Porous Materials
Herausgegeben von Bruce, Duncan W.; O'Hare, Dermot; Walton, Richard I.
Porous Materials
Herausgegeben von Bruce, Duncan W.; O'Hare, Dermot; Walton, Richard I.
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Porous Materials focuses on the exciting field of porous materials, in which there have been a number of significant breakthroughs in the design and processing of novel porous materials. The authors demonstrate rapid growth of emerging applications, such as energy conversion and storage, catalysis, tissue engineering, drug delivery, medical diagnosis, and photonics. Ideal for graduate students and researchers in inorganic chemistry and solid-state physics, the chapters in this volume cover inorganic zeotypes, ordered mesoporous materials, silicates, metal oxides, and advances in silicate zeolite chemistry, among other topics.…mehr
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- Produktdetails
- Inorganic Materials Series
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 352
- Erscheinungstermin: 6. Dezember 2010
- Englisch
- Abmessung: 234mm x 157mm x 23mm
- Gewicht: 635g
- ISBN-13: 9780470997499
- ISBN-10: 0470997494
- Artikelnr.: 28776948
- Inorganic Materials Series
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 352
- Erscheinungstermin: 6. Dezember 2010
- Englisch
- Abmessung: 234mm x 157mm x 23mm
- Gewicht: 635g
- ISBN-13: 9780470997499
- ISBN-10: 0470997494
- Artikelnr.: 28776948
Metal-Organic Framework Materials (Cameron J. Kepert). 1.1 Introduction.
1.2 Porosity. 1.2.1 Framework Structures and Properties. 1.2.2 Storage and
Release. 1.2.3 Selective Guest Adsorption and Separation. 1.2.4
Heterogeneous Catalysis. 1.3 Incorporation of Other Properties. 1.3.1
Magnetic Ordering. 1.3.2 Electronic and Optical Properties. 1.3.3
Structural and Mechanical Properties. 1.4 Concluding Remarks.
Acknowledgements. References. 2 Mesoporous Silicates (Karen J. Edler). 2.1
Introduction. 2.2 Nomenclature. 2.3 Methods of Preparation. 2.4 Surfactant
Aggregation. 2.5 Silica Source. 2.6 Template Removal. 2.7 Synthetic Routes
and Formation Mechanisms. 2.7.1 True Liquid Crystal Templating. 2.7.2
Cooperative Self-Assembly. 2.7.3 Evaporation-Induced Self-Assembly. 2.8
Properties and Characterisation. 2.9 Macroscopic Structures. 2.10
Applications. References. 3 Ordered Porous Crystalline Transition Metal
Oxides (Masahiro Sadakane and Wataru Ueda). 3.1 Introduction. 3.2 Scope and
Limitations of this Review. 3.3 Microporous Transition Metal Oxide
Materials. 3.4 Mesoporous Transition Metal Oxide Materials. 3.4.1 Soft
Template Method. 3.4.2 Hard Template Method. 3.4.3 Mesoporous Oxides of
Group 4 Elements (Ti, Zr). 3.4.4 Mesoporous Oxidesof Group 5 Elements (Nb,
Ta). 3.4.5 Mesoporous Oxides of Group 6 Elements (Cr, Mo, W). 3.4.6
Mesoporous Oxides of Group 7 Elements (Mn). 3.4.7 Mesoporous Oxides of
Elements of Groups 8-11 (Fe, Co, Ni, Cu). 3.4.8 Mesoporous Oxides of
Lanthanide Elements (Ce). 3.5 Macroporous Materials. 3.5.1 Macroporous
Monometal Oxides. 3.5.2 Macroporous Oxides of Group 4 Elements (Ti, Zr).
3.5.3 Macroporous Oxides of Group 5 Elements(V, Nb). 3.5.4 Macroporous
Oxides of Group 6 Elements(Cr,W). 3.5.5 Macroporous Oxides of Elements of
Groups 7-11 (Mn, Fe, Co, Ni, Cu). 3.5.6 Macroporous Oxides of Lanthanide
Elements (La, Ce, Nd, Sm, Eu). 3.5.7 Macroporous Multi-Component Metal
Oxides. 3.5.8 Two-Step Templating Method. 3.5.9 Applications. 3.6
Conclusion. References. 4 Templated Porous Carbon Materials: Recent
Developments (Yongde Xia, Zhuxian Yang and Robert Mokaya). 4.1
Introduction. 4.2 Microporous Carbon Materials. 4.2.1 Zeolites as Hard
Template. 4.2.2 Clays as Hard Template. 4.2.3 Other Microporous Materials
as Hard Template. 4.3 Mesoporous Carbon Materials. 4.3.1 Conventional Hard
Template Synthesis Strategy. 4.3.2 Cost-Effective Strategies for the
Synthesis of Mesoporous Carbons. 4.3.3 Soft-Template Synthesis Strategy for
Ordered Mesoporous Carbons. 4.3.4 Ordered Mesoporous Carbons with Graphitic
Pore Wall. 4.3.5 Mesopore Size Control. 4.3.6 Morphology Control. 4.4
Macroporous Carbon Materials. 4.4.1 Silica Colloidal Crystals as Hard
Template. 4.4.2 Polymer Microspheres as Template. 4.4.3 Dual Template
Method. References. 5 Synthetic Silicate Zeolites: Diverse Materials
Accessible Through Geoinspiration (Miguel A. Camblor and Suk Bong Hong).
5.1 Introduction. 5.2 Zeolites: Some Definitions. 5.3 Zeolite Structures.
5.4 Chemical Composition of Silicate Zeolites. 5.4.1 Naming Zeolites. 5.4.2
Loewenstein's Rule. 5.5 Zeolite Properties. 5.6 Zeolite Applications. 5.7
Zeolite Synthesis. 5.7.1 The Synthetic Zeolites as Geoinspired Materials.
5.7.2 Thermochemistry of Zeolite Synthesis. 5.7.3 Organic
Structure-Directing Agents. 5.7.4 Structure-Direction by Flexible,
Hydrophilic OSDAs. 5.7.5 Double OSDA Strategies. 5.7.6 Structure-Direction
by T-Atoms. 5.7.7 Zeolite Synthesis from Nonaqueous Solvents. 5.7.8 The
Fluoride Route to Zeolites. 5.7.9 Structure-Direction Issues in the
Fluoride Route to Pure-Silica Zeolites. 5.7.10 Topotactic Condensation of
Layered Silicates. 5.8 Concluding Remarks. Acknowledgements. References.
Index.
Metal-Organic Framework Materials (Cameron J. Kepert). 1.1 Introduction.
1.2 Porosity. 1.2.1 Framework Structures and Properties. 1.2.2 Storage and
Release. 1.2.3 Selective Guest Adsorption and Separation. 1.2.4
Heterogeneous Catalysis. 1.3 Incorporation of Other Properties. 1.3.1
Magnetic Ordering. 1.3.2 Electronic and Optical Properties. 1.3.3
Structural and Mechanical Properties. 1.4 Concluding Remarks.
Acknowledgements. References. 2 Mesoporous Silicates (Karen J. Edler). 2.1
Introduction. 2.2 Nomenclature. 2.3 Methods of Preparation. 2.4 Surfactant
Aggregation. 2.5 Silica Source. 2.6 Template Removal. 2.7 Synthetic Routes
and Formation Mechanisms. 2.7.1 True Liquid Crystal Templating. 2.7.2
Cooperative Self-Assembly. 2.7.3 Evaporation-Induced Self-Assembly. 2.8
Properties and Characterisation. 2.9 Macroscopic Structures. 2.10
Applications. References. 3 Ordered Porous Crystalline Transition Metal
Oxides (Masahiro Sadakane and Wataru Ueda). 3.1 Introduction. 3.2 Scope and
Limitations of this Review. 3.3 Microporous Transition Metal Oxide
Materials. 3.4 Mesoporous Transition Metal Oxide Materials. 3.4.1 Soft
Template Method. 3.4.2 Hard Template Method. 3.4.3 Mesoporous Oxides of
Group 4 Elements (Ti, Zr). 3.4.4 Mesoporous Oxidesof Group 5 Elements (Nb,
Ta). 3.4.5 Mesoporous Oxides of Group 6 Elements (Cr, Mo, W). 3.4.6
Mesoporous Oxides of Group 7 Elements (Mn). 3.4.7 Mesoporous Oxides of
Elements of Groups 8-11 (Fe, Co, Ni, Cu). 3.4.8 Mesoporous Oxides of
Lanthanide Elements (Ce). 3.5 Macroporous Materials. 3.5.1 Macroporous
Monometal Oxides. 3.5.2 Macroporous Oxides of Group 4 Elements (Ti, Zr).
3.5.3 Macroporous Oxides of Group 5 Elements(V, Nb). 3.5.4 Macroporous
Oxides of Group 6 Elements(Cr,W). 3.5.5 Macroporous Oxides of Elements of
Groups 7-11 (Mn, Fe, Co, Ni, Cu). 3.5.6 Macroporous Oxides of Lanthanide
Elements (La, Ce, Nd, Sm, Eu). 3.5.7 Macroporous Multi-Component Metal
Oxides. 3.5.8 Two-Step Templating Method. 3.5.9 Applications. 3.6
Conclusion. References. 4 Templated Porous Carbon Materials: Recent
Developments (Yongde Xia, Zhuxian Yang and Robert Mokaya). 4.1
Introduction. 4.2 Microporous Carbon Materials. 4.2.1 Zeolites as Hard
Template. 4.2.2 Clays as Hard Template. 4.2.3 Other Microporous Materials
as Hard Template. 4.3 Mesoporous Carbon Materials. 4.3.1 Conventional Hard
Template Synthesis Strategy. 4.3.2 Cost-Effective Strategies for the
Synthesis of Mesoporous Carbons. 4.3.3 Soft-Template Synthesis Strategy for
Ordered Mesoporous Carbons. 4.3.4 Ordered Mesoporous Carbons with Graphitic
Pore Wall. 4.3.5 Mesopore Size Control. 4.3.6 Morphology Control. 4.4
Macroporous Carbon Materials. 4.4.1 Silica Colloidal Crystals as Hard
Template. 4.4.2 Polymer Microspheres as Template. 4.4.3 Dual Template
Method. References. 5 Synthetic Silicate Zeolites: Diverse Materials
Accessible Through Geoinspiration (Miguel A. Camblor and Suk Bong Hong).
5.1 Introduction. 5.2 Zeolites: Some Definitions. 5.3 Zeolite Structures.
5.4 Chemical Composition of Silicate Zeolites. 5.4.1 Naming Zeolites. 5.4.2
Loewenstein's Rule. 5.5 Zeolite Properties. 5.6 Zeolite Applications. 5.7
Zeolite Synthesis. 5.7.1 The Synthetic Zeolites as Geoinspired Materials.
5.7.2 Thermochemistry of Zeolite Synthesis. 5.7.3 Organic
Structure-Directing Agents. 5.7.4 Structure-Direction by Flexible,
Hydrophilic OSDAs. 5.7.5 Double OSDA Strategies. 5.7.6 Structure-Direction
by T-Atoms. 5.7.7 Zeolite Synthesis from Nonaqueous Solvents. 5.7.8 The
Fluoride Route to Zeolites. 5.7.9 Structure-Direction Issues in the
Fluoride Route to Pure-Silica Zeolites. 5.7.10 Topotactic Condensation of
Layered Silicates. 5.8 Concluding Remarks. Acknowledgements. References.
Index.