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1. Introduction.- 2. Description of Polarized Electrons.- 3. Polarization Effects in Electron Scattering Caused by Spin-Orbit Interaction.- 4. Polarization Effects Caused by Exchange Processes in Electron-Atom Scattering.- 5. Polarized Electrons by Ionization Processes.- 6. Further Relativistic Processes Involving Polarized Electrons.- 7. Polarized Electrons from Solids and Surfaces.- 8. Further Applications and Prospects.- References.