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This volume highlights the latest advances, innovations, and applications in the field of asphalt pavement technology, as presented by leading international researchers and engineers at the 5th International Symposium on Asphalt Pavements & Environment (ISAP 2019 APE Symposium), held in Padua, Italy on September 11-13, 2019. It covers a diverse range of topics concerning materials and technologies for asphalt pavements, designed for sustainability and environmental compatibility: sustainable pavement materials, marginal materials for asphalt pavements, pavement structures, testing methods and performance, maintenance and management methods, urban heat island mitigation, energy harvesting, and Life Cycle Assessment. The contributions, which were selected by means of a rigorous international peer-review process, present a wealth of exciting ideas that will open novel research directions and foster multidisciplinary collaboration among different specialists.