Ruthenium Catalysts and Fine Chemistry
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Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness…mehr

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Produktbeschreibung
Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness in organic synthesis of specific reactions including carbocyclization, cyclopropanation, olefin metathesis, carbonylation, oxidation, transformation of silicon containing substrates, and show novel reactions operating via vinylidene intermediates, radical processes, inert bonds activation as well as catalysis in water. Therefore, the reader will receive a balanced view of this rapidly developing field.
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Autorenporträt
Pierre H. Dixneuf is professor of chemistry at the University of Rennes, now Emeritus Professor. He has created a team on Organometallic Chemistry and Catalysis, and in 2000 he founded the Research Institute of Chemistry of Rennes. He has developed successively several processes in ruthenium catalysed reactions: transformations of alkynes, incorporation of CO2, ruthenium-vinylidenes and allenylidenes in catalysis, catalytic synthesis of heterocycles, alkene metahesis catalysts and applications, C-H bond activation including in water. He has designed many new ruthenium catalysts especially involving metal-carbene bond. He has published more than 380 papers, edited 2 books and owns 5 patents. He is a member of Institute Universitaire de France (IUF) since 2000.