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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Phosphorus trioxide is the chemical compound with the molecular formula P4O6. Although it should properly be named tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound''s molecular structure, and its usage continues today. This colorless solid is structurally related to adamantane. It is formally the anhydride of phosphorous acid, H3PO3, but cannot be obtained by the dehydration of the acid. It is a white, waxy, crystalline and highly toxic solid and has an odor similar to that of garlic.