Oxidative Palladium(II)-Catalyzed Carbocyclization - Kandukuri, Sandeep Reddy
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The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective Fujiwara Moritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.…mehr

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Produktbeschreibung
The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective Fujiwara Moritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.
Autorenporträt
Sandeep Reddy Kandukuri studied Master of Science (MS) at the Indian Institute of Science, Bangalore (2006¿2009). He earned his PhD in Chemistry under the guidance of Prof. Martin Oestreich at the WWU Münster (Germany) in 2013.