Mixed Schiff ¿Base Complexes of Cu & Ni - Bani Mustafa, Ashraf
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Reactions were carried out on Schiff bases derived from condensation of 2-hydroxynaphthaldehyde or salicylaldehyde with 2-aminophenol and 8-aminoquinoline. The Schiff bases were reacted with Ni(II) and Cu(II) metal ions in presence of diamines as 2,2'-dipyridyl or 1,10-phenathroline or S-donor anion as thiophenolate. The used Schiff bases were N-salicylidene-8-aminoquinoline (HQS), N-2-hydroxynaphthalidene-8-aminoquinoline (HQN), N-2-hydroxynaphthalidene-2-aminophenol (H2PN) and N-salicylidene-2-aminophenol (H2PS). The complexes were found to have the general formulas [M(SB)(N-N)] ,…mehr

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Produktbeschreibung
Reactions were carried out on Schiff bases derived from condensation of 2-hydroxynaphthaldehyde or salicylaldehyde with 2-aminophenol and 8-aminoquinoline. The Schiff bases were reacted with Ni(II) and Cu(II) metal ions in presence of diamines as 2,2'-dipyridyl or 1,10-phenathroline or S-donor anion as thiophenolate. The used Schiff bases were N-salicylidene-8-aminoquinoline (HQS), N-2-hydroxynaphthalidene-8-aminoquinoline (HQN), N-2-hydroxynaphthalidene-2-aminophenol (H2PN) and N-salicylidene-2-aminophenol (H2PS). The complexes were found to have the general formulas [M(SB)(N-N)] , [M(SB)(N-N)AcO].XH2O and [M(QN)(SPh)], where M is Cu(II) or Ni(II), SB is the Schiff base and N-N is 2,2-'dipyridyl or 1,10-phenathroline. All complexes were characterized by elemental analysis, infrared spectroscopy, UV-visible spectroscopy, electrical conductivity and magnetic susceptibility measurements.
Autorenporträt
Mr.Ashraf Naim Bani Mustafa has M.A. degree in Inorganic Chemistry specialization from Al-Yarmouk University in 2010. Interested in Mixed Schiff-Base Complexes - Synthesis and Characterization. He is a member of Jordanian Chemical Society.