Macromolecules Containing Metal and Metal-Like Elements, Volume 9

Supramolecular and Self-Assembled Metal-Containing Materials
Herausgeber: Abd-El-Aziz, Alaa S; Zeldin, Martel; Pittman, Charles U; Carraher, Charles E

• Gebundenes Buch

Produktbeschreibung

Volume 9 in a scientific research series, covering macromolecules This book, Macromolecules Containing Metal and Metal-like Elements, presents research developments in the study of: supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies. The topics addressed involve materials containing metals and metal-like elements as well as the possible applications of hybrid materials. The volume offers a broad series of coverage with conclusions and perspectives for the various areas covered.

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Produktdetails

• Verlag: Wiley
• Seitenzahl: 560
• Erscheinungstermin: 2. November 2009
• Englisch
• Abmessung: 239mm x 163mm x 30mm
• Gewicht: 839g
• ISBN-13: 9780470251447
• ISBN-10: 0470251441
• Artikelnr.: 28240663

Autorenporträt

Alaa S. Abd-El-Aziz is the Associate Vice-President (Academic and Research) at theUniversity ofBritish Columbia Okanagan. In 1997, he was named a Fellow of the Chemical Institute of Canada, and has been the recipient of a number of awards including the Manitoba Outstanding Chemist Award, the Erica & Arnold Rogers Award for Excellence in Research and Scholarship, and the Clifford J. Robson Memorial Award for Excellence in Teaching. Charles Carraher is Professor of Chemistry atFloridaAtlanticUniversity and Associate Director of theFloridaCenter for Environmental Studies. Dr. Carraher previously was Dean of the Charles E.Schmidt College of Science at FAU, Chair of the Science Division at theUniversity ofSouth Dakota and Chair of the Department of Chemistry at Wright State University. His research deals with the general topic of polymers as applied to electronics, computers, biomedicine, instrumentation and construction. Charles Pittman came to Mississippi State in 1983 as Professor of Industrial Chemistry and Catalysis. He was appointed Full Professor in 1975 and University Research Professor in 1977. He is also Research Director of the University/Industry Chemical Research Center. Martin Zeldin is Visiting Senior Research Scholar at the University of Richmond in Virginia. He received his Ph.D. in inorganic chemistry in 1968 from Pennsylvania State University.

Inhaltsangabe

Preface xvii Series Preface xxi 1. Supramolecular Structures and Functions with Inorganic Building Blocks 1 Katsuhiko Ariga, Ajayan Vinu, Jonathan P. Hill, Pavuluri Srinivasu, Somobrata Acharya, and Qingmin Ji I. Introduction 2 II. Hybrid Lipid Thin Films 2 III. Layer-by-Layer Assemblies 8 IV. Structure Transcription 13 V. Functional Mesoporous Hybrids 20 VI. Future Perspectives 30 VII. Acknowledgments 30 VIII. References 30 2. Self-Assembly of Hydrophilic Polyoxometalate Macroanions in Dilute Solutions 35 Melissa L. Kistler, Joe Pigga, and Tianbo Liu I. Introduction 36 II. Solution Behavior of POM Macroions: Soluble but Still Aggregate 38 III. Characterization of the Supramolecular Structures 40 IV. Controlling the Blackberry Formation and Blackberry Size by Changing Solvent Quality 41 V. Counterion Association around Discrete POM Macroions 45 VI. Counterion Condensation around Blackberries 46 VII. Identification of the Driving Forces Responsible for the Blackberry Formation 47 VIII. Soft Nature of the Blackberries-Effect of Additional Hydrogen Bonding 47 IX. Weak Electrolyte Type POMs 48 X. Effect of Additional Electrolytes 49 XI. Kinetic Process of Blackberry Formation 52 XII. Cation Transport over the Anionic Blackberry Membrane 55 XIII. Macroions in Solution: An important Linkage among Simple Ions, Polymers, Colloids, and Biosystems 57 XIV. Conclusions 58 XV. Acknowledgments 58 XVI. References 58 3. Supramolecular Structures and Polyoxometalates 61 Samar K. Das I. Introduction 62 II. Supramolecular Features of Polyoxometalate-Supported Transition-Metal Complexes 62 III. Polyoxometalate Crown Ether Complexes with Supramolecular cations 91 IV. Supramolecular Water Clusters Associated with Polyoxometalates 103 V. Concluding Remarks 118 VI. Acknowledgements 119 VII. References 120 4. Supramolecular Coordination Networks Employing Sulfonate and Phosphonate Linkers: From Layers to Open Structures 125 George K. H. Shimizu, Jared M. Taylor, and Ramanathan Vaidhyanathan I. Introduction 126 II. The Sulfonate Group as a Ligand 127 III. Layered Metal Sulfonates 128 IV. Nonlayered Metal Sulfonates 137 A. Dynamic and Crystalline Metal Sulfonate Frameworks 147 B. Hydrogen Bonded Second Sphere Coordination Networks 155 V. Metal phosphonates 167 VI. Conclusion 176 VII. References 177 5. Transition-Metal-Based Linear Chain Compounds 181 Moumita Majumdar, and Jitendra K. Bera I. Introduction 182 II. Ligand-Supported Metal Chains 183 A. Linear Chains of Chromium 183 B. Linear Metal Chains of Cobalt 187 C. Linear Chains of Copper 197 D. Linear Chains of Nickel 200 E. Linear Chains of Palladium 211 III. Unsupported Metal Chains 221 A. Linear Chain Compounds of Rhodium 221 B. Linear Chain of Iridium 233 C. The Platinum Blues 241 IV. Concluding Remarks 246 V. References 247 6. Boronate-Linked Materials: Ranging from Amorphous Assemblies to Highly Structured Networks 255 Brett M. Rambo, R. William Tilford, Laura M. Lanni, Jie Liu, and John J. Lavigne I. Introduction and Scope 256 II. Supramolecular Boronate Assemblies 257 A. ''Traditional'' Hydrogen Bonded Supramolecular Assemblies 258 B. ''Novel'' Phenyl-Boron-Phenyl Sandwich Supramolecular Assembly 258 C. Coordination-Based Macrocyclic Assemblies 261 D. Coordination-Based Linear Assemblies 267 III. Covalently Linked Boronate Assemblies 270 A. Covalently Linked Macrocyclic and Cage Assemblies 271 B. Covalently Linked Linear Assemblies 279 C. Covalently Linked Network Assemblies 284 IV. Summary and Outlook 289 V. References 291 7. Mixed-Metal Supramolecular Complexes Coupling Polyazine Light Absorbers and Reactive Metal Centers 295 Shamindri M. Arachchige, and Karen J. Brewer I. Introduction 299 A. Light Absorption 300 i. Molecular Photovoltaics 301 ii. Ruthenium Charge Transfer Light Absorbers 301 iii. Osmium Charge Transfer Light Absorbers 303 B. Solar Water Splitting 304 C. Metal Complexes as DNA Targeting Agents 306 D. Supramolecular Charge Transfer Complexes 306 E. Cyclic Voltammetry of Charge Transfer Light Absorbers 308 II. Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers and Rh(III) Reactive Metal Centers 309 A. The Complexes [(bpy)2Ru(BL)RhH2(PPh3)2]3+ 309 i. Redox Properties of [(bpy)2Ru(BL)RhH2(PPh3)2]3+ 309 ii. Spectroscopic Properties of [(bpy)2Ru(BL)RhH2(PPh3)2]3+ 311 iii. Photophysical and Photochemical Properties of [(bpy)2Ru(BL)RhH2(PPh3) 2]3+ 311 B. Cyanide-Bridged Ru(II)-Rh(III) Complexes 312 i. Redox Properties of Cyanide-Bridged Ru(II)-Rh(III) Complexes 312 ii. Spectroscopic Properties of Cyanide-Bridged Ru(II)-Rh(III) Complexes 313 iii. Photophysical and Photochemical Properties of Cyanide-Bridged Ru(II)-Rh(III) Complexes 313 C. Polyazine-Bridged [(bpy)2Ru(dpp)Rh(bPy)25+ 314 i. Redox Properties of [(bpy)2Ru(dpp)Rh(bPy)25+ 314 ii. Spectroscopic Properties of [(bpy)2Ru(dpp)Rh(bpy)25+ 314 iii. Photophysical and Photochemical Properties of [(bpy)2Ru(dpp)Rh(bpy)2 5+ 315 D. Tridentate-Bridged Complexes: [(ttpy)Ru(tpy-(Ph)n-tpy)Rh(ttpy)]5+ (n = 0
2) 315 i. Redox Properties of [(ttpy)Ru(tpy-(Ph)n-tpy)Rh(ttpy)]5+ 316 ii. Spectroscopic Properties of [(ttpy)Ru(tpy-(Ph)n-tpy)Rh(ttpy)]5+ 317 iii. Photophysical and Photochemical Properties of [(ttpy)Ru(tpy-(Ph)n -tpy)Rh(ttpy)]5+ 317 E. Ru(II)-Rh(III) Complexes Bridged with a Flexible Spacer: [(Me2phen)2 Ru(Mebpy-CH2-CH2-Mebpy)Rh(Me 2bpy)2]5+ 319 i. Redox Properties of [(Me2phen)2Ru(Mebpy-CH2-CH2-Mebpy)Rh(Me2bpy)2]5+ 320 ii. Spectroscopic Properties of [(Me2phen)2Ru(Mebpy-CH2-CH2-Mebpy)Rh(Me2 bpy)2]5+ 320 iii. Photochemical and Photophysical Properties of [(Me2phen)2Ru(Mebpy-CH2 -CH2-Mebpy)Rh(Me2bpy)2 ]5+ 321 F. Dendrimeric Ru(II)/Os(II)-Rh(III) Complexes: [M{(dpp)Rh(ppy)2}3](PF6)5 321 i. Redox Properties of [M{(dpp)Rh(ppy)2}3](PF6)5 322 ii. Spectroscopic Properties of [M{(dpp) Rh(ppy)2}3](PF6)5 323 iii. Photophysical and Photochemical Properties of [M{(dpp)Rh(ppy)2}3](PF6 )5 323 G. Extended Supramolecular Architectures with Fe(II)/Ru(II)/Rh(III) 324 H. Stereochemically Defined Tridentate-Bridged Ru(II)-Rh(III) Complex 324 i. Redox Properties of [(tpy)Ru(tppz)RhCl3](PF6)2 325 ii. Spectroscopic Properties of [(tpy)Ru(tppz)RhCl3](PF6)2 326 iii. Photophysical and Photochemical Properties of [(tpy)Ru(tppz)RhCl3](PF 6)2 326 I. Photoinitiated Electron Collection 327 i. LA-BL-Rh-BL-LA Supramolecular Assemblies 328 ii. Redox Properties of LA-BL-Rh-BL-LA 328 iii. Spectroscopic Properties of LA-BL-Rh-BL-LA 330 iv. Photochemical and Photophysical Properties of LA-BL-Rh-BL-LA 331 v. Photoinitiated Electron Collection on a Rhodium Center 332 vi. Photochemistry with LA-BL-Rh-BL-LA Architectures 333 III. Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers to Reactive Pt(II) Metal Centers 338 A. Cyanide-Bridged Ru(II)-Pt(II) Complexes: [(bpy)2(CN)Ru(CN)Pt(dien)](ClO 4)2 and [(dien)Pt(NC)(bpy)2 Ru(CN)Pt(dien)](ClO4)4 338 i. Redox Properties of [(bpy)2(CN)Ru(CN)Pt(dien)](ClO4)2 and [(dien)Pt(NC)(bpy)2Ru(CN)Pt(dien)](ClO4)4 338 ii. Spectroscopic Properties of [(bpy)2(CN)Ru(CN)Pt(dien)](ClO4)2 and [(dien)Pt(NC)(bpy)2 Ru(CN)Pt(dien)](ClO4)4 339 iii. Photochemical and Photophysical Properties of [(bpy)2 (CN)Ru(CN)Pt(dien)](ClO4)2 and [(dien)Pt(NC)(bpy)2Ru(CN)Pt(dien)](ClO4)4 339 B. A Ru(II)-Pt(II) Complex as a Chemodosimeter 340 C. Ru(II)-Pt(II) Complexes Bridged by Flexible Spacers 341 i. Redox Properties of [(bpy)2Ru(Mebpy-CH2-CH2-Mebpy)PtCl2](PF6)2 341 ii. Spectroscopic Properties of [(bpy)2Ru(Mebpy-CH2-CH2-Mebpy)PtCl2](PF6)2 341 D. A bpm-Bridged Ru(II)-Pt(II) Complex: [(bpy)2Ru(bpm)PtCl2]2+ 342 i. Redox Properties of [(bpy)2Ru(bpm)PtCl2]2+ 342 ii. Spectroscopic Properties of [(bpy)2Ru(bpm)PtCl2]2+ 343 E. Ru(II)-Pt(II) dpp-Bridged Complexes: [(bpy)2Ru(dpp)PtMe2]2+ and [(bpy)2 Ru(dpp)PtCl2]2+ 343 i. Redox Properties of [(bpy)2Ru(dpp)PtMe2]2+ and [(bpy)2Ru(dpp)PtCl2]2+ 343 ii. Spectroscopic Properties of [(bpy)2Ru(dpp)PtMe2]2+ and [(bpy)2 Ru(dpp)PtCl2]2+ 344 iii. Photophysical and Photochemical Properties of [(bpy)2Ru(dpp)PtMe2]2+ and [(bpy)2Ru(dpp)PtCl2]2+ 344 F. Ru(II)-Pt(II) Complexes Bridged by a BL Ligand with Two Inequivalent Sites 345 i. Redox Properties of [(bpy)2Ru(AB)PtCl2](PF6)2 and [(bpy)2Ru(BA)PtCl2 ](PF6)2 345 ii. Spectroscopic Properties of [(bpy)2Ru(AB)PtCl2](PF6)2 and [(bpy)2 Ru(BA)PtCl2](PF6)2 346 iii. Photophysical and Photochemical Properties of [(bpy)2Ru(AB)PtCl2](PF6 )2 and [(bpy)2 Ru(BA)PtCl2 ](PF6)2 346 G. DNA Binding of the Ru(II)-Pt(II) Complex: [(tpy)Ru(dtdeg)PtCl]Cl3 347 H. Ru(II)-Pt(II) Complexes with Amino Linkages: [(bpy)2Ru(BL)PtCl2](PF6)2 (BL = bpy(CONH(CH2)3NH2)2 and phenNHCO(COOHbpy)) 347 i. Photophysical Properties and DNA Binding Ability of [(bpy)2Ru(BL)PtCl2 ](PF6)2 348 ii. Photophysical Properties and Photocatalytic Activity of [(bpy)2 Ru(BL)PtCl2](PF6)2 348 I. Systematic Studies of Ru(II)/Os(II)-Pt(II) Complexes with Polyazine Bridging Ligands 349 i. Redox Properties [(bpy)2M(BL)PtCl2](PF6)2 349 ii. Spectroscopic Properties of [(bpy)2M(BL)PtCl2](PF6)2 351 iii. DNA Binding by [(bpy)2M(dpb)PtCl2](PF6)2 353 J. Dendrimeric Ru(II)-Pt(II) Complexes Bridged by Polyazine Bridging Ligands 354 i. Redox and Spectroscopic Properties of [Ru{(dpq) (PtCl2)}3](PF6)2 354 ii. Multifunctional DNA Binding and Photocleavage Agent: [{(bpy)2Ru(dpp)}2 Ru(dpp)PtCl2](PF6)6 355 IV. Supramolecular Complexes Coupling Ru(II) Polyazine Light Absorbers to Reactive Pd(II) Metal Centers 356 A. Ru(II)-Pd(II) Complexes Bridged by dpp and bpm Ligands: [(bpy)2 Ru(dpp)PdCl2](PF6)2 and [(bpy)2 Ru(bpm)PdCl2](ClO4)2 356 i. Redox Properties of [(bpy)2Ru(dpp)PdCl2](PF6)2 and [(bpy)2 Ru(bpm)PdCl2 ](ClO4)2 356 ii. Spectroscopic Properties of [(bpy)2Ru(dpp)PdCl2](PF6)2 and [(bpy)2 Ru(bpm)PdCl2](ClO4)2 356 B. Ru(II)-Pd(II) Complexes Bridged by an Extended Polyazine Ligand: [(tBu2 bpy)2Ru(tpphz)PdCl2](PF6)2 357 i. Spectroscopic Properties of [(tBu2bpy)2Ru(tpphz)PdCl2](PF6)2 358 C. Ru(II)-Pd(II) Complexes Bridged by bpm type Ligands: [(bpy)2 Ru(BL)PdMeCl]2+ 358 D. A Ru(II)-Pd(II) Complex Bridged by a Flexible Polyazine Bridging Ligand: [(bpy)2Ru(DMB)PdCl2]2+ 359 i. Redox and Spectroscopic Properties of (bpy)2Ru(DMB)PdCl2]2+ 359 ii. Photochemistry of [(bpy)2Ru(DMB)PdCl2]2+ 359 V. Conclusions 364 VI. Acknowledgments 366 VII. References 366 8. Supramolecular Hybrid Materials-Integrating Functionality with Sensing 369 Ramo
n Mart
nez-Män
ez, Fe
lix Sanceno
n, Ana Bele
n Descalzo, and Knut Rurack I. Introduction 370 II. Enhanced Coordination by Preorganization. Surface Chelate Effect and Signaling 371 III. Enhanced Signaling by Preorganization 378 IV. Assembly-Disassembly 381 V. Selectivity by Polarity and Size. Biomimetic Signaling 386 VI. Switching, Gating and Signaling 391 VII. Conclusions 399 VIII. Acknowledgments 400 IX. References 400 9. Molecular Recognition Process between Nucleobases and Metal-Oxalato Frameworks 407 Oscar Castillo, Antonio Luque, Juan P. Garc
á-Terän, and Pilar Amo-Ochoa I. Introduction 408 A. Molecular Recognition 408 B. Nucleobases 409 C. Oxalate 412 II. Metal-Oxalato-Nucleobase Extended Systems 413 III. Other metal-nucleobase 1D Extended Systems 427 VI. Hybrid Systems Based on Metal-Oxalato and Protonated Nucleobases 433 V. Conclusions 443 VI. References 443 10. Crystal Engineering of Coordination Polymers 451 Marius Andruh, and Catalina Ruiz-Pe
rez I. Introduction 452 II. Synthetic Approaches 453 A. The Node-and-Spacer Paradigm 454 i. Bridging ligands 455 ii. Oligonuclear Complexes as Nodes 461 a. Alkoxo-Bridged Binuclear Copper(II) Complexes as Nodes 463 b. Homobinuclear Complexes with Compartmental Ligands as Nodes 468 c. Heterobinuclear Complexes as Node 473 d. Heterotrimetallic Coordination Polymers 478 B. Flexible Ligand Approach: Polycarboxylates as Anionic Linkers. A Case Study-Malonato Complexes 479 i. Dicarboxylates 480 ii. The Case of Malonate. 482 iii. Influence of the synthetic conditions 482 iv. The use of co-ligands 489 v. Ligand Adaptation 493 vi. Perspectives 497 C. The Building-Block Approach 497 i. Oxalato-Bridged Coordination Ploymers 498 ii. Bisoxamidato Complexes as Building Blocks 501 iii. Cyano-Bridged Coordination Polymers 501 III. Conclusions and Perspectives 505 IV. Acknowledgments 506 V. References 506 Index 513