Mössbauer Spectroscopy
Applications in Chemistry, Biology, and Nanotechnology
Herausgegeben von Sharma, Virender K.; Klingelhofer, Gostar; Nishida, Tetsuaki
Mössbauer Spectroscopy
Applications in Chemistry, Biology, and Nanotechnology
Herausgegeben von Sharma, Virender K.; Klingelhofer, Gostar; Nishida, Tetsuaki
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Providing a modern update of the field, Mossbauer Spectroscopy focuses on applications across a broad range of fields, including analysis of inorganic elements, nanoparticles, metalloenzymyes, biomolecules (including proteins), glass, coal, and iron. Ideal for a broad range of scientists, this one-stop reference presents advances gained in the field over past two decades, including a detailed theoretical description of Mossbauer spectroscopy, an extensive treatment of Mossbauer spectroscopy in applied areas, and challenges and future opportunities for the further development of this…mehr
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A one-stop reference for determining the oxidation states of elements so that oxidation eduction chemistry can be studied across a wide variety of systems, this book presents advances in the field from the last two decades. Beginning with a detailed theoretical description of Mossbauer spectroscopy, followed by an extensive treatment of its use in applied areas such as synchrotron radiation, biotechnology, and nanoparticle analysis, the book discusses future opportunities for the further development of this technique. Designed for spectroscopists, inorganic, physical, analytical, and solid-state chemists and other researchers.
- Produktdetails
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 672
- Erscheinungstermin: 28. Oktober 2013
- Englisch
- Abmessung: 279mm x 224mm x 38mm
- Gewicht: 1800g
- ISBN-13: 9781118057247
- ISBN-10: 1118057244
- Artikelnr.: 33271654
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 672
- Erscheinungstermin: 28. Oktober 2013
- Englisch
- Abmessung: 279mm x 224mm x 38mm
- Gewicht: 1800g
- ISBN-13: 9781118057247
- ISBN-10: 1118057244
- Artikelnr.: 33271654
Synchrotron Radiation on Thin Films 3 S Stankov, T Zl'zak, M Zajc, M
Zl'zak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J
Aa ewski, K ParliDski, and J Korecki 1 1 Introduction 3 References 39
Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence
States of Ironin the Earth's Lower Mantle 43 Jung-Fu Lin, Zhu Mao, and
Ercan E Alp Acknowledgments 55 References 55 Chapter 3 In-beam Mössbauer
Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58
Yoshio Kobayashi 3 .4 Summary 66 References 67 Part II Radionuclides 71
Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of
Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73
Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda
Conclusion 92 References 93 Chapter 5 Mössbauer and Magnetic Study of
Neptunyl(+1) Complexes 95 T Nakamoto, A Nakamura and M Takeda Conclusion
113 Acknowledgment 113 References 113 Chapter 6 Mössbauer Spectroscopy of
161Dy in Dysprosium Dicarboxylates 116 M Takahashi, C I Wynter, B R
Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M
Takeda, and E Brown Acknowledgment 122 References 122 Chapter 7 Study of
Exotic Uranium Compounds using 238U Mössbauer Spectroscopy 123 Satoshi
Tsutsui 1,2 and Masami Nakada 1 Summary 137 Acknowledgment 138 References
138 Part III Spin Dynamics 141 Chapter 8 Reversible Spin-state Switching
Involving a Structural Change 143 Satoru Nakashima References 151 Chapter 9
Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge
152 N Kokima and A Sugahara 9 3 Charge Transfer Phase Transition 161 9 4
Spin Equilibrium and Succeeding Phenomena 168 References 175 Chapter 10
Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin
State 177 Mikio Nakamura and Masashi Takahashi Acknowledgments 198
References 199 Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on
Structures and Properties, and Mössbauer Spectroscopic Properties 202
Georges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar
216 Acknowledgments 243 References 243 Part IV Biological Applications 247
Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering:
Applications to Bioinorganic Chemistry 249 Yisong Guo, Yoshitaka Yoda,
Xiaowei Zhang, Yuming Xiao, Stephen P Cram Acknowledgment 269 References
269 Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research
272 Alexander A Kamnev,*, Krisztina Kovács, Irina V Alenkina, and Michael
I. Oshtrakh Acknowledgments 287 References 287 Chapter 14 Controlled
Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292 Vladimir
I Vysotskii and Alla A Kornilova References 314 Chapter 15 Natural's
Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of
High-Valent Fe Intermediates 315 Kednerlin Dornevil and Aimin Liu
References 322 Chapter 16 Iron in Neurodegeneration 324 Jolanta
GaBzka-Friedman, Erika R Bauminger, and Andrzej Friedman References 331
Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related
Applications, Potentials and Prospects 333 Alexander A Kamnev
Acknowledgments 345 References 346 Part V Iron Oxides 349 Chapter 18
Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal
Processes 351 JiYí Tu ek, Libor Machala, JiYí Frydrych, JiYí Pechousek, and
Radek ZboYil Acknowledgment 389 References 389 Chapter 19 Transmission and
Emission 57Fe Mössbauer Studies on Perovskites and Related Oxide Systems
393 Zoltán Homonnay and Zoltán Németh References 413 Chapter 20 Enhancing
the Possibilities of 57Fe Mössbauer Spectrometry to Study the Inherent
Properties of Rust Layers 415 Karen E García, César A Barrero, Alvaro L
Morales, and Jean-Marc Greneche Acknowledgments 426 References 426 Chapter
21 Application of Mössbauer Spectroscopy in Nanomagnetics 429 Lakshmi
Nambakkat Conclusion 452 Acknowledgment 453 References 453 Chapter 22
Mössbauer Spectroscopy and Surface Analysis 455 José F Marco, J Ramón
Gancedo, Matteo Monti and Juan de la Figuera Acknowledgments 468 References
468 Chapter 23 57Fe Mössbauer Spectroscopy in the Investigation of the
Precipitation of Iron Oxides 470 Svetozar Music, Mira Ristic, and Stjepko
Krehula Acknowledgment 496 References 497 Chapter 24 Ferrates (IV, V, and
VI): Mössbauer Spectroscopy Characterization 505 Virender K Sharma, Yurii
Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter Acknowledgments
517 References 517 Chapter 25 Characterization of Dilute Iron-Doped Yttrium
Aluminum Garnets by Mössbauer Spectrometry 521 Kiyoshi Nomura and Zoltán
Németh Conclusion 531 Acknowledgment 532 References 532 Part VI Industrial
Applications 533 Chapter 26 Some Mössbauer Studies of Fe-As Based High
Temperature Superconductors 535 Amar Nath and Airat Khasanov Acknowledgment
541 References 541 Chapter 27 Mossbauer Study of New Electrically
Conductive Glass 542 Tetsuaki Nishida and Shiro Kubuki Acknowledgments 551
References 551 Chapter 28 Applications of Mössbauer Spectroscopy in the
Study of Lithium Battery Materials 552 Ricardo Alcántara, Pedro Lavela,
Carlos Pérez Vicente, José L Tirado Conclusions 561 Acknowledgment 561
References 562 Chapter 29 Mössbauer Spectroscopic Investigations of Novel
Bimetal Catalysts for Preferential CO Oxidation in H2 564 Wansheng Zhang,
Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang Conclusion 574 Acknowledgments
574 References 575 Chapter 30 The use of Mossbauer Spectroscopy in Coal
Research-Is it Relevant or Not? 576 F B Waanders Conclusions 590 References
591 Part VII Environmental Applications 593 Chapter 31 Water Purification
and Characterization of Recycled Iron-Silicate Glass 595 Shiro Kubuki and
Tetsuaki Nishida Reference 606 Chapter 32 Mössbauer Spectroscopy in the
Study of Laterite Mineral Processing 608 Eamonn Devlin, Michail Samouhos,
Charalabos Zografidis Reference 619 Index 621
Synchrotron Radiation on Thin Films 3 S Stankov, T Zl'zak, M Zajc, M
Zl'zak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J
Aa ewski, K ParliDski, and J Korecki 1 1 Introduction 3 References 39
Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence
States of Ironin the Earth's Lower Mantle 43 Jung-Fu Lin, Zhu Mao, and
Ercan E Alp Acknowledgments 55 References 55 Chapter 3 In-beam Mössbauer
Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58
Yoshio Kobayashi 3 .4 Summary 66 References 67 Part II Radionuclides 71
Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of
Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73
Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda
Conclusion 92 References 93 Chapter 5 Mössbauer and Magnetic Study of
Neptunyl(+1) Complexes 95 T Nakamoto, A Nakamura and M Takeda Conclusion
113 Acknowledgment 113 References 113 Chapter 6 Mössbauer Spectroscopy of
161Dy in Dysprosium Dicarboxylates 116 M Takahashi, C I Wynter, B R
Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M
Takeda, and E Brown Acknowledgment 122 References 122 Chapter 7 Study of
Exotic Uranium Compounds using 238U Mössbauer Spectroscopy 123 Satoshi
Tsutsui 1,2 and Masami Nakada 1 Summary 137 Acknowledgment 138 References
138 Part III Spin Dynamics 141 Chapter 8 Reversible Spin-state Switching
Involving a Structural Change 143 Satoru Nakashima References 151 Chapter 9
Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge
152 N Kokima and A Sugahara 9 3 Charge Transfer Phase Transition 161 9 4
Spin Equilibrium and Succeeding Phenomena 168 References 175 Chapter 10
Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin
State 177 Mikio Nakamura and Masashi Takahashi Acknowledgments 198
References 199 Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on
Structures and Properties, and Mössbauer Spectroscopic Properties 202
Georges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar
216 Acknowledgments 243 References 243 Part IV Biological Applications 247
Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering:
Applications to Bioinorganic Chemistry 249 Yisong Guo, Yoshitaka Yoda,
Xiaowei Zhang, Yuming Xiao, Stephen P Cram Acknowledgment 269 References
269 Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research
272 Alexander A Kamnev,*, Krisztina Kovács, Irina V Alenkina, and Michael
I. Oshtrakh Acknowledgments 287 References 287 Chapter 14 Controlled
Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292 Vladimir
I Vysotskii and Alla A Kornilova References 314 Chapter 15 Natural's
Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of
High-Valent Fe Intermediates 315 Kednerlin Dornevil and Aimin Liu
References 322 Chapter 16 Iron in Neurodegeneration 324 Jolanta
GaBzka-Friedman, Erika R Bauminger, and Andrzej Friedman References 331
Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related
Applications, Potentials and Prospects 333 Alexander A Kamnev
Acknowledgments 345 References 346 Part V Iron Oxides 349 Chapter 18
Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal
Processes 351 JiYí Tu ek, Libor Machala, JiYí Frydrych, JiYí Pechousek, and
Radek ZboYil Acknowledgment 389 References 389 Chapter 19 Transmission and
Emission 57Fe Mössbauer Studies on Perovskites and Related Oxide Systems
393 Zoltán Homonnay and Zoltán Németh References 413 Chapter 20 Enhancing
the Possibilities of 57Fe Mössbauer Spectrometry to Study the Inherent
Properties of Rust Layers 415 Karen E García, César A Barrero, Alvaro L
Morales, and Jean-Marc Greneche Acknowledgments 426 References 426 Chapter
21 Application of Mössbauer Spectroscopy in Nanomagnetics 429 Lakshmi
Nambakkat Conclusion 452 Acknowledgment 453 References 453 Chapter 22
Mössbauer Spectroscopy and Surface Analysis 455 José F Marco, J Ramón
Gancedo, Matteo Monti and Juan de la Figuera Acknowledgments 468 References
468 Chapter 23 57Fe Mössbauer Spectroscopy in the Investigation of the
Precipitation of Iron Oxides 470 Svetozar Music, Mira Ristic, and Stjepko
Krehula Acknowledgment 496 References 497 Chapter 24 Ferrates (IV, V, and
VI): Mössbauer Spectroscopy Characterization 505 Virender K Sharma, Yurii
Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter Acknowledgments
517 References 517 Chapter 25 Characterization of Dilute Iron-Doped Yttrium
Aluminum Garnets by Mössbauer Spectrometry 521 Kiyoshi Nomura and Zoltán
Németh Conclusion 531 Acknowledgment 532 References 532 Part VI Industrial
Applications 533 Chapter 26 Some Mössbauer Studies of Fe-As Based High
Temperature Superconductors 535 Amar Nath and Airat Khasanov Acknowledgment
541 References 541 Chapter 27 Mossbauer Study of New Electrically
Conductive Glass 542 Tetsuaki Nishida and Shiro Kubuki Acknowledgments 551
References 551 Chapter 28 Applications of Mössbauer Spectroscopy in the
Study of Lithium Battery Materials 552 Ricardo Alcántara, Pedro Lavela,
Carlos Pérez Vicente, José L Tirado Conclusions 561 Acknowledgment 561
References 562 Chapter 29 Mössbauer Spectroscopic Investigations of Novel
Bimetal Catalysts for Preferential CO Oxidation in H2 564 Wansheng Zhang,
Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang Conclusion 574 Acknowledgments
574 References 575 Chapter 30 The use of Mossbauer Spectroscopy in Coal
Research-Is it Relevant or Not? 576 F B Waanders Conclusions 590 References
591 Part VII Environmental Applications 593 Chapter 31 Water Purification
and Characterization of Recycled Iron-Silicate Glass 595 Shiro Kubuki and
Tetsuaki Nishida Reference 606 Chapter 32 Mössbauer Spectroscopy in the
Study of Laterite Mineral Processing 608 Eamonn Devlin, Michail Samouhos,
Charalabos Zografidis Reference 619 Index 621