E. F. Caldin, Victor Gold

Proton-Transfer Reactions

• Broschiertes Buch

Produktbeschreibung

1 Proton acids, Lewis acids, hard acids, soft acids and superacids.- 2 Gas-phase proton-transfer equilibria.- 3 Proton-transfer and the solvation of ammonium ions.- 4 Participation of hydroxylic solvent molecules.- 5 Hydrogen bonding and proton-transfer reactions in non-aqueous solvents.- 6 Fast and slow proton-transfer reactions in solution.- 7 The Br¿nsted relation; significance of the exponent.- 8 Substrate isotope effects.- 9 Solvent isotope effects.- 10 Tunnelling in hydrogen transfer reactions.- 11 Neighbouring group participation.- 12 Proton-transfer in enzymatic catalysis.- 13 Heterogeneous proton-transfer reactions.

Produktdetails

• Verlag: Springer / Springer US / Springer, Berlin
• Artikelnr. des Verlages: 978-0-412-12700-7
• Softcover reprint of the original 1st ed. 1975
• Seitenzahl: 456
• Erscheinungstermin: 1. Januar 1975
• Englisch
• Abmessung: 235mm x 155mm x 25mm
• Gewicht: 686g
• ISBN-13: 9780412127007
• ISBN-10: 0412127008
• Artikelnr.: 41326472

Inhaltsangabe

1 Proton acids, Lewis acids, hard acids, soft acids and superacids.- 2 Gas-phase proton-transfer equilibria.- 3 Proton-transfer and the solvation of ammonium ions.- 4 Participation of hydroxylic solvent molecules.- 5 Hydrogen bonding and proton-transfer reactions in non-aqueous solvents.- 6 Fast and slow proton-transfer reactions in solution.- 7 The Brønsted relation; significance of the exponent.- 8 Substrate isotope effects.- 9 Solvent isotope effects.- 10 Tunnelling in hydrogen transfer reactions.- 11 Neighbouring group participation.- 12 Proton-transfer in enzymatic catalysis.- 13 Heterogeneous proton-transfer reactions.