This comprehensive book describes the design, synthesis, mechanisms, characterization, fundamental properties, functions and development of self-healing smart materials and their composites with their allied applications. It covers cementitious concrete composites, bleeding composites, elastomers, tires, membranes, and composites in energy storage, coatings, shape-memory, aerospace and robotic applications. The 21 chapters are written by researchers from a variety of disciplines and backgrounds.
This comprehensive book describes the design, synthesis, mechanisms, characterization, fundamental properties, functions and development of self-healing smart materials and their composites with their allied applications. It covers cementitious concrete composites, bleeding composites, elastomers, tires, membranes, and composites in energy storage, coatings, shape-memory, aerospace and robotic applications. The 21 chapters are written by researchers from a variety of disciplines and backgrounds.Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Inamuddin PhD is an assistant professor at King Abdulaziz University, Jeddah, Saudi Arabia and is also an assistant professor in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. He has extensive research experience in multidisciplinary fields of analytical chemistry, materials chemistry, electrochemistry, renewable energy and environmental science. He has published about 150 research articles in various international scientific journals, 18 book chapters, and edited 60 books with multiple well-known publishers. Mohd Imran Ahamed PhD is in the Department of Chemistry, Aligarh Muslim University, Aligarh, India. He has published several research and review articles in SCI journals. His research focuses on ion-exchange chromatography, wastewater treatment and analysis, actuators and electrospinning. Rajender Boddula PhD is currently working for the Chinese Academy of Sciences President's International Fellowship Initiative (CAS-PIFI) at the National Center for Nanoscience and Technology (NCNST, Beijing). His academic honors include multiple fellowships and scholarships, and he has published many scientific articles in international peer-reviewed journals, edited books with numerous publishers and has authored 20 book chapters. Tariq Altalhi PhD is Head of the Department of Chemistry and Vice Dean of Science College at Taif University, Saudi Arabia. He received his PhD from the University of Adelaide, Australia in 2014. His research interests include developing advanced chemistry-based solutions for solid and liquid municipal waste management, converting plastic bags to carbon nanotubes, and fly ash to efficient adsorbent material.
Inhaltsangabe
Preface xv
1 Self-Healing Polymer Coatings 1 Facundo I. Altuna and Cristina E. Hoppe
1.1 Introduction 2
1.2 Extrinsic Self-Healing Polymer Coatings 5
1.3 Intrinsic Self-Healing Polymer Coatings 13
1.4 Remote Activation of Self-Healing 21
1.5 Perspectives and Challenges 26
References 27
2 Smart Phenolics for Self-Healing and Shape Memory Applications 39 Baris Kiskan and Yusuf Yagci
2.1 Introduction 40
2.2 Self-Healable Polybenzoxazines 42
2.3 Benzoxazine Resins for Shape Memory Applications 51
2.4 Conclusion 57
References 58
3 Self-Healable Elastomers 65 Mariajose Cova Sánchez, Daniela Belén García, Mariano Martin Escobar and Marcela Mansilla
3.1 Introduction 65
3.2 Self-Healing in Elastomers 67
3.2.1 Self-Healing Mechanism 68
3.2.1.1 Heat Stimulated Self-Healing 68
3.2.1.2 Light Stimulated Self-Healing 68
3.2.1.3 Mechanochemical Self-Healing 68
3.2.1.4 Encapsulation 69
3.2.2 Characterization of Healing Process 70
3.3 Particular Cases in Different Elastomers 71
3.3.1 Natural Rubber (NR) 71
3.3.2 Styrene Butadiene Rubber (SBR) 76
3.3.3 Polybutadiene Rubber 79
3.3.4 Bromobutyl Rubber 81
3.3.5 Silicones 84
3.3.6 Polyurethanes 89
References 92
4 Self-Healable Tires 99 Norazlianie Sazali, Mohamad Azuwa Mohamed and Zul Adlan Mohd Hir
4.1 Introduction 100
4.2 Self-Healable Rubber 102
4.3 Promising Strategy for Self-Healing Rubber-Based Material 103
4.4 Conclusion 113
References 113
5 Self-Healing Bacterial Cementitious Composites 123 R. Preetham, R. Hari Krishna, M.N. Chandraprabha and R. Sivaramakrishna
5.1 Introduction 124
5.2 Biomineralization for Self-Healing 130
5.2.1 Bacteria as Self-Healing Agent 130
5.2.2 Bacterial Metabolic Pathway in Self-Healing 131
5.2.2.1 Urea Hydrolysis by Ureolytic Bacteria 132
5.2.2.2 Hydrolysis of CO2 by Carbonic Anhydrase Producing Bacteria 133
5.2.2.3 Hydrolysis of Organic Acids 134
5.2.2.4 Dissimilatory Nitrate Reduction 134
5.2.2.5 Dissimilatory Sulfate Reduction 135
5.2.2.6 Ammonification 135
5.3 Strategies to Enhance the Performance of Bacterial Self-Healing 139
5.4 Evaluation of Factors Affecting Bacterial Self-Healing 141
5.4.1 Nutrient Suitability for Optimal Bacterial Growth 142
5.4.2 Viability and Activity of Encapsulated Spores 143
