Ming Qiu Zhang, Min Zhi Rong

Self-Healing Polymers and Polymer Composites

• Gebundenes Buch

Produktbeschreibung

This book covers the fundamentals, theory, design, fabrication, characterization, and application of self-healing polymers and polymer composites. Innovative routes that correlate materials chemistry to the self-healing functionality are summarized for future industrial use. Throughout the book, the authors emphasize integration of existing techniques and / or novel synthetic approaches for target-oriented materials design and fabrication. With this book, experienced readers will gain a comprehensive view of the emerging field, while new researchers will understand the framework for creating new materials or new applications.

Produktdetails

• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 440
• Erscheinungstermin: 6. September 2011
• Englisch
• Abmessung: 241mm x 161mm x 32mm
• Gewicht: 792g
• ISBN-13: 9780470497128
• ISBN-10: 0470497122
• Artikelnr.: 33255787

Autorenporträt

MING QIU ZHANG has over twenty-eight years of systematic experience in polymers, polymer blends, and polymer composites. He serves as a member of Asian-Australasian Association for Composite Materials (AACM) Council and the standing council of Chinese Society for Composites, as well as President of Guangdong Society for Composites. In 1997, he received the prestigious fellowship from the Natural Science Foundation of China for Outstanding Young Scientists; and in 2005, the Li Ka Shing Foundation and the Ministry of Education of China selected him as a Cheung Kong Scholar. In addition, Professor Zhang is on the editorial board of eight scientific journals and holds forty-three patents. MIN ZHI RONG obtained his PhD degree in polymer chemistry and physics in 1994 in Zhongshan University. Before that, he was a researcher and lecturer in the Department of Materials Science and Engineering, Tianjin University. His main interests are focused on thermosetting/thermoplastic blends, polymeric functional materials, structure of polymer networks, polymeric nanocomposites, natural fiber composites, and self-healing of polymeric materials. Among his many professional accolades, Professor Rong won the 2007 Prize for Achievements in Natural Science Research for his work on polymer nanocomposites awarded by the Ministry of Education of China. Along with having been published in about 180 journal papers and book chapters, Professor Rong also holds thirty-five patents.

Inhaltsangabe

Preface. 1 Basics of Self-Healing: State of the Art. 1.1 Background. 1.1.1
Adhesive Bonding for Healing Thermosetting Materials. 1.1.2 Fusion Bonding
for Healing Thermoplastic Materials. 1.1.3 Bioinspired Self-Healing. 1.2
Intrinsic Self-Healing. 1.2.1 Self-Healing Based on Physical Interactions.
1.2.2 Self-Healing Based on Chemical Interactions. 1.2.3 Self-Healing Based
on Supramolecular Interactions. 1.3 Extrinsic Self-Healing. 1.3.1
Self-Healing in Terms of Healant Loaded Pipelines. 1.3.2 Self-Healing in
Terms of Healant Loaded Microcapsules. 1.4 Insights for Future Work.
References. 2 Theoretical Consideration and Modeling. 2.1 Molecular
Mechanisms. 2.1.1 Self-Healing Below Glass Transition Temperature. 2.1.2
Self-Healing Above Glass Transition Temperature. 2.2 Healing Modeling.
2.2.1 Percolation Modeling. 2.2.2 Continuum and Molecular-Level Modeling of
Fatigue Crack Retardation. 2.2.3 Continuum Damage and Healing Mechanics.
2.2.4 Discrete Element Modeling and Numerical Study. 2.3 Design of
Self-Healing Composites. 2.3.1 Entropy Driven Self-Assembly of
Nanoparticles. 2.3.2 Optimization of Microvascular Networks. 2.4 Concluding
Remarks. References. 3 Extrinsic Self-Healing via Addition Polymerization.
3.1 Design and Selection of Healing System. 3.2 Microencapsulation of
Mercaptan and Epoxy by in situ Polymerization. 3.2.1 Microencapsulation of
Mercaptan. 3.2.2 Microencapsulation of Epoxy. 3.3 Characterization of
Self-Healing Functionality. 3.3.1 Self-Healing Epoxy Materials with
Embedded Dual Encapsulated Healant: Healing of Crack Due to Monotonic
Fracture. 3.3.2 Factors Related to Performance Improvement. 3.3.3
Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant:
Healing of Fatigue Crack. 3.3.4 Self-Healing Epoxy/Glass Fabric Composites
with Embedded Dual Encapsulated Healant: Healing of Impact Damage. 3.4
Concluding Remarks. References. 4 Extrinsic Self-Healing via Cationic
Polymerization. 4.1 Microencapsulation of Epoxy by UV Irradiation-Induced
Interfacial Copolymerization. 4.2 Encapsulation of Boron-Containing Curing
Agent. 4.2.1 Loading Boron-Containing Curing Agent onto Porous Media. 4.2.2
Microencapsulation of Boron-Containing Curing Agent via Hollow Capsules
Approach. 4.3 Characterization of Self-Healing Functionality. 4.3.1
Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and
(C2H5)2O·BF3-Loaded Sisal. 4.3.2 Self-Healing Epoxy Materials with Embedded
Dual Encapsulated Healant. 4.4 Concluding Remarks. References. 5 Extrinsic
Self-Healing via Anionic Polymerization. 5.1 Preparation of Epoxy-Loaded
Microcapsules and Latent Hardener. 5.1.1 Microencapsulation of Epoxy by in
situ Condensation. 5.1.2 Preparation of Imidazole Latent Hardener. 5.2
Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and
Latent Hardener. 5.3 Self-Healing Epoxy/Woven Glass Fabric Composites with
Embedded Epoxy-Loaded Microcapsules and Latent Hardener: Healing of
Interlaminar Failure. 5.4 Durability of Healing Ability. 5.5 Self-Healing
Epoxy/Woven Glass Fabric Composites with Embedded Epoxy-Loaded
Microcapsules and Latent Hardener: Healing of Impact Damage. 5.6 Concluding
Remarks. References. 6 Extrinsic Self-Healing via Miscellaneous Reactions.
6.1 Extrinsic Self-Healing via Nucleophilic Addition and Ring-Opening
Reactions. 6.1.1 Microencapsulation of GMA by in situ Polymerization. 6.1.2
Self-Healing Epoxy Materials with Embedded Single-Component Healant. 6.2
Extrinsic Self-Healing via Living Polymerization. 6.2.1 Preparation of
Living PMMA and Its Composites with GMA-Loaded Microcapsules. 6.2.2
Characterization of Self-Healing Functionality. 6.3 Extrinsic Self-Healing
via Free Radical Polymerization. 6.3.1 Microencapsulation of Styrene and
BPO. 6.3.2 Self-Healing Performance of Epoxy Filled with Dual Capsules. 6.4
Concluding Remarks. References. 7 Intrinsic Self-Healing via Diels-Alder
Reaction. 7.1 Molecular Design and Synthesis. 7.1.1 Synthesis and
Characterization of DGFA. 7.1.2 Reversibility of DA Bonds and Crack
Remendability of DGFA Based Polymer. 7.1.3 Synthesis and Characterization
of FGE. 7.1.4 Reversibility of DA Bonds and Crack Remendability of
FGE-Based Polymer. 7.2 Blends of DGFA and FGE. 7.2.1 Reversibility of DA
Bonds. 7.2.2 Crack Remendability of Cured DGFA/FGE Blends. 7.3 Concluding
Remarks. References. 8 Applications. 8.1 Coatings and Films. 8.2
Elastomers. 8.3 Smart Composites. 8.4 Tires. 8.5 Concluding Remarks.
References. Appendix: Nomenclature. Index.