations
73 References
75 3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in Aqueous Solution 83 Elise Deniau-Lejeune
Olga Borisova
Petr St¡epánek
Laurent Billon
and Oleg Borisov 3.1 Introduction
83 3.2 Synthetic Strategies for The Preparation of Gradient Copolymers
86 3.2.1 Preparation of Gradient Copolymers by Controlled Radical Copolymerization
87 3.2.2 Preparation of Block-Gradient Copolymers Using Controlled Radical Polymerization
106 3.3 Self-Assembly
110 3.3.1 Gradient Copolymers
110 3.3.2 Diblock-Gradient Copolymers
111 3.3.3 Triblock-Gradient Copolymers
113 3.4 Conclusion and Outlook
114 Abbreviations
115 References
117 4 Electrostatically Assembled Complex Macromolecular Architectures Based on Star-Like Polyionic Species 125 Dmitry V. Pergushov and Felix A. Plamper 4.1 Introduction
125 4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed with Linear Polyions
127 4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic Amphiphilic Diblock Copolymers Complexed with Linear Polyions
130 4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed with Linear Polyions
133 4.5 Conclusions
137 Acknowledgment
137 References
137 5 Solution Properties of Associating Polymers 141 Olga Philippova 5.1 Introduction
141 5.2 Structures of Associating Polyelectrolytes
142 5.3 Associating Polyelectrolytes in Dilute Solutions
142 5.3.1 Intramolecular Association
145 5.3.2 Intermolecular Association
147 5.4 Associating Polyelectrolytes in Semidilute Solutions
151 5.5 Conclusions
155 References
155 6 Macromolecular Decoration of Nanoparticles for Guiding Self-Assembly in 2D and 3D 159 Christian Kuttner
Munish Chanana
Matthias Karg
and Andreas Fery 6.1 Introduction
159 6.2 Guiding Assembly by Decoration with Artificial Macromolecules
160 6.2.1 Decoration of Nanoparticles
161 6.2.2 Distance Control in 2D and 3D
166 6.2.3 Breaking the Symmetry
171 6.3 Guiding Assembly by Decoration with Biomacromolecules
173 6.3.1 DNA-Assisted Assembly
173 6.3.2 Protein-Assisted Assembly
177 6.4 Application of Assemblies
181 6.5 Conclusions and Outlook
183 References
184 7 Self-Assembly of Biohybrid Polymers 193 Dawid Kedracki
Jancy Nixon Abraham
Enora Prado
and Corinne Nardin 7.1 Introduction
193 7.1.1 Amphiphiles
194 7.1.2 Packing Parameter and Interfacial Tension
195 7.1.3 Interaction Forces in Self-Assembly
196 7.2 Self-Assembly of Biohybrid Polymers
198 7.2.1 Polymer-DNA Hybrids
198 7.2.2 Polypeptide Block Copolymers
204 7.2.3 Block Copolypeptides
205 7.3 Self-Assembly Driven Nucleation Polymerization
207 7.3.1 Polymer-DNA Hybrids
209 7.3.2 Polymer-Peptide Hybrids
209 7.3.3 DNA-Peptide Hybrids
212 7.4 Self-Assembly Driven by Electrostatic Interactions
213 7.4.1 DNA/Polymer Bio-IPECs
216 7.4.2 DNA/Copolymer Bio-IPECs
216 7.5 Conclusion
218 References
219 8 Biomedical Application of Block Copolymers 231 Martin Hrub?
Sergey K. Filippov
and Petr St¡epánek 8.1 Introduction
231 8.2 Diblock and Triblock Copolymers
234 8.3 Graft and Statistical Copolymers
240 8.4 Concluding Remarks
245 Acknowledgment
245 References
245 Index 251
1 1.2 Synthetic Approaches to Host/Guest Functionalized Building Blocks
3 1.2.1 CD Functionalization
3 1.2.2 Suitable Guest Groups
5 1.3 Supramolecular CD Self-Assemblies
7 1.3.1 Linear Polymers
7 1.3.2 Branched Polymers
12 1.3.3 Cyclic Polymer Architectures
17 1.4 Higher Order Assemblies of CD-Based Polymer Architectures Toward Nanostructures
17 1.4.1 Micelles/Core-Shell Particles
17 1.4.2 Vesicles
19 1.4.3 Nanotubes and Fibers
20 1.4.4 Nanoparticles and Hybrid Materials
21 1.4.5 Planar Surface Modification
22 1.5 Applications
23 1.6 Conclusion and Outlook
26 References
26 2 Polymerization-Induced Self-Assembly: The Contribution of Controlled Radical Polymerization to The Formation of Self-Stabilized Polymer Particles of Various Morphologies 33 Muriel Lansalot
Jutta Rieger
and Franck D'Agosto 2.1 Introduction
33 2.2 Preliminary Comments Underlying Controlled Radical Polymerization
36 2.2.1 Introduction
36 2.2.2 Major Methods Based on a Reversible Termination Mechanism
37 2.2.3 Major Methods Based on a Reversible Transfer Mechanism
39 2.3 Pisa Via CRP Based on Reversible Termination
40 2.3.1 PISA Using NMP
40 2.3.2 Using ATRP
46 2.4 Pisa Via CRP Based on Reversible Transfer
48 2.4.1 Using RAFT in Emulsion Polymerization
48 2.4.2 Using RAFT in Dispersion Polymerization
61 2.4.3 Using TERP
70 2.5 Concluding Remarks
71 Acknowledgments
73 Abbreviations
73 References
75 3 Amphiphilic Gradient Copolymers: Synthesis and Self-Assembly in Aqueous Solution 83 Elise Deniau-Lejeune
Olga Borisova
Petr St¡epánek
Laurent Billon
and Oleg Borisov 3.1 Introduction
83 3.2 Synthetic Strategies for The Preparation of Gradient Copolymers
86 3.2.1 Preparation of Gradient Copolymers by Controlled Radical Copolymerization
87 3.2.2 Preparation of Block-Gradient Copolymers Using Controlled Radical Polymerization
106 3.3 Self-Assembly
110 3.3.1 Gradient Copolymers
110 3.3.2 Diblock-Gradient Copolymers
111 3.3.3 Triblock-Gradient Copolymers
113 3.4 Conclusion and Outlook
114 Abbreviations
115 References
117 4 Electrostatically Assembled Complex Macromolecular Architectures Based on Star-Like Polyionic Species 125 Dmitry V. Pergushov and Felix A. Plamper 4.1 Introduction
125 4.2 Core-Corona Co-Assemblies of Homopolyelectrolyte Stars Complexed with Linear Polyions
127 4.3 Core-Shell-Corona Co-Assemblies of Star-Like Micelles of Ionic Amphiphilic Diblock Copolymers Complexed with Linear Polyions
130 4.4 Vesicular Co-Assemblies of Bis-Hydrophilic Miktoarm Stars Complexed with Linear Polyions
133 4.5 Conclusions
137 Acknowledgment
137 References
137 5 Solution Properties of Associating Polymers 141 Olga Philippova 5.1 Introduction
141 5.2 Structures of Associating Polyelectrolytes
142 5.3 Associating Polyelectrolytes in Dilute Solutions
142 5.3.1 Intramolecular Association
145 5.3.2 Intermolecular Association
147 5.4 Associating Polyelectrolytes in Semidilute Solutions
151 5.5 Conclusions
155 References
155 6 Macromolecular Decoration of Nanoparticles for Guiding Self-Assembly in 2D and 3D 159 Christian Kuttner
Munish Chanana
Matthias Karg
and Andreas Fery 6.1 Introduction
159 6.2 Guiding Assembly by Decoration with Artificial Macromolecules
160 6.2.1 Decoration of Nanoparticles
161 6.2.2 Distance Control in 2D and 3D
166 6.2.3 Breaking the Symmetry
171 6.3 Guiding Assembly by Decoration with Biomacromolecules
173 6.3.1 DNA-Assisted Assembly
173 6.3.2 Protein-Assisted Assembly
177 6.4 Application of Assemblies
181 6.5 Conclusions and Outlook
183 References
184 7 Self-Assembly of Biohybrid Polymers 193 Dawid Kedracki
Jancy Nixon Abraham
Enora Prado
and Corinne Nardin 7.1 Introduction
193 7.1.1 Amphiphiles
194 7.1.2 Packing Parameter and Interfacial Tension
195 7.1.3 Interaction Forces in Self-Assembly
196 7.2 Self-Assembly of Biohybrid Polymers
198 7.2.1 Polymer-DNA Hybrids
198 7.2.2 Polypeptide Block Copolymers
204 7.2.3 Block Copolypeptides
205 7.3 Self-Assembly Driven Nucleation Polymerization
207 7.3.1 Polymer-DNA Hybrids
209 7.3.2 Polymer-Peptide Hybrids
209 7.3.3 DNA-Peptide Hybrids
212 7.4 Self-Assembly Driven by Electrostatic Interactions
213 7.4.1 DNA/Polymer Bio-IPECs
216 7.4.2 DNA/Copolymer Bio-IPECs
216 7.5 Conclusion
218 References
219 8 Biomedical Application of Block Copolymers 231 Martin Hrub?
Sergey K. Filippov
and Petr St¡epánek 8.1 Introduction
231 8.2 Diblock and Triblock Copolymers
234 8.3 Graft and Statistical Copolymers
240 8.4 Concluding Remarks
245 Acknowledgment
245 References
245 Index 251