Macromolecule-Metal Complexes gives the first concise overview on the topic, both on fundamentals and new application areas. Their synthesis, kinetics and thermodynamics are detailed; special properties such as gas transport, charge transport, catalysis and lightinduced processes are emphasized. Furthermore, the authors treat the actual working areas for new application methods. Thus, the book will be a very helpful tool for Polymer Scientists, Materials Scientists, Organic Chemists, and Physical Chemists working in these fields.
Macromolecule-Metal Complexes gives the first concise overview on the topic, both on fundamentals and new application areas. Their synthesis, kinetics and thermodynamics are detailed; special properties such as gas transport, charge transport, catalysis and lightinduced processes are emphasized. Furthermore, the authors treat the actual working areas for new application methods. Thus, the book will be a very helpful tool for Polymer Scientists, Materials Scientists, Organic Chemists, and Physical Chemists working in these fields.
Macromolecule-Metal Complexes have been known for a long time in biological systems; they are e.g. involved in photosynthesis, metal enzymes, electron transfer reactions and gas transport. Scientists have been enthusiastic about synthesizing macromolecule-metal complexes which can be used as new materials with new exciting properties. This book gives the first overview of fundamentals and application methods.
Inhaltsangabe
1 Introduction and Fundamental Aspects.- 1.1 Macromolecular Metal Complexes.- 1.2 Types, Formation and Structural Features of MMC.- 1.3 Properties and Application of MMC.- 1.4 Aim of the Book.- 2 Synthesis and Structure of Macromolecular Metal Complexes.- 2.1 Main Structural Principles of Formation and Characteristics of Macromolecular Metal Complexes.- 2.2 Type I: Metal Complexes Bound to Macromolecular Carriers via Ligands or Metal Ions.- 2.3 Type II: Metal Complexes and Metals as Part of a Polymer Chain or Network.- 2.4 Type III: Metal Complexes, Zero-Valent Metals and Metal Clusters Physically Connected with Macromolecular Compounds.- 3 Polymer Metal Complexes in Living Systems.- 3.1 Introduction.- 3.2 Overview of Ligands Present in Living Systems.- 3.3 Metal Ions Occurring in Biological Systems.- 3.4 Applications of Metal Complexes in Living Systems.- 3.5 Conclusion.- 4 Electronic Processes in Macromolecular Metal Complexes.- 4.1 Ion-Conductive Materials of Macromolecules.- 4.2 Transport Phenomena and Separation of Small Molecules.- 4.3 Assembled Porphyrins and Oxygen Coordination.- 4.4 Catalysis in Macromolecular Metal Complexes.- 4.5 Recent Advances in Oxidative Polymerization Through Multielectron Transfer.- 5 Photoinduced Electron Transport of Macromolecular Metal Complexes.- 5.1 Photoinduced Electron Transport in Solution.- 5.2 Photoinduced Electron Transport at Solid/Liquid Interface.- 5.3 Conduction and Photoinduced Behavior in Solid Macromolecular Metal Complexes.- 6 Outlook.- 6.1 Structure of MMC.- 6.2 Properties and Applications of MMC.- 6.3 Conclusion.
1 Introduction and Fundamental Aspects.- 1.1 Macromolecular Metal Complexes.- 1.2 Types, Formation and Structural Features of MMC.- 1.3 Properties and Application of MMC.- 1.4 Aim of the Book.- 2 Synthesis and Structure of Macromolecular Metal Complexes.- 2.1 Main Structural Principles of Formation and Characteristics of Macromolecular Metal Complexes.- 2.2 Type I: Metal Complexes Bound to Macromolecular Carriers via Ligands or Metal Ions.- 2.3 Type II: Metal Complexes and Metals as Part of a Polymer Chain or Network.- 2.4 Type III: Metal Complexes, Zero-Valent Metals and Metal Clusters Physically Connected with Macromolecular Compounds.- 3 Polymer Metal Complexes in Living Systems.- 3.1 Introduction.- 3.2 Overview of Ligands Present in Living Systems.- 3.3 Metal Ions Occurring in Biological Systems.- 3.4 Applications of Metal Complexes in Living Systems.- 3.5 Conclusion.- 4 Electronic Processes in Macromolecular Metal Complexes.- 4.1 Ion-Conductive Materials of Macromolecules.- 4.2 Transport Phenomena and Separation of Small Molecules.- 4.3 Assembled Porphyrins and Oxygen Coordination.- 4.4 Catalysis in Macromolecular Metal Complexes.- 4.5 Recent Advances in Oxidative Polymerization Through Multielectron Transfer.- 5 Photoinduced Electron Transport of Macromolecular Metal Complexes.- 5.1 Photoinduced Electron Transport in Solution.- 5.2 Photoinduced Electron Transport at Solid/Liquid Interface.- 5.3 Conduction and Photoinduced Behavior in Solid Macromolecular Metal Complexes.- 6 Outlook.- 6.1 Structure of MMC.- 6.2 Properties and Applications of MMC.- 6.3 Conclusion.
Rezensionen
"...an excellent source of information in a field of increasing importance. ...highly recommended to anyone needing an up-to-date insight into this important field." Polymer News
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