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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In a mixed-order reaction the order of a reaction changes in the course of a reaction as a result of changing variables such as pH. An example is the oxidation of an alcohol to a ketone by a ruthenate (RuO42 ) and a hexacyanoferrate, the latter serving as the sacrificial catalyst converting Ru(IV) back to Ru(VI) : the disappearing-rate of the ferrate is zero-order with respect to the ferrate at the onset of the reaction (when its concentration is high and the…mehr

Produktbeschreibung
Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In a mixed-order reaction the order of a reaction changes in the course of a reaction as a result of changing variables such as pH. An example is the oxidation of an alcohol to a ketone by a ruthenate (RuO42 ) and a hexacyanoferrate, the latter serving as the sacrificial catalyst converting Ru(IV) back to Ru(VI) : the disappearing-rate of the ferrate is zero-order with respect to the ferrate at the onset of the reaction (when its concentration is high and the ruthenium catalyst is quickly regenerated) but changes to first-order when its concentration decreases.