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Radiation technology has long been recognized as a process that can degrade, graft and crosslink polymers to fabricate novel value added products. Considering the crucial role that radiation technology plays in the production of commodities aimed at increasing crop yields and consequently preserving these crops, the IAEA and its Member States have initiated and supported projects related to the radiation processing of polymers for agricultural applications. This publication reviews the recent developments in the use of radiation technologies for the preparation of green products based on polymers for agricultural applications.