Roussin's Red Salt
22,99 €
inkl. MwSt.

Versandfertig in 6-10 Tagen
  • Broschiertes Buch

Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Roussin''s Red Salt is the inorganic compound with the formula [K2][Fe2S2(NO)4]. This metal nitrosyl consists of the potassium salt of the [Fe2N4O4S2]2 anion. This compound was first described in 1858 by the French chemist M.L. Roussin while experimenting with reactions between nitroprusside ion, [Fe(CN)5NO]2 , and sulfur, making it the first synthetic iron-sulfur cluster. Roussin''s red salt anion is an example of a ligand-bridged metal dimer. Its structure is…mehr

Andere Kunden interessierten sich auch für
Produktbeschreibung
Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Roussin''s Red Salt is the inorganic compound with the formula [K2][Fe2S2(NO)4]. This metal nitrosyl consists of the potassium salt of the [Fe2N4O4S2]2 anion. This compound was first described in 1858 by the French chemist M.L. Roussin while experimenting with reactions between nitroprusside ion, [Fe(CN)5NO]2 , and sulfur, making it the first synthetic iron-sulfur cluster. Roussin''s red salt anion is an example of a ligand-bridged metal dimer. Its structure is described as an edge-shared bitetrahedron, wherein a pair Fe(NO)2 units are bridged by a pair of sulfide ligands. The Fe-NO bonds are linear indicating NO is acting as a three electron donor.