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High Quality Content by WIKIPEDIA articles! In chemical compounds, polymerization occurs via a variety of reaction mechanisms that vary in complexity due to functional groups present in reacting compounds and their inherent steric effects explained by VSEPR Theory. In more straightforward polymerization, alkenes, which are relatively stable due to bonding between carbon atoms form polymers through relatively simple radical reactions; in contrast, more complex reactions such as those that involve substitution at the carbonyl group require more complex synthesis due to the way in which reacting molecules polymerize.