This book reviews the key issues in processing and characterization of nanoscale ferroelectrics and multiferroics, and provides a comprehensive description of their properties, with an emphasis in differentiating size effects of extrinsic ones like boundary or interface effects. Dieses Buch beleuchtet die wichtigsten Aspekte der Verarbeitung und Charakterisierung von Ferroelektrika und Multiferroika auf Nanoebene, präsentiert eine umfassende Beschreibung der jeweiligen Eigenschaften und legt dabei den Schwerpunkt auf die Unterscheidung von Größeneffekten bei extrinsischen Eigenschaften wie…mehr
This book reviews the key issues in processing and characterization of nanoscale ferroelectrics and multiferroics, and provides a comprehensive description of their properties, with an emphasis in differentiating size effects of extrinsic ones like boundary or interface effects.Dieses Buch beleuchtet die wichtigsten Aspekte der Verarbeitung und Charakterisierung von Ferroelektrika und Multiferroika auf Nanoebene, präsentiert eine umfassende Beschreibung der jeweiligen Eigenschaften und legt dabei den Schwerpunkt auf die Unterscheidung von Größeneffekten bei extrinsischen Eigenschaften wie Rand- oder Interface-Effekte. Eingegangen wird auch auf neuartige Nanoebene. Das Fachbuch ist in drei Abschnitte unterteilt und beschreibt die Verarbeitung (Nanostrukturierung), Charakterisierung (nanostrukturierter Materialien) und Nanoeffekte. Unter Rückgriff auf die Synergien zwischen Nano-Ferroelektrika und -Multiferroika werden Materialien behandelt, die auf allen Ebenen einer Nanostrukturierung unterzogen werden, von Technologien für keramische Materialien wie ferroelektrische Nanopulver, nanostrukturierte Keramiken und Dickschichten sowie magnetoelektrische Nanokomposit-Materialien bis hin zu freistehenden Nanoobjekten mit spezifischen Geometrien wie Nanodrähte und Nanoröhren auf verschiedenen Entwicklungsstufen. Grundlage des Buches ist die europäische Wissensplattform im Wissenschaftsbereich innerhalb der Aktion von COST (Europäische Zusammenarbeit in Wissenschaft und Technik) zu ein- und mehrphasigen Ferroika und Multiferroika mit begrenzten Geometrien (SIMUFER, Ref. MP0904). Die Autoren der Kapitelbeiträge wurden sorgfältig ausgewählt, haben allesamt ganz wesentlich zur Wissensbasis für das jeweilige Thema beigetragen und gehören vor allem zu den renommiertesten Wissenschaftlern des Fachgebiets.Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Dr Miguel Algueró is Senior Researcher at Instituto de Ciencia de Materiales de Madrid (ICMM), of Consejo Superior de Investigaciones Científicas (CSIC), Spain. He is a material scientist with a strong expertise in ferroelectrics, mainly for piezoelectric applications, from which he approached the resurgent field of multiferroics. His research interest covers all ceramics and thin films, processing and properties with an emphasis on nanostructuring issues and size effects at the nanoscale. Professor J. Marty Gregg holds a chair in the School of Mathematics and Physics at Queen's University Belfast, UK. His current research interests are in the experimental exploration of the behaviour of ferroelectrics at reduced dimensions and in nanoshapes of complex morphology. He has co-organized various symposia including symposa E- Metal Oxide Nanostructures (EMRS, Strasbourg, 2009), Functional Ceramic Materials and Devices (EUROMAT 2009), and the International Symposium on Integrated Ferroelectrics held in Edinburgh in 2010. Professor Liliana Mitoseriu is based at the Faculty of Physics, University "Alexandru Ioan Cuza" Iasi, Romania. Prof. Mitoseriu has co-authored 130 peer reviewed papers in the field of ferroelectric and multiferroic oxides. She has written six books for students (in Romanian) and edited two international books addressing modern topics in Electroceramics. She is currently the Chair of the FP7-ESF-COST Action MP0904 Single- and multiphase ferroics and multiferroics with restricted geometries, and the major outputs are presented in this book.
Inhaltsangabe
Preface List of Contributors Why nanoscale ferroelectrics and multiferroics? Miguel Algueró, J. Marty Gregg and Liliana Mitoseriu Part A Nanostructuring: bulk 1 Incorporation mechanism and functional properties of Ce-doped BaTiO3 ceramics derived from nanopowders prepared by the modified-Pechini method Adelina-Carmen Ianculescu, Daniela C. Berger, Catalina A. Vasilescu, Marius Olariu, Bogdan S. Vasile, Lavinia P. Curecheriu, Andreja Gajovi and Roxana Trüc 2 Synthesis and ceramic nanostructuring of ferroic and multiferroic low tolerance factor perovskite oxides Teresa Hungria, Covadonga Correas and Alicia Castro 3 Core-shell heterostructures: from particle synthesis to bulk dielectric, ferroelectric and multiferroic composite materials Vincenzo Buscaglia and Maria Teresa Buscaglia 4 Modeling of colloidal suspensions for the synthesis of the ferroelectric oxides with complex chemical composition Gregor Trefalt, Bosiljka Tadi and Barbara Mali Nanostructuring: thin films 5 Self-assemblage and patterning of thin film ferroic nanostructures Theodor Schneller 6 Thin film porous ferroic nanostructures: Strategies and characterization Alichandra Castro, Paula Ferreira, Stella Skiadopoulou, Paula M. Vilarinho, Liliana P. Ferreira, Margarida Godinho and Brian J. Rodriguez 7 Low-temperature photo-chemical solution deposition of ferroelectric and multiferroic thin films Christopher De Dobbelaere, An Hardy, Marlies K. Van Bael, Iñigo Bretos, Ricardo Jiménez and M. Lourdes Calzada Nanostructuring: fibers and wires 8 Synthesis and properties of ferroelectric nanotubes and nanowires. A review Vincenzo Buscaglia and Maria Teresa Buscaglia 9 Fabrication of one dimensional ferroelectric nano and micro structures by different spinning techniques and their characterization Tony Lusiola and Frank Clemens PART B Characterization (of the nanostructured materials): crystal structure 10 Structural characterization of ferroelectric and multiferroic nanostructures by advanced TEM techniques Etienne Snoeck, Axel Lubk and César Magén 11 Raman spectroscopy of nanostructured ferroelectric materials Marco Deluca and Andreja Gajovic 12 Neutron and synchrotron X-ray scattering studies of bulk and nanostructured multiferroic and ferroelectric materials Evagelia G. Moshopoulou, Pascale Foury-Leylekian, Katharine Page, C. Doubrovsky, Martha Greenblatt and Alan J. Hurd Characterization (of the nanostructured materials): domains 13 Advanced characterization of multiferroic materials by scanning probe methods and scanning electron microscopy Michael R. Koblischka and Anjela Koblischka-Veneva 14 Electrostatic and Kelvin probe force microscopy for domain imaging of ferroic systems Brian J. Rodriguez PART C Nanoscale effects: bulk properties 15 Nanostructured barium titanate ceramics. Intrinsic vs. extrinsic size effects Liliana Mitoseriu and Lavinia P. Curecheriu 16 The effects of ceramic nanostructuring in high sensitivity piezoelectrics Harvey Amorín, Ricardo Jiménez, Jesús Ricote, Alicia Castro and Miguel Algueró 17 Correlation between microstructure and electrical properties of ferroelectric relaxors J.D. Bobic, J. Macutkevic, R. Grigalaitis, Maksim Ivanov, M.M. Vijatovic Petrovic, Juras Banys and Biljana D. Stojanovic 18 Local field engineering approach for tuning dielectric and ferroelectric properties in nanostructured ferroelectrics and composites Leontin Padurariu and Liliana Mitoseriu Nanoscale effects: thin film properties 19 Ferroelectric phase transitions in epitaxial perovskite films Marina Tyunina 20 Interfaces in epitaxial ferroelectric layers/multilayers and their effect on the macroscopic electrical properties Lucian Pintilie, Andra G. Boni, Cristina Chirila, Luminita M. Hrib, Alin Iuga, Lucian Trupina, Ioana Pintilie, Iuliana Pasuk, Raluca Negrea, Corneliu Ghica, Mihaela Botea, Nicoleta Apostol and Cristian M. Teodorescu 21 Electric-field control of magnetism based on elastically coupled ferromagnetic and ferroelectric domains Kévin J. A. Franke, Tuomas H. E. Lahtinen, Arianna Casiraghi, Diego López González, Sampo J. Hämäläinen and Sebastiaan van Dijken Nanoscale effects: novel phenomena and applications 22 Ferroelectric vortices and related configurations Sergei Prosandeev, Ivan I. Naumov, Huaxiang Fu, Laurent Bellaiche, Michael P. D. Campbell, Raymond G. P. McQuaid, Li-Wu Chang, Alina Schilling, Leo. J. McGilly, Amit Kumar and J. Marty Gregg 23 Reentrant phenomena in relaxors Alexei A. Bokov and Zuo-Guang Ye 24 Functional twin boundaries: Multiferroicity in confined spaces Ekhard. K. H. Salje and Xiangdong Ding 25 Novel approaches for genuine single phase room temperature magnetoelectric multiferroics Lynette Keeney, Michael Schmidt, Andreas Amann, Tuhin Maity, Nitin Deepak, Ahmad Faraz, Nikolay Petkov, Saibal Roy, Martyn E. Pemble and Roger W. Whatmore 26 Semiconducting and photovoltaic ferroelectrics and multiferroics Andrew R. Akbashev and Jonathan E Spanier Index
Preface List of Contributors Why nanoscale ferroelectrics and multiferroics? Miguel Algueró, J. Marty Gregg and Liliana Mitoseriu Part A Nanostructuring: bulk 1 Incorporation mechanism and functional properties of Ce-doped BaTiO3 ceramics derived from nanopowders prepared by the modified-Pechini method Adelina-Carmen Ianculescu, Daniela C. Berger, Catalina A. Vasilescu, Marius Olariu, Bogdan S. Vasile, Lavinia P. Curecheriu, Andreja Gajovi and Roxana Trüc 2 Synthesis and ceramic nanostructuring of ferroic and multiferroic low tolerance factor perovskite oxides Teresa Hungria, Covadonga Correas and Alicia Castro 3 Core-shell heterostructures: from particle synthesis to bulk dielectric, ferroelectric and multiferroic composite materials Vincenzo Buscaglia and Maria Teresa Buscaglia 4 Modeling of colloidal suspensions for the synthesis of the ferroelectric oxides with complex chemical composition Gregor Trefalt, Bosiljka Tadi and Barbara Mali Nanostructuring: thin films 5 Self-assemblage and patterning of thin film ferroic nanostructures Theodor Schneller 6 Thin film porous ferroic nanostructures: Strategies and characterization Alichandra Castro, Paula Ferreira, Stella Skiadopoulou, Paula M. Vilarinho, Liliana P. Ferreira, Margarida Godinho and Brian J. Rodriguez 7 Low-temperature photo-chemical solution deposition of ferroelectric and multiferroic thin films Christopher De Dobbelaere, An Hardy, Marlies K. Van Bael, Iñigo Bretos, Ricardo Jiménez and M. Lourdes Calzada Nanostructuring: fibers and wires 8 Synthesis and properties of ferroelectric nanotubes and nanowires. A review Vincenzo Buscaglia and Maria Teresa Buscaglia 9 Fabrication of one dimensional ferroelectric nano and micro structures by different spinning techniques and their characterization Tony Lusiola and Frank Clemens PART B Characterization (of the nanostructured materials): crystal structure 10 Structural characterization of ferroelectric and multiferroic nanostructures by advanced TEM techniques Etienne Snoeck, Axel Lubk and César Magén 11 Raman spectroscopy of nanostructured ferroelectric materials Marco Deluca and Andreja Gajovic 12 Neutron and synchrotron X-ray scattering studies of bulk and nanostructured multiferroic and ferroelectric materials Evagelia G. Moshopoulou, Pascale Foury-Leylekian, Katharine Page, C. Doubrovsky, Martha Greenblatt and Alan J. Hurd Characterization (of the nanostructured materials): domains 13 Advanced characterization of multiferroic materials by scanning probe methods and scanning electron microscopy Michael R. Koblischka and Anjela Koblischka-Veneva 14 Electrostatic and Kelvin probe force microscopy for domain imaging of ferroic systems Brian J. Rodriguez PART C Nanoscale effects: bulk properties 15 Nanostructured barium titanate ceramics. Intrinsic vs. extrinsic size effects Liliana Mitoseriu and Lavinia P. Curecheriu 16 The effects of ceramic nanostructuring in high sensitivity piezoelectrics Harvey Amorín, Ricardo Jiménez, Jesús Ricote, Alicia Castro and Miguel Algueró 17 Correlation between microstructure and electrical properties of ferroelectric relaxors J.D. Bobic, J. Macutkevic, R. Grigalaitis, Maksim Ivanov, M.M. Vijatovic Petrovic, Juras Banys and Biljana D. Stojanovic 18 Local field engineering approach for tuning dielectric and ferroelectric properties in nanostructured ferroelectrics and composites Leontin Padurariu and Liliana Mitoseriu Nanoscale effects: thin film properties 19 Ferroelectric phase transitions in epitaxial perovskite films Marina Tyunina 20 Interfaces in epitaxial ferroelectric layers/multilayers and their effect on the macroscopic electrical properties Lucian Pintilie, Andra G. Boni, Cristina Chirila, Luminita M. Hrib, Alin Iuga, Lucian Trupina, Ioana Pintilie, Iuliana Pasuk, Raluca Negrea, Corneliu Ghica, Mihaela Botea, Nicoleta Apostol and Cristian M. Teodorescu 21 Electric-field control of magnetism based on elastically coupled ferromagnetic and ferroelectric domains Kévin J. A. Franke, Tuomas H. E. Lahtinen, Arianna Casiraghi, Diego López González, Sampo J. Hämäläinen and Sebastiaan van Dijken Nanoscale effects: novel phenomena and applications 22 Ferroelectric vortices and related configurations Sergei Prosandeev, Ivan I. Naumov, Huaxiang Fu, Laurent Bellaiche, Michael P. D. Campbell, Raymond G. P. McQuaid, Li-Wu Chang, Alina Schilling, Leo. J. McGilly, Amit Kumar and J. Marty Gregg 23 Reentrant phenomena in relaxors Alexei A. Bokov and Zuo-Guang Ye 24 Functional twin boundaries: Multiferroicity in confined spaces Ekhard. K. H. Salje and Xiangdong Ding 25 Novel approaches for genuine single phase room temperature magnetoelectric multiferroics Lynette Keeney, Michael Schmidt, Andreas Amann, Tuhin Maity, Nitin Deepak, Ahmad Faraz, Nikolay Petkov, Saibal Roy, Martyn E. Pemble and Roger W. Whatmore 26 Semiconducting and photovoltaic ferroelectrics and multiferroics Andrew R. Akbashev and Jonathan E Spanier Index
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