Polyester Films

Materials, Processes and Applications
Herausgegeben:Cakmak, Miko; Greener, Jehuda

• Gebundenes Buch

Produktbeschreibung

This volume presents a comprehensive review of key aspects of polyester film technology, ranging from first principles to practical applications

Bringing together world-class experts to review the state-of-the-art of key materials and processing elements of polyester film technology, Polyester Films covers a wide range of topics with direct utility to students, practitioners, business managers and researchers, in academia and industry. Topics covered in this volume include survey of optical and physical properties, microlayer coextrusion, polyester ionomers, polyester blends, biomedical applications and recycling . In particular, the text focuses on novel design and application of polyester films, such as those used in the production of flat panel displays, flexible electronics, and barrier films.

The overriding objective of the book is to scope the multitude of options available to material and product designers in manipulating the properties of polyester films to meet specific performance and product criteria. These options include synthetic modifications (copolymerization), physical enhancements (blending), and process upgrades (tenter-frame changes, coextrusion, and coating).

Edited by two highly qualified material scientists with extensive experience in academia and industry, Polyester Films covers topics such as:
_ Historical review of polyester film technology
_ Overview of physical performance and applications of key polyester films, especially PET and PEN
_ Synthetic options available for manipulating the structure and properties of polyesters, with special focus on polyester ionomers
_ Main blending options available to enhance the performance of commodity polyesters
_ Rheo-optical properties of polyester films and corresponding testing methodology
_ Micro-layer coextrusion technology as applied to modify the performance of polyester films
_ Bio-medical applications
_ Polyester recycling, with special focus on upcycling

With an interdisciplinary approach covering the performance of real-life products and components, Polyester Films is an essential resource for researchers and engineers in academia and industry working in physics, material science, chemistry and process engineering. This volume should also be invaluable for graduate students and early-career researchers in similar fields.

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Produktdetails

• Verlag: Wiley / Wiley & Sons
• Artikelnr. des Verlages: 1W119535750
• 1. Auflage
• Seitenzahl: 384
• Erscheinungstermin: 25. Juli 2023
• Englisch
• Abmessung: 229mm x 152mm x 22mm
• Gewicht: 762g
• ISBN-13: 9781119535751
• ISBN-10: 1119535751
• Artikelnr.: 66453961

Autorenporträt

Prof. Mukerrem (Miko) Cakmak is currently the Reilly Chaired Professor of Materials and Mechanical Engineering at Purdue University, USA. He is one of the founders of the Polymer Engineering Department at the University of Akron where he was Harold A. Morton Chair and Distinguished Professor of Polymer Engineering for 32 years. Dr. Jehuda Greener is an independent consultant specializing in film technologies and polymeric materials and processes. Until 2013, he was a Technology Associate and Distinguished Scientist with the Tech Center of Dow Chemical's Advanced Materials Division (Formerly Rohm and Haas Electronic Materials).

Inhaltsangabe

List of Contributors xi

Preface xiii

1 Polyester Films: An Overview 1
Jehuda Greener

1.1 Introduction 1

1.2 Historical Overview 6

1.3 Physical Properties 7

1.4 Light Management Films 12

1.5 Summary 15

References 16

2 Polyester Materials and Properties 19
Dennis J. Massa

2.1 Introduction 19

2.2 Thermoplastic Polyesters: PET, PBT, and PTT 20

2.3 Thermoplastic Polyesters Containing Cyclic Diols 22

2.4 Thermoplastic Polyester Films: PET and PEN 23

2.5 Aromatic Polyesters 26

2.6 Thermotropic Main- Chain Liquid- Crystalline Polyesters 27

2.7 Wholly Aliphatic Polyesters 28

2.8 Branched and Hyperbranched Polyesters 28

2.9 Thermoplastic Polyester Elastomers and Multiblock Copolymers 29

2.10 Biodegradable and Compostable Polyesters, and Polyesters from Renewable Feedstocks 29

2.11 Dependence of Polyester Properties on Polymer Entanglement Molar Mass 31

2.12 Polyester Blends 32

2.13 Ion- containing Polyesters 33

2.14 Filled Polyesters 34

2.15 Polyester Degradation 34

Acknowledgment 35

References 35

3 Film Properties and Internal Structure Development of Miscible Polyester Blends 47
Karnav Kanuga

3.1 Introduction 47

3.1.1 Thermal Transitions in Polyester 48

3.1.2 PET/PEN Blends 49

3.1.3 PET/PEI Blends 52

3.1.4 PEN/PEI Blends 56

3.1.4.1 Liquid- Liquid Transition Temperature (T ll) 61

3.1.5 PEN/PEI/PEEK Ternary Blends 63

References 65

4 Polyester Ionomers 67
Robert A. Weiss

4.1 Introduction 67

4.2 Random and Segmented Polyester Ionomers 69

4.3 Poly(Ether- Ester) Ionomers 89

4.4 Random Polylactide Ionomers 104

4.5 Telechelic Polyester Ionomers 107

4.6 Liquid Crystalline Ionomers (LCI) 112

4.7 Polyester Ionomer Patents 126

4.7.1 Ionomer Synthesis 126

4.7.1.1 Polyester Ionomers 126

4.7.1.2 Poly(Ether Ester) Ionomers 127

4.7.2 Polyester Ionomer Applications 127

4.7.2.1 Adhesives 127

4.7.2.2 Films, Fibers, and Textiles 128

4.7.2.3 Imaging and Inks 128

4.7.2.4 Coatings and Packaging 129

4.7.2.5 Antistatic and Conductive Compositions 130

4.7.2.6 Polymer Blends, Compatibilizers, and Nanocomposites 130

4.7.2.7 Cosmetics and Personal Care Products 131

4.7.2.8 Miscellaneous Applications 132

Abbreviations 132

References 135

5 The Rheo- Optical Properties of Polyester Films 157
Baris Yalcin and Miko Cakmak

5.1 Birefringence and Its Measurement 157

5.2 Polyester Films 164

5.3 Online Optical Measurements 167

5.4 Polyethylene Terephthalate 176

5.4.1 Simultaneous Stretching 176

5.4.1.1 Regime I 178

5.4.1.2 Regime II 180

5.4.1.3 Regime III 180

5.4.1.4 Regime IV 181

5.4.2 Sequential Stretching 181

5.4.2.1 Regime I 182

5.4.2.2 Regime II 183

5.4.2.3 Regime III 184

5.4.3 Relaxation 184

5.4.4 Heat- setting 189

5.4.4.1 Category I 190

5.4.4.2 Category II 192

5.4.4.3 Category III 192

5.5 Poly(Ethylene Terephthalate) (PET) and Poly(Etherimide) (PEI) Blend 195

5.6 Polyethylene Naphthalate (PEN) 198

5.7 Poly (Lactic Acid) 209

5.8 Summary 215

5.8.1 Stretching Stage 215

5.8.2 Relaxation Stage 217

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