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This monograph is devoted to one of the actual directions in modern silicate production - autoclave technologies of creation and processing of silicate materials. One of the effective ways to solve this issue is the development of autoclave binder technology, which allows producing products based on lime-silica binders in a few hours without the use of cumbersome firing process. The revealed regularities "composition-structure-property" during autoclaving of lime-silica binders containing the mentioned additives make a certain contribution into development of chemistry and technology of autoclave curing materials.