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High Quality Content by WIKIPEDIA articles! In electrochemistry, the Nernst equation is an equation which can be used (in conjunction with other information) to determine the equilibrium reduction potential of a half-cell in an electrochemical cell. It can also be used to determine the total voltage (electromotive force) for a full electrochemical cell. It is named after the German physical chemist who first formulated it, Walther Nernst.When the membrane is in thermodynamic equilibrium (i.e. no net flux of ions), the membrane potential must be equal to the Nernst potential. However, in physiology, due to active ion pumps, the inside and outside of a cell are not in equilibrium. In this case the resting potential can be determined from the Goldman equation.