to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7…mehr
to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.
to Volume Two.- Classification.- The 18-electron rule.- 1. Two-Electron Ligands.- A. Classification.- B. The preparation of olefin-transition metal complexes.- C. A molecular orbital description of the bonding in organo-metallic complexes.- D. A description of the bonding of 2-electron ligands to transition metals.- E. General comments of 2-electron ligands.- F. Particular complexes of metals with 2-electron ligands.- 2. Three-Electron Ligands.- A. Preparation of ?-enyl complexes.- B. The structure of ?-enyl complexes.- C. The ?-allyl metal bond.- D. Dynamic equilibria in allyl complexes.- E. The chemistry of particular ?-enyl complexes.- 3. Four-Electron Ligands.- A. Some differences between unconjugated and conjugated olefin ligands.- B. The bonding of 4-electron ligands to transition metals.- C. Particular studies.- 4. Five-Electron Ligands.- A. Cyclopentadienyl metal complexes.- B. ?-Cyclopentadienyl transition metal complexes.- C. Cyclopentadienide transition metal complexes.- D. The bonding in mono-?-cyclopentadienyl transition metal complexes.- E. ?-Cyclopentadienyl carbonyl complexes.- F. ?-Cyclopentadienyl nitrosyl complexes.- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands.- H. ?-Cyclopentadienyl hydride complexes.- I. ?-Cyclopentadienyl halides and oxides.- J. Other 5-electron ligands.- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes.- L. Some particular reactions.- 5. Six-Electron Ligands.- A. Arene transition metal complexes.- (a) Preparation.- B. Olefin 6-electron ligands.- C. Transition metal complexes containing ?-bonded heterocyclic ligands.- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes.- A. 7-Electron ligands.-B. Mixed sandwich complexes.- C. Metal complexes formed from azulenes.- D. Cyclo-octatetraene complexes.- 7. One-Electron Ligands.- I.1. Hydrocarbon alkyl and aryl complexes.- I.2 Transition metal-acyl complexes.- I.3. ?-Cyclopentadienyl complexes.- II. Transition metal fluorocarbon complexes.- III. Transition metal acetytides and alkynyls.- 8. Organometallic Complexes Formed From Acetylenes.- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands.- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands.- C. Monoacetylene trinuclear complexes.- D. Monoacetylene tetranuclear complexes.- E. Bis-acetylene mononuclear complexes.- F. Bis-acetylene trinuclear complexes.- G. Tris-acetylene mononuclear complexes.- H. Tris-acetylene binuclear complexes.- I. Miscellaneous.- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions.- A. Some chemistry of transition metal hydride complexes.- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions.- C. Homogeneous hydrogenation of olefins and acetylenes.- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes.- E. Hydroformylation and related carhonylation reactions.- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts.- G. Miscellaneous.- Author.- Subject.- Crystal Structures>.
to Volume Two.- Classification.- The 18-electron rule.- 1. Two-Electron Ligands.- A. Classification.- B. The preparation of olefin-transition metal complexes.- C. A molecular orbital description of the bonding in organo-metallic complexes.- D. A description of the bonding of 2-electron ligands to transition metals.- E. General comments of 2-electron ligands.- F. Particular complexes of metals with 2-electron ligands.- 2. Three-Electron Ligands.- A. Preparation of ?-enyl complexes.- B. The structure of ?-enyl complexes.- C. The ?-allyl metal bond.- D. Dynamic equilibria in allyl complexes.- E. The chemistry of particular ?-enyl complexes.- 3. Four-Electron Ligands.- A. Some differences between unconjugated and conjugated olefin ligands.- B. The bonding of 4-electron ligands to transition metals.- C. Particular studies.- 4. Five-Electron Ligands.- A. Cyclopentadienyl metal complexes.- B. ?-Cyclopentadienyl transition metal complexes.- C. Cyclopentadienide transition metal complexes.- D. The bonding in mono-?-cyclopentadienyl transition metal complexes.- E. ?-Cyclopentadienyl carbonyl complexes.- F. ?-Cyclopentadienyl nitrosyl complexes.- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands.- H. ?-Cyclopentadienyl hydride complexes.- I. ?-Cyclopentadienyl halides and oxides.- J. Other 5-electron ligands.- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes.- L. Some particular reactions.- 5. Six-Electron Ligands.- A. Arene transition metal complexes.- (a) Preparation.- B. Olefin 6-electron ligands.- C. Transition metal complexes containing ?-bonded heterocyclic ligands.- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes.- A. 7-Electron ligands.-B. Mixed sandwich complexes.- C. Metal complexes formed from azulenes.- D. Cyclo-octatetraene complexes.- 7. One-Electron Ligands.- I.1. Hydrocarbon alkyl and aryl complexes.- I.2 Transition metal-acyl complexes.- I.3. ?-Cyclopentadienyl complexes.- II. Transition metal fluorocarbon complexes.- III. Transition metal acetytides and alkynyls.- 8. Organometallic Complexes Formed From Acetylenes.- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands.- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands.- C. Monoacetylene trinuclear complexes.- D. Monoacetylene tetranuclear complexes.- E. Bis-acetylene mononuclear complexes.- F. Bis-acetylene trinuclear complexes.- G. Tris-acetylene mononuclear complexes.- H. Tris-acetylene binuclear complexes.- I. Miscellaneous.- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions.- A. Some chemistry of transition metal hydride complexes.- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions.- C. Homogeneous hydrogenation of olefins and acetylenes.- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes.- E. Hydroformylation and related carhonylation reactions.- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts.- G. Miscellaneous.- Author.- Subject.- Crystal Structures>.
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