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By means of luminescent method the new ¿ "insulating" ¿ mechanism of supersensitization of silver halide photographic materials hydrophobic compounds is studied and reasonable. The monograph consists of introduction, four chapters and the conclusion. In chapter 1 the short literary overview of experimental results on influence of electric fields on sensitivity of photographic materials is given and the theory of ionization of semiconductors is stated. Also questions of increase in efficiency of spectral sensitization of silver halide photographic materials are considered. In chapter 2 the test aggregate and the measuring technique of luminescent spectrums of silver halides is described. Besides, justification of application of luminescent method as research tool is given.Experimental results on the electroinduced luminescence of silver halides and also their discussion are given in the chapter 3.In chapter 4 results of research of the "insulating" mechanism of supersensitization of silver halide photographic materials are described. In the conclusion short conclusions by the main results of work are given.