The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects - properties, synthesis, reactions, physiological and industrial significance - of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors…mehr
The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects - properties, synthesis, reactions, physiological and industrial significance - of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Edwin M. Smolin is the editor of s-Triazines and Derivatives, Volume 13, published by Wiley. Lorence Rapoport is the editor of s-Triazines and Derivatives, Volume 13, published by Wiley.
Inhaltsangabe
Introduction 1 I. Cyanuric Acid and Derivatives 17 I. Introduction 17 II. Cyanunc Acid 20 III. Cyanuric Halides 48 IV. Cyanuric Acid Esters 67 V. Acyloxy-s-triazines 90 VI. Cyanuric Azides 100 VII. Thiocyanuric Acids 105 VIII. Triazinylthioglycolic Acids and Their Derivatives 114 IX. 2.4.6-Tri(acetonylthio).s.triazine 115 X. Triselenocyanuric Acid 116 XI. Esters of s-Triazine-2,4.6-triphosphonite 117 XII. Uses and Industrial Applications of Cyanuric Chloride and Derivatives 117 II. Alkyl(Ary1)-s-triazines 147 I. Introduction 147 II. General Synthetic Methods 149 III. Reactions 162 IV. Trialkyl-s-Triazines 165 V. Triaryl-s-triazines 171 VI. Alkyl-aryl-s-Triazines 179 VII. Alkyl-aryl-dihydro-s-triazines 179 VIII. Applications 182 III. Monohydroxy-, Hydroxyamino-, Dihydroxy-s-triazines and Related Compounds 185 I. Monohydroxy-s-triazines 185 II. Monochloro-s-triazines 185 III. Hydroxyamino-s-triazines 187 IV. Dihydroxy-s-triazines 202 V. Hydrogenated Derivatives 209 VI. Dihalo-s-triazines 214 lV. Monoamino- and Diamino-s-triazines 217 I. Monoamino-s-triazines 217 II. Diamino-s-triazines 222 III. Diamino dihydro-s-triazines 258 V. Ammelide. Ammeline. and Related Compounds 269 I. Ammelide 269 II. Ammelide Ethers 274 III. Aminodichloro-s-triazines 279 IV.Ammeline 281 V. Ammeline Ethers 285 VI. Diaminochloro-s-triazines 292 VII. Dithioammelide 297 VIII. Thioammeline 298 IX. Thioammeline Ethers 301 X. Related Compounds 305 VI. Melamine and Substituted Melamines 309 I. Introduction 309 II. Physical Properties 309 III. Synthesis of Melamine 309 IV. Reactions of Melamine 321 V. Structure 348 VI. Substituted "Normal" Melamines 349 VII. Applications of Melamine and Derivatives 373 VIII. IsomelaminES 379 VII. Isocyanuric Acid and Derivatives 389 I. Isocyanuric Acid 389 II. 1.3.5.Trihalo.2.4.6.trioxohexahydro-s-triazines 390 III. Esters ofIsocyanuric Acid 393 IV. Isothiocyanuric Acid 416 V. Other Isocyanuric Compounds 420 VIII. Condensed Ring s-Triazine Systems 423 I.Endo Compounds 423 II. Condensed Five-Membered Ring Compounds 426 III. Condensed-Six-Membered Ring Compounds 445 IX. Hexahydro-s-triazines 473 I. Introduction 473 II. Hexahydro-s-triazine and Nitrate 473 III. 1.3.5.Trialkylhexahydro-s-triazine 476 IV. Aryl and Arylalkylhexahydro-s-triazines 490 V. 2.4,6-Trialkyl- and Triarylhexahydro-s-triazines 505 VI. Halogen Derivatives of Hexahydro-s-triazine and Alkylhexahydro-s -triazines 506 VII. Nitro- and Nitrosohexahydro-s-triazines 509 VIII. Amino Derivatives of Hexahydro-s-triazines 526 IX. Sulfonyl Derivatives 528 X. Hydroxy Derivatives: 1.3.5-Trihydroxyhexahydro-s-triazines 1,3,5-Trinitrosohexahydros-s-triazines 531 XI. Carbonyl (Acyl) Derivatives 533 XII. Oxo and Thion Derivatives 536 XIII. Carboxylic Acid Derivatives 539 XIV. 1-Sulfo-4-alkylhexahydro.2,4,6-triazines 540 X. Hexamethylenetetramine 545 I. Introduction 545 II. Structure 545 III. Formation 546 IV. Physical Properties 550 V. Preparation 551 VI. Reactions 552 VII. Detection and Analysis of Hexamethylenetetramie 588 VIII. Uses of Hexamethylenetetramine 588 XI. s-Triazaborane and Its Derivatives 597 I. Introduction 597 II. s-Triazaborane 597 III. Alkyl Derivatives of s-Triazaborane 607 IV. Halogen Derivatives of s-Triazaborane 619 V. Hydroxy-s-triazaboranes 624 VI. Methoxy-s-triazaboranes 624 VII. Other s-Triazaborane Derivatives 625
Introduction 1 I. Cyanuric Acid and Derivatives 17 I. Introduction 17 II. Cyanunc Acid 20 III. Cyanuric Halides 48 IV. Cyanuric Acid Esters 67 V. Acyloxy-s-triazines 90 VI. Cyanuric Azides 100 VII. Thiocyanuric Acids 105 VIII. Triazinylthioglycolic Acids and Their Derivatives 114 IX. 2.4.6-Tri(acetonylthio).s.triazine 115 X. Triselenocyanuric Acid 116 XI. Esters of s-Triazine-2,4.6-triphosphonite 117 XII. Uses and Industrial Applications of Cyanuric Chloride and Derivatives 117 II. Alkyl(Ary1)-s-triazines 147 I. Introduction 147 II. General Synthetic Methods 149 III. Reactions 162 IV. Trialkyl-s-Triazines 165 V. Triaryl-s-triazines 171 VI. Alkyl-aryl-s-Triazines 179 VII. Alkyl-aryl-dihydro-s-triazines 179 VIII. Applications 182 III. Monohydroxy-, Hydroxyamino-, Dihydroxy-s-triazines and Related Compounds 185 I. Monohydroxy-s-triazines 185 II. Monochloro-s-triazines 185 III. Hydroxyamino-s-triazines 187 IV. Dihydroxy-s-triazines 202 V. Hydrogenated Derivatives 209 VI. Dihalo-s-triazines 214 lV. Monoamino- and Diamino-s-triazines 217 I. Monoamino-s-triazines 217 II. Diamino-s-triazines 222 III. Diamino dihydro-s-triazines 258 V. Ammelide. Ammeline. and Related Compounds 269 I. Ammelide 269 II. Ammelide Ethers 274 III. Aminodichloro-s-triazines 279 IV.Ammeline 281 V. Ammeline Ethers 285 VI. Diaminochloro-s-triazines 292 VII. Dithioammelide 297 VIII. Thioammeline 298 IX. Thioammeline Ethers 301 X. Related Compounds 305 VI. Melamine and Substituted Melamines 309 I. Introduction 309 II. Physical Properties 309 III. Synthesis of Melamine 309 IV. Reactions of Melamine 321 V. Structure 348 VI. Substituted "Normal" Melamines 349 VII. Applications of Melamine and Derivatives 373 VIII. IsomelaminES 379 VII. Isocyanuric Acid and Derivatives 389 I. Isocyanuric Acid 389 II. 1.3.5.Trihalo.2.4.6.trioxohexahydro-s-triazines 390 III. Esters ofIsocyanuric Acid 393 IV. Isothiocyanuric Acid 416 V. Other Isocyanuric Compounds 420 VIII. Condensed Ring s-Triazine Systems 423 I.Endo Compounds 423 II. Condensed Five-Membered Ring Compounds 426 III. Condensed-Six-Membered Ring Compounds 445 IX. Hexahydro-s-triazines 473 I. Introduction 473 II. Hexahydro-s-triazine and Nitrate 473 III. 1.3.5.Trialkylhexahydro-s-triazine 476 IV. Aryl and Arylalkylhexahydro-s-triazines 490 V. 2.4,6-Trialkyl- and Triarylhexahydro-s-triazines 505 VI. Halogen Derivatives of Hexahydro-s-triazine and Alkylhexahydro-s -triazines 506 VII. Nitro- and Nitrosohexahydro-s-triazines 509 VIII. Amino Derivatives of Hexahydro-s-triazines 526 IX. Sulfonyl Derivatives 528 X. Hydroxy Derivatives: 1.3.5-Trihydroxyhexahydro-s-triazines 1,3,5-Trinitrosohexahydros-s-triazines 531 XI. Carbonyl (Acyl) Derivatives 533 XII. Oxo and Thion Derivatives 536 XIII. Carboxylic Acid Derivatives 539 XIV. 1-Sulfo-4-alkylhexahydro.2,4,6-triazines 540 X. Hexamethylenetetramine 545 I. Introduction 545 II. Structure 545 III. Formation 546 IV. Physical Properties 550 V. Preparation 551 VI. Reactions 552 VII. Detection and Analysis of Hexamethylenetetramie 588 VIII. Uses of Hexamethylenetetramine 588 XI. s-Triazaborane and Its Derivatives 597 I. Introduction 597 II. s-Triazaborane 597 III. Alkyl Derivatives of s-Triazaborane 607 IV. Halogen Derivatives of s-Triazaborane 619 V. Hydroxy-s-triazaboranes 624 VI. Methoxy-s-triazaboranes 624 VII. Other s-Triazaborane Derivatives 625
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