Name Reactions for Homologation, Part 1

Herausgeber: Li, Jie Jack

• Gebundenes Buch

Produktbeschreibung

"A valuable addition to the literature by any measure and surely will prove its merit in years to come. The new knowledge that arises with its help will be impressive and of great benefit to humankind." --From the Foreword by E. J. Corey, Nobel Prize Laureate An invaluable guide to name reactions and reagents for homologations Name Reactions for Homologations, Part I of Wiley's Comprehensive Name Reactions series comprises a comprehensive treatise on name reactions for homologations. With contributions from world-recognized authorities in the field, this reference offers an up-to-date, concise compilation of the most commonly used and widely known name reactions and reagents. Part I discusses Organometallics, Carbon-chain Homologation, and Radical Chemistry. Arranged alphabetically by name reactions, the listing provides: * Description of the reaction * Historical perspective * A mechanism for the reaction * Variations and improvements on the reaction * Synthetic utilities of the reaction * Experimental details * References to the current primary literature Armed with this invaluable resource, both students and professionals will have at their fingertips a comprehensive guide to important mechanisms and phenomena in homologation.

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Produktdetails

• Verlag: Wiley
• Seitenzahl: 732
• Erscheinungstermin: 1. April 2009
• Englisch
• Abmessung: 236mm x 193mm x 43mm
• Gewicht: 1406g
• ISBN-13: 9780470085073
• ISBN-10: 047008507X
• Artikelnr.: 29930995

Autorenporträt

Jie Jack Li is a chemist at Bristol-Myers Squibb Company. He received his BS from Nanjing University and his PhD in organic chemistry at Indiana University. Dr. Li completed a postdoctoral fellowship at MIT. He is coauthor of various books, including Name Reactions in Heterocyclic Chemistry, Contemporary Drug Synthesis, Name Reactions for Functional Group Transformations, Name Reactions for Homologations, Parts I and II, Name Reactions on Ring Formations, and The Art of Drug Synthesis, all published by Wiley.

Inhaltsangabe

Foreword.
Preface.
Contributing Authors.
Chapter 1: Organometallics.
Section 1.1 Palladium Chemistry.
Section 1.2 Organocopper Reagents.
Section 1.3 Other Organometallic Reagents.
Chapter 2: Carbon-Chain Homologations.
2.1 Arndt-Eistert homologation.
2.2 Morita-Baylis-Hillman reaction.
2.3 Benzoin condensation.
2.4 Corey-Fuchs reaction.
2.5 Henry reaction.
2.6 Horner-Wadsworth-Emmons reaction.
2.7 Julia-Lythgoe olefination.
2.8 Knoevenagel condensation.
2.9 Mukaiyama aldol reaction.
2.10 Peterson olefination.
2.11 Sakurai allylation reaction.
2.12 Stetter reaction.
2.13 Wittig reaction.
Chapter 3: Radical Chemistry.
3.1 Barton-McCombie deoxygenation.
3.2 Barton nitrite photolysis.
3.3 Sandmeyer reaction.
3.4 Wohl-Ziegler reaction.
Appendixes.
Appendix 1, Table of Contents for Volume 1: Name Reactions in Heterocyclic
Chemistry.
Appendix 2, Table of Contents for Volume 2: Name Reactions for Functional
Group Transformations.
Appendix 3, Table of Contents for Volume 4: Name Reactions for
Homologations-2.

Rezensionen

Applied Organometallic Chemistry"Jack Li and his illustrious team of chemists have done it again.It is hard to imagine how one could organize and categorize a topicso broad as "homologation" reactions. These are some of the breadand butter transforms of organic chemistry ? reactions that arefundamentally important to the practice of chemical synthesis. Thistwo book series is masterfully organized and easy to use both as areference work for the classroom and a springboard forpractitioners to rapidly apply these reactions in the laboratory.The extensive coverage of these critical reactions, including ahistorical perspective, mechanism, synthetic utility, and actualexperimental details will ensure that these books will be on theshelf of every serious organic chemist for years to come."

--Phil S. Baran, The Scripps Research Institute