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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Rotational spectroscopy or microwave spectroscopy studies the absorption and emission of electromagnetic radiation (typically in the microwave region of the electromagnetic spectrum) by molecules associated with a corresponding change in the rotational quantum number of the molecule. The use of microwaves in spectroscopy essentially became possible due to the development of microwave technology for RADAR during World War II. Rotational spectroscopy is only really practical in the gas phase where the rotational motion is quantized. In solids or liquids the rotational motion is usually quenched due to collisions.